Hydrocarbon conversion process using a molten salt

• US 4,665,261 A
• Filed: 06/21/1985
• Issued: 05/12/1987
• Est. Priority Date: 06/21/1985
• Status: Expired due to Fees

• Current Assignee: Atlantic Richfield Company
• Original Assignee: Atlantic Richfield Company Incorporated (BP PLC)
• Inventors: Mazurek, Harry
• Primary Examiner(s): NOT, DEFINED
• Assistant Examiner(s): Prezlock, Cynthia A.
• Application Number:
  US06/747,548
• Time in Patent Office: 690 Days
• Field of Search: 585/500, 585/943, 585/654, 585/656, 585/658, 585/661, 585/541, 585/700, 585/415, 585/417, 585/418, 423/DIG. 12
• US Class Current: 585/500
• CPC Class Codes: C07C 2/82 oxidative coupling
• CPC Class Codes: C07C 2/84 catalytic
• CPC Class Codes: C07C 2521/06 Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
• CPC Class Codes: C07C 2523/00 Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 C07C2521/16 takes precedence
• CPC Class Codes: C07C 2523/04 Alkali metals
• CPC Class Codes: C07C 2523/08 of gallium, indium or thallium
• CPC Class Codes: C07C 2523/14 of germanium, tin or lead
• CPC Class Codes: C07C 2523/18 Arsenic, antimony or bismuth
• CPC Class Codes: C07C 2523/34 Manganese
• CPC Class Codes: Y10S 585/943 Synthesis from methane or inorganic carbon source, e.g. coal

Abstract

A process for converting low molecular weight gases such as methane and natural gas to higher hydrocarbons by means of a molten salt containing a synthesizing contact agent. The gas is contacted with a molten salt containing a metal, the oxide of which is reduced when contacted with methane at a temperature in the range of 500° to 1000° C. to produce higher hydrocarbons and water. The reduced metal oxide/salt mixture may be regenerated to the active state by contacting the molten salt mixture with an oxygen-containing gas.

Claims

1. A method for conversion of methane to higher hydrocarbons which comprises contacting a hydrocarbon gas comprising methane with a mixture comprising molten salt and at least one reducible metal oxide contact agent at a selected temperature within the range of about 500°

to about 1000°

C. to produce higher hydrocarbons and water.

2. The method of claim 1 wherein said mixture comprises additionally a support comprising at least one member of a group consisting of oxides of silicon, oxides of alkaline earth metals, and mixed oxides of silicon and at least one alkaline earth metal.

3. The method of claim 1 wherein said contact agent is selected from a group consisting of oxides of maganese, tin, indium, germanium, antimony, lead, bismuth, and mixtures thereof.

4. The method of claim 1 comprising additionally at least one alkali metal.

5. The method of claim 2 wherein said support comprises at least two oxides.

6. The method of claim 5 wherein said support comprises magnesia and silica.

7. The method of claim 2 wherein said support comprises magnesia.

8. The method of claim 2 wherein said support comprises silicon oxide.

9. The method of claim 3 wherein said contact agent comprises manganese oxide.

10. The method of claim 9 wherein the contact agent additionally comprises an alkali metal.

11. The method of claim 1 wherein said molten salt comprises an alkali or alkaline earth metal salt selected from a group consisting of halides, phosphates, borates, carbonates, sulfates, tungsten oxides, silicates, molybdenum oxides, and mixtures thereof.

12. The method of claim 10 wherein said metal oxide is dissolved in said molten salt.

13. The method of claim 1 wherein said mixture contains an inert gas dispersing agent.