Flame-sprayed ferrous alloy enhanced boiling surface

• US 4,663,243 A
• Filed: 10/28/1982
• Issued: 05/05/1987
• Est. Priority Date: 10/28/1982
• Status: Expired due to Fees

• Current Assignee: UOP Des Plaines IL A NY General Partnership
• Original Assignee: Union Carbide Corporation (Dow, Inc.)
• Inventors: Kern, James W., Czikk, Alfred M.
• Primary Examiner(s): BECK, SHRIVE
• Application Number:
  US06/437,122
• Time in Patent Office: 1,650 Days
• Field of Search: 165/133, 427/423, 428/557, 428/553, 428/559, 428/937
• US Class Current: 428/559
• CPC Class Codes: C23C 4/02 Pretreatment of the material to be coated, e.g. for coating on selected surface areas
• CPC Class Codes: C23C 4/123 Spraying molten metal
• CPC Class Codes: C23C 4/129 Flame spraying
• CPC Class Codes: F28F 13/187 especially adapted for evaporator surfaces or condenser surfaces, e.g. with nucleation sites
• CPC Class Codes: Y10S 428/937 Sprayed metal
• CPC Class Codes: Y10T 428/12063 Nonparticulate metal component
• CPC Class Codes: Y10T 428/12104 Particles discontinuous

Abstract

A porous boiling surface and method of making, which surface comprises a flame-sprayed matrix of ferrous alloy powder on a metal substrate, the matrix being characterized by having irregularly spaced, angled macropores which extend partly through the thickness of the matrix and which improve the boiling perfrmance of the surface.

Claims

1. A method of depositing on a metal substrate a porous ferrous alloy boiling surface having macropores therein to enhance boiling which method comprises the steps of:

(a) aligning an oxy-fuel spray gun in relationship to said substrate such that the centerline distance between the nozzle of said spray gun and said substrate is from about 4 inches (10.2 cm) to about 6 inches (15.2 cm) and said spray gun is inclined so that the angle of flame spraying is from about 30°

to about 50°

;

(b) entraining ferrous alloy powder in an inert gas stream;

(c) injecting said inert gas stream into a reducing oxy-fuel flame which is dispensed from the nozzle of said spray gun; and

(d) providing relative movement between said oxy-fuel flame and said substrate so as to apply at least one layer of ferrous alloy powder onto said substrate.

2. The method of forming a porous boiling surface in accordance with claim 1 wherein prior to step (a) a base layer is deposited on said substrate by means of a thermal spray gun.

3. The method of forming a porous boiling surface in accordance with claim 1 wherein said reducing oxy-fuel flame is produced by a reactive gas mixture having an oxidizing-to-fuel gas mole ratio of less than about seventy-five percent of the stoichiometric ratio.

4. The method of forming a porous boiling surface in accordance with claim 1 wherein said fuel is acteylene and said inert gas in nitrogen.

5. An enhanced boiling surface comprising a metal substrate and a flame-sprayed matrix of ferrous alloy particles thereon, said matrix having nucleate boiling sites therein and further characterized by having randomly disposed, irregularly shaped macropores therein which extend inwardly from the outer surface of the matrix to a depth equal to at least one-third the thickness of the matrix and which macropores have axial centerlines with approximately the same orientation one with the other and which interesect the substrate surface at an acute angle, which macropores enhance boiling by providing improved access of liquid to and vapor from the nucleate boiling sites throughout the matrix, said ferrous alloy particles being flame-sprayed in a gas stream comprising a reducing environment.

6. The porous boiling surface in accordance with claim 5 wherein said macropores occur longitudinally at a rate of from about 20 to about 200 macropores per linear centimeter.

7. The porous boiling surface in accordance with claim 5 wherein said angle at which the centerline of said macropores is inclined toward such substrate is from about 40°

to about 60°

.

8. The porous boiling surface in accordance with claim 5 wherein the width of said macropores is from about 0.001 inch (0.003 cm) to about 0.007 inch (0.018 cm) and the thickness of said ferrous alloy matrix is from about 0.003 inch (0.01 cm) to about 0.030 inch (0.08 cm).

9. The porous boiling surface in accordance with claim 5 wherein the major void fraction of said ferrous alloy matrix is from about 0.10 to about 0.60 and the minor void fraction is from between 0.10 and about 0.40 of the total volume of said ferrous alloy matrix.

10. The porous boiling surface in accordance with claim 5 in which said matrix comprises ferrous alloy particles flame-sprayed in powder form.