Fiber reinforced composites and method for their manufacture

• US 4,663,225 A
• Filed: 05/02/1986
• Issued: 05/05/1987
• Est. Priority Date: 05/02/1986
• Status: Expired due to Fees

• Current Assignee: Allied Corp. (Honeywell International Inc.)
• Original Assignee: Allied Corp. (Honeywell International Inc.)
• Inventors: Homonoff, Edward C., Rodman, Clarke A., Vaughn, Edward A., Farley, Radcliffe W.
• Primary Examiner(s): Cannon, James C.
• Application Number:
  US06/858,974
• Time in Patent Office: 368 Days
• Field of Search: 156/221, 156/228, 156/245, 264/119, 264/122, 264/126, 264/257, 264/328.1, 428/35, 428/174, 428/290, 428/296
• US Class Current: 442/71
• CPC Class Codes: B29B 15/12 of reinforcements of indefinite length
• CPC Class Codes: B29C 43/12 using bags surrounding the moulding material or using membranes contacting the moulding material
• CPC Class Codes: B29C 70/443 and impregnating by vacuum or injection
• CPC Class Codes: B29C 70/48 and impregnating the reinforcements in the closed mould, e.g. resin transfer moulding [RTM] , e.g. by vacuum
• CPC Class Codes: B29C 70/502 by first forming a mat composed of short fibres
• CPC Class Codes: B29K 2101/10 Thermosetting resins
• CPC Class Codes: B29K 2101/12 Thermoplastic materials
• CPC Class Codes: B29K 2105/0854 in the form of a non-woven mat
• CPC Class Codes: D04H 1/4209 Inorganic fibres
• CPC Class Codes: D04H 1/5418 Mixed fibres, e.g. at least two chemically different fibres or fibre blends
• CPC Class Codes: D04H 1/64 the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
• CPC Class Codes: D04H 1/732 by fluid current, e.g. air-lay
• CPC Class Codes: Y10T 156/1043 Subsequent to assembly
• CPC Class Codes: Y10T 428/1314 Contains fabric, fiber particle, or filament made of glass, ceramic, or sintered, fused, fired, or calcined metal oxide, or metal carbide or other inorganic compound [e.g., fiber glass, mineral fiber, sand, etc.]
• CPC Class Codes: Y10T 428/1362 Textile, fabric, cloth, or pile containing [e.g., web, net, woven, knitted, mesh, nonwoven, matted, etc.]
• CPC Class Codes: Y10T 428/24628 Nonplanar uniform thickness material
• CPC Class Codes: Y10T 442/2098 At least two coatings or impregnations of different chemical composition
• CPC Class Codes: Y10T 442/2361 Coating or impregnation improves stiffness of the fabric other than specified as a size

Abstract

A fiber reinforced, composite article is manufactured by forming a nonwoven, air-laid batt from a single fiber type or a mixture of fibers. The batt is either resinated with a thermoplastic material or includes a thermoplastic binder fiber. The batt is formed into a preform having the desired shape in a through-air mold and heated sufficiently to set the thermoplastic material, so that the resulting preform retains the desired shape and is sufficiently stiff to withstand the pressure of the injected resin. The preform is then transferred to a resin injection mold, where the interstices between the fibers are saturated with an appropriate resin matrix. As the fibers of the preform are saturated (or after a saturation but before the resin sets) the resin transfer mold is compressed, thereby forming the preform into its final desired thickness and increasing the concentration of the fibers to give the preform appropriate strength. Accordingly, the preform retains the open characteristics permitting easy injection of the resin, while later being compressed to increase the concentration of the reinforcing fibers to give the resulting composite the appropriate strength.

Claims

1. Method of manufacturing fiber reinforced composites comprising the steps of forming a nonwoven batt from structural fibers and a thermoplastic binder material, orienting the fibers as the batt is formed so that a substantial portion of the fibers interlock randomly with other fibers in the mat in each of the three spatial dimensions, molding the batt while heating the batt to a termperature to at least partially melt the binder material to form the batt into a shape-retaining preform of the desired configuration and injecting the preform with a resin matrix to fill the interstices between the fibers.

2. Method of manufacturing fibers reinforced composites as claimed in claim 1, wherein said batt is formed with both said structural fibers and with a thermoplastic binder fiber, said thermoplastic binder fiber being said thermoplastic material added to the batt.

3. Method of manufacturing fiber reinforced composites as claimed in claim 1, wherein the thermoplastic binder material is a thermoplastic compound applied to the batt after the batt is laid.

4. Method of manufacturing fiber reinforced composites as claimed in claim 1, including the step of heating the batt to a lower temperature sufficient to stabilize the batt and permit handling of the batt without tearing the batt apart and then heating the batt to a higher temperature sufficient to at least partially melt the binder material as the batt is formed into said shape-retaining preform.

5. Method of manufacturing fiber reinforced composites as claimed in claim 1, wherein the steps of forming the batt into a shape-retaining preform is effected without substantially compressing the batt.

6. Method of manufacturing fiber reinforced composites as claimed in claim 5, wherein the batt is formed into the shape retaining preform by placing the batt on a gas-permeable member having a desired shape and then drawing gas through the preform and the gas-permeable member to force the batt to assume the contour of the gas-permeable member.

7. Method of manufacturing fiber reinforced composites as claimed in claim 6, wherein the batt is heated as it is formed on said member by heating the gas drawn through the preform.

8. Method of manufacturing fiber reinforced composites as claimed in claim 6, wherein the preform is transferred to a resin injection mold after the preform is molded, the preform being injected with said resin matrix while the preform is disposed in said resin injection mold, said resin injection mold compressing the preform as the fibers of the preform become saturated by said resin matrix to insure the concentration of the structure fibers in the composite and mold the composite into the desired thickness.

9. Method of manufacturing a fiber reinforced composite as claimed in claim 1, wherein the batt is placed in a contour mold to heat the mold sufficiently to at least partially melt the binder material while forming the batt into the shape-retaining preform, and the preform is transferred from the contour mold into a resin injection mold where the preform is injected with the resin matrix.

10. Method of manufacturing fiber reinforced composite as claimed in claim 9, wherein the resin injection mold compresses the preform as the fibers of the preform become saturated by the resin matrix to thereby increase the concentration of the structured fibers in the composite and to mold the composite into the desired thickness.

11. Method of manufacutring a fiber reinforced composite article as claimed in claim 10, wherein said contour mold forms said preform without substantially compressing the batt.

12. Method of manufacturing fiber reinforced composites as claimed in claim 1, wherein said batt is formed by mixing the fibers from which the batt is formed in an air stream, pneumatically conveying said fibers by said air stream to a condenser, and randomly depositing the fibers on the condenser.

13. Method of manufacturing fiber reinforced composites as claimed in claim 12, and further including the step of adjusting the direction of the air stream with respect to the condenser to control the percentage of fibers deposited on the condenser which extend away from the condenser.

14. Method of manufacturing fiber reinforced composites comprising the steps of forming an air-laid nonwoven batt including structural fibers and a thermoplastic binder material, transferring a section of the batt to a preform mold, molding said batt section into a desired preform in the preform mold, transferring the preform to a resin transfer mold, injecting the preform with a resin matrix to fill the interstices between the fibers, and removing the article from the mold after the resin has cured sufficiently to permit handling.

15. Method of manufacturing fiber reinforced composites as claimed in claim 14, wherein said batt section is heated to a temperature sufficient to at least partially melt the binder material while the batt section is disposed in the preform mold.

16. Method of manufacturing fiber reinforced composites as claimed in claim 15, wherein said batt section is molded into said preform without substantial compression of the batt setion.

17. Method of manufacturing fiber reinforced composites as claimed in claim 15, wherein said preform mold includes a gas-permeable member contoured to produce the shape of the preform, said preform being molded by placing the batt section on the gas-permeable member and then drawing gas through the batt section and the gas-permeable member to force the batt section to assume the countour of the gas-permeable member.

18. Method of manufacturing fiber reinforced composites as claimed in claim 17, wherein said batt section is heated by heating the gas drawn through the batt section and the gas-permeable member.

19. Method of manufacturing fiber reinforced composites as claimed in claim 16, wherein said preform is compressed in said resin injection molds the fibers in the preform become saturated with the resin matrix to thereby increase the concentration of the structured fibers in the composite and to mold the composite into the desired thickness.

20. Method of manufacturing fiber reinforced composites as claimed in claim 14, wherein said batt is formed by mixing the fibers from which the batt is formed in an air stream, pneumatically conveying said fibers by said air stream to a condenser, and randomly depositing the fibers on the condenser.

21. Method of manufacturing fiber reinforced composites as claimed in claim 20, further including the step of adjusting the direction of the air stream with respect to the condenser to control the percentages of fibers deposited on the condenser which extend in the direction of the depth of the batt.

22. Fiber reinforced composite acticle comprising a batt of nonwovern structured fibers, said fibers being randomly arranged and interlocked with one another in each of the three spatial dimensions, said batt including a thermoplastic material which has been heated to a temperature sufficient to at least partially melt the thermoplastic material and thus at least partially fuse the staple structural fibers to one another, and a cured resin matrix filling the interstices between the fibers.

23. Fiber reinforced composite article as claimed in claim 22, wherein the batt is a mixture of a first fiber which is relatively inelastic, has relatively low impact strength and a second fiber which has high impact strength.

24. Fiber reinforced composite article as claimed in claim 23, wherein the first fiber is fiberglass.

25. Fiber reinforced composite article as claimed in claim 22, wherein the batt is a mixture of a first fiber which is relatively inelastic but has a relatively low strength, a second fiber which has high impact strength, and a third binder fiber which has a melting point substantially lower than the melting point of the first and second fibers.

26. Fiber reinforced composite article as claimed in claim 22, wherein said batt is a mixture of at least two different types of fibers having different elasticities and impact strength.

27. Fiber reinforced composite article as claimed in claim 22, wherein the article has a greater concentration of fibers than did the batt from which the article was made.

28. Fiber reinforced composite article as claimed in claim 22, wherein said article is molded and has a predetermined concentration of fibers and a predetermined thickness.