Polyesteramide

• US 4,663,428 A
• Filed: 08/20/1985
• Issued: 05/05/1987
• Est. Priority Date: 12/27/1983
• Status: Expired due to Fees

• Current Assignee: Daicel Chemical Industries Limited (Daicel Corporation)
• Original Assignee: Daicel Chemical Industries Limited (Daicel Corporation)
• Inventors: Watanabe, Shiogi, Okitu, Kiyoshi
• Primary Examiner(s): Phynes, Lucille M.
• Application Number:
  US06/772,599
• Time in Patent Office: 623 Days
• Field of Search: 528/292, 528/302, 528/324, 528/326
• US Class Current: 528/324
• CPC Class Codes: C08G 69/44 Polyester-amides

Abstract

A polyesteramide is prepared by reacting

(1) at least one polyamide-forming compound selected from the group consisting of amino carboxylic acids having 6 to 12 carbon atoms, lactams having 6 to 12 carbon atoms and nylon salts comprising dicarboxylic acids having 4 to 12 carbon atoms and diamines having 4 to 12 carbon atoms,

(2) a dicarboxylic acid having 4 to 54 carbon atoms, and

(3) a polycaprolactonediol having an average molecular weight of 200 to 2,500 or 4,500 to 10,000; and is good at heat stability.

Claims

1. A polyesteramide obtained by reacting

(1) at least one polyamide-forming compound selected from the group consisting of aminocarboxylic acids having from 6 to 12 carbon atoms, lactams having from 6 to 12 carbon atoms and nylon salts prepared by reacting a dicarboxylic acid having from 4 to 12 carbon atoms with a diamine having 4 to 12 carbon atoms;

(2) a dicarboxylic acid having from 4 to 54 carbon atoms, and

(3) a reactant selected from the group consisting of

(a) polycaprolactonediols having an average molecular weight of from 200 to 2,500,

(b) polycaprolactonediols having an average molecular weight of from 4,500 to 10,000, and

(c) a mixture of from 70 to 99.9 wt. % of a polycaprolactonediol having an average molecular weight of from 200 to 10,000, and 0.1 to 30 wt. % of a polycaprolactone polyol having an average molecular weight of from 200 to 10,000 and having at least three functional groups in the molecule,

under esterification and polycondensation reaction conditions effective to produce the polyesteramide and wherein during the polycondensation reaction, the amounts of carboxyl groups, amino groups and hydroxyl groups supplied by (1), (2) and (3) satisfy the reaction ##EQU2##

2. A polyesteramide as claimed in claim 1 which has been prepared by polycondensation of (1) and (2) and (3).

3. A polyesteramide as claimed in claim 1 which has been prepared by reacting (1) and (2) to form a dicarboxylic acid polyamide and then polycondensing same with (3).

4. A polyesteramide as claimed in claim 1 which has been prepared by reacting (1) and (2) to form a dicarboxylic acid polyamide and then effecting ring-opening polycondensation of said dicarboxylic acid polyamide with ε

-caprolactone and an initiator.

5. A polyesteramide as claimed in claim 1 which has been prepared by effecting ring-opening polycondensation reaction of (1), (2), ε

-caprolactone and an initiator.

6. A polyesteramide as claimed in claim 1 in which said aminocarboxylic acid is selected from the group consisting of 6-aminocaproic acid, 11-aminoundeconoic acid and 12-aminododecanoic acid, said lactam is selected from the group consisting of caprolactam and lauryllactam and said nylon salt is selected from the group consisting of the salt of adipic acid with hexamethylenediamine, the salt of sebacic acid with hexamethylenediamine, the salt of isophthalic acid with hexamethylenediamine and the salt of terephthalic acid with trimethylhexamethylenediamine.

7. A polyesteramide as claimed in claim 6 in which said dicarboxylic acid is selected from the group consisting of terephthalic acid, isophthalic acid, 1,4-cyclohexanedicarboxylic acid, adipic acid, sebacic acid, dodecanedioic acid and dimer acid.

8. A polyesteramide as claimed in claim 1 in which said reactant (3) is (a).

9. A polyesteramide as claimed in claim 1 in which said reactant (3) is (b).

10. A polyesteramide as claimed in claim 1 in which said reactant (3) is (c).