Blocker device for eliminating specular reflectance from a diffuse reflection spectrum

• US 4,661,706 A
• Filed: 02/25/1985
• Issued: 04/28/1987
• Est. Priority Date: 02/25/1985
• Status: Expired due to Term

• Current Assignee: Spectra-Tech, Inc. (Thermo Fisher Scientific Incorporated)
• Original Assignee: Spectra-Tech, Inc. (Thermo Fisher Scientific Incorporated)
• Inventors: Messerschmidt, Robert G., Sting, Donald W.
• Primary Examiner(s): FALCONE, JANICE ARRINGTON
• Application Number:
  US06/705,201
• Time in Patent Office: 792 Days
• Field of Search: 250/338 R, 250/341, 250/353, 250/372, 250/336.1, 250/461.1, 350/266, 350/268
• US Class Current: 250/341.8
• CPC Class Codes: G01N 2021/3595 using FTIR
• CPC Class Codes: G01N 2021/4769 Fluid samples, e.g. slurries, granulates; Compressible powdery of fibrous samples
• CPC Class Codes: G01N 21/474 Details of optical heads therefor, e.g. using optical fibres

Abstract

Diffuse reflectance spectra may be obtained that are free from the distortions caused by specular reflections by using an apparatus and method for physically blocking out specularly reflected energy. The apparatus consists of a blocker that is positioned substantially in contact with the surface of the sample at the region wherein an input beam of energy is focused on the sample. Specularly reflected energy that would otherwise be reflected to a detector is physically blocked by the blocker. That part of the input energy beam that penetrates into the sample is diffusely reflected. Part of the diffusely reflected energy passes under the blocker where it is collected and focused on the detector. The blocker is found to have particular application in the field of infrared spectroscopy of inorganic compounds, particularly compounds having a powdered structure.

Claims

1. An apparatus for obtaining a diffuse reflectance spectra comprising:

means for providing an incident energy beam;

means for directing the incident energy beam to a sample;

means for collecting energy that is diffusely reflected from the sample;

blocking means positioned on or adjacent to the sample to substantially eliminate energy that is specularly reflected off the sample.

2. The apparatus of claim 1, wherein

the means for providing an incident energy beam to the sample includes means for focusing the incident energy beam substantially at a surface of the sample;

and

the means for collecting the energy that is diffusely reflected from the sample includes means for focusing the reflected energy onto a detector means.

3. The apparatus of claim 2, wherein

the incident energy beam contains infrared radiation;

and

the detector is used for obtaining a diffuse reflectance spectrum of the sample.

4. The apparatus of claim 2, wherein the blocking means on or adjacent to the sample does not penetrate the surface of the sample.

5. The apparatus of claim 2, wherein said blocking means is separated from a surface of the sample by a distance that is less than a wavelength of the energy of the incident energy beam.

6. The apparatus of claim 2, wherein said blocking means has a thickness that is not substantially greater than the average penetration of the incident energy beam into the sample.

7. The apparatus of claim 2, wherein said blocking means is a straight-edged object that extends substantially beyond edges of the incident energy beam.

8. The apparatus of claim 2, wherein

said blocking means is generally conical in shape;

and

the means for directing the incident energy beam to the sample is positioned such that the incident energy impinges substantially normal to the sample through an aperture in the blocking means.

9. The apparatus of claim 2, wherein the blocking means is arcuate-shaped to substantially match an outer edge of at least one-half of a shape of the incident energy beam on the surface of the sample.

10. An apparatus responsive to a distribution of energy in a reflectance spectra, comprising

means for directing an incident energy beam to a sample;

means for receiving energy reflected from the sample; and

blocking means positioned on or adjacent to the sample to block out energy specularly reflected off the sample.

11. The apparatus of claim 10, wherein

the means for receiving and responding to energy reflected from the sample includes detector means;

the detector means receives energy containing the reflectance spectra of the sample and the sample specularly reflects energy which produces distortion of the distribution of energy in the reflectance spectra of the sample; and

the blocking means substantially eliminates the distortion in the reflectance spectra received by the detector means by blocking out the energy specularly reflected off the sample.

12. The apparatus of claim 11, wherein

the blocking means is at a distance from the sample such that the specularly reflected energy from the sample is substantially eliminated without also substantially eliminating energy from the sample which is not specularly reflected;

and

the detector means is used in obtaining a diffuse reflectance spectra from at least a portion of the energy not specularly reflected from the sample.

13. The apparatus of claim 11, wherein the substantial elimination of the distortion in the reflectance spectra received by the detector causes at least a portion of the energy in the spectra to vary linearly with a concentration of a composition of matter in the sample producing the absorption feature.

14. The apparatus of claim 11, wherein the substantial elimination of the distortion in the reflectance spectra received by the detector produces a reproducible spectra of the sample that is indicative of a composition of or a concentration of a substance contained in the sample.

15. A method for blocking out specularly reflected energy, comprising

directing energy to a sample;

positioning a blocking element on or adjacent to the sample so that the specularly reflected energy from a surface of the sample is separated from energy diffusely reflected from the sample;

collecting the energy diffusely reflected from the sample.

16. The method of claim 15, wherein

the directing of the energy to the sample comprises focusing a beam of energy onto the surface of the sample;

the positioning of the blocking element includes positioning an edge of the blocking element at a distance from the surface of the sample not substantially greater than a wavelength of the energy;

the collecting of the diffusely reflected energy includes focusing the diffusely reflected energy to a detector.

17. The method of claim 16, wherein the detector is used to obtain a diffuse reflectance spectrum of the sample.

18. The method of claim 17, wherein the energy is at infrared wavelengths.

19. The method of claim 16, wherein the positioning of the blocking element on or adjacent to the surface of the sample does not cause the edge of the blocking element to penetrate into the sample.

20. The method of claim 16, wherein

the positioning of the blocking element is determined by a predetermined positioning of the collecting means;

and

the positioning of the collecting means determines a positioning of the sample.