Silicone coated fabric

• US 4,666,765 A
• Filed: 10/02/1985
• Issued: 05/19/1987
• Est. Priority Date: 10/02/1985
• Status: Expired due to Term

• Current Assignee: Nextec Applications Incorporated
• Original Assignee: Sili-Tex Incorporated
• Inventors: Caldwell, James M., Lubitz, Michael R., Ruston, Eric J.
• Primary Examiner(s): Lusignan, Michael R.
• Application Number:
  US06/782,962
• Time in Patent Office: 594 Days
• Field of Search: 427/358, 427/407.3, 427/381, 427/387, 428/429, 428/447, 428/448, 428/266, 428/268
• US Class Current: 442/85
• CPC Class Codes: D06N 3/128 with silicon polymers
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane
• CPC Class Codes: Y10T 442/2213 Coating or impregnation is specified as weather proof, water vapor resistant, or moisture resistant
• CPC Class Codes: Y10T 442/2631 Coating or impregnation provides heat or fire protection

Abstract

The present invention is directed to method for making silconecoated woven fabric substrates, and the products produced by such method. The method comprises the steps of applying a first liquid polysilicane elastomer to the substrate so as to form a base coat, curing the base coat, applying a second liquid polysilicane elastomer over the base coat so as to form a top coat, and curing the top coat. By specifically selecting the polysilicane elastomers as well as the substrate, and by further selecting the reaction parameters, a high strength, non-flammable, waterproof, self-cleaning, translucent and weather-resistant fabric is produced.

Claims

1. A method for making a translucent, weather-resistant, fire-retardant, silcone coated woven fabric substrate comprising the steps of:

(a) applying a high tear strength composition comprising a first translucent silicone liquid elastomer and aluminum hydroxide, to a clean, woven, translucent substrate;

(b) allowing the first silicone liquid elastomer to penetrate the substrate and thereby form a translucent base coating on the translucent substrate;

(c) passing the translucent base coated substrate through first fashioning means for controlling the thickness of the base coating;

(d) allowing the base coating to cure;

(e) applying a second translucent silicone liquid elastomer to the cured translucent base coated substrate thereby forming a translucent top coating, said second silicone liquid elastomer being applied at a temperature of less than about 150°

F.;

(f) passing the top coated substrate resulting from step (e) through second fashioning means for controlling the thickness of the top coating; and

(g) curing the top coating, whereby, a translucent, fire retardant, woven fabric substrate is produced.

2. The method of claim 1 wherein the base coating formed in step (c) has a thickness of about 3-10 mils thicker than the substrate.

3. The method of claim 2 wherein the top coating formed in step (f) has a thickness of about 1.5 mils.

4. The method of claim 1 wherein the base coating is produced by immersing the substrate into a formulation comprising, by weight:

(1) about 100 parts of a liquid vinyl chain-stopped polysiloxane having the formula;

##STR2## where R and R'"'"' are monovalent hydrocarbon radicals free of aliphatic unsaturation, with at least 50 mole percent of the R'"'"' groups being methyl and where n has a value sufficient to provide a viscosity of from about 50,000 to 750,000 centistrokes at 25°

C.;

(2) from about 20 to about 50 parts of an organopolysiloxane copolymer comprising trimethylsiloxane units, methylvinylsiloxane units, and SiO₂ units and where from about 2.5 to 10 mole percent of the silicon atoms contain silicon bonded vinyl groups and where the ratio of trimethylsiloxane units to the SiO₂ units is between 0.5;

1 and 1;

1,

(3) a platinum-containing catalyst;

(4) an amount of a liquid organohydrogenpolysiloxane having the formula;

space="preserve" listing-type="equation">(R).sub.b (H).sub.c SiO.sub.4-b-c/2

sufficient to provide from about 0.5 to 1.0 silicon-bonded hydrogen atoms per silicon-bonded vinyl group in the compositions, where b has a value of from 1.00 to 2.1, c has a value of from about 0.1 to 1.0, and the sum of b and c is from about 2.00 to 2.67, there being at least two silicon-bonded hydrogen atoms per molecule;

(5) from about 0.3 to 100 parts per weight of finely divided aluminum hydroxide per 100 parts of the base coating ingredients 1-4 above inclusive;

and the top coating is produced by immersing the base coated substrate into a formulation comprising;

(1) a liquid vinyl chain-stopped polysiloxane having the formula where m has a value sufficient to provide a viscosity up to about 1,000 centipose at 25°

C.;

(2) a resinous organopolysiloxane copolymer comprising;

(i) (R²)₃ SiO₀.5 units and SiO₂ units,

(ii) (R²)₃ SiO₀.5 units, (R³)₂ SiO₂ units and SiO₂ units, or

(iii) mixtures thereof, where R² and R³ are selected from the group consisting of vinyl radicals and monovalent hydrocarbon radicals and monovalent hydrocarbon radicals free of aliphatic unsaturation, where from about 1.5 to about 10 mole percent of the silicone atoms contain silicon-bonded vinyl groups, where the ratio of monofunctional units to tetrafunctional units is from about 0.5;

1 to about 1;

1, and the ratios of difunctional units to tetrafunctional units ranges up to about 0.1;

1;

(3) a platinum-containing catalyst;

(4) a liquid organohydrogenpolysiloxane having the formula;

space="preserve" listing-type="equation">(R.sup.4).sub.d (H).sub.e SiO.sub.4-d-e/2

sufficient to provide from about 0.5 to about 1.0 silicon-bonded hydrogen atoms per silicon-bonded vinyl group, R⁴ is a monovalent hydrocarbon radical free to aliphatic unsaturation, "d" has a value of from about 1.0 to about 2.1, "e" has a value of from about 0.1 to about 1.0, and the sum of "d" and "e" is from about 2.0 to about 2.7, there being at least two silicon-bonded hydrogen atoms per molecule; and

(5) from 0 to 200 parts by weight solvent per 100 parts of the top coating ingredients 1-4 above, inclusive.

5. The method of claim 1 wherein said base coat is cured in step (d) at a temperature of about 400°

F. and is then cooled to a temperature of below about 100°

F. in step (e).

6. The method of claim 4 wherein said base coating is applied as a bath and the ingredients (1), (2) and (4) of the base coating are mixed together prior to the addition of the catalyst (3).

7. A product produced according to the method of claim 1.

8. A product produced according to the method of claim 4.

9. A product produced according to claim 4 wherein the platinum-containing catalyst is a platinumolefinic hydrocarbon complex obtained from the reaction of a platinum halide and an olefinic hydrocarbon selected from the group consisting of styrene and ring substitued styrenes in the presence of a basic material.

10. A method for making a translucent, weather-resistant, fire retardant, silcone coated architectural fabric substrate comprising the steps of:

(a) applying a coating composition comprising a first translucent liquid polysiloxane elastomer and aluminum hydroxide, to a translucent silane-treated woven glass substrate so as to form a translucent base coating of about 3-10 mils in thickness;

(b) curing said base coating;

(c) applying a second translucent liquid polysiloxane elastomer, which is resistant to dirt pickup, at a temperature of about 50°

F. to about 100°

F. over said translucent base coating so as to form a translucent top coating; and

(d) curing said translucent top coating.

11. The method of claim 10 wherein said substrate is a woven glass cloth which has been cleaned prior to applying the silane finish.

12. The method of claim 10 where said first polysiloxane is produced by immersing the substrate into a formulation comprising, by weight:

(1) about 100 parts of a liquid vinyl chain-stopped polysiloxane having the formula;

##STR3## where R and R'"'"' are monovalent hydrocarbon radicals free of aliphatic unsaturation, with at least 50 mole percent of the R'"'"' groups being methyl and where n has a value sufficient to provide a viscosity of from about 50,000 to 750,000 centistrokes at 25°

C.,

(2) from about 20 to about 50 parts of an organopolysiloxane copolymer comprising trimethylsiloxane units, methylvinylsiloxane units, and SiO₂ units and where from about 2.5 to 10 mole percent of the silicon atoms contain silicon bonded vinyl groups and where the ratio of trimethylsiloxane units to the SiO₂ units is between 0.5;

1 and 1;

1;

(3) a platinum-containing catalyst; and

(4) an amount of a liquid organohydrogenpolysiloxane having the formula;

space="preserve" listing-type="equation">(R).sub.b (H).sub.c SiO.sub.4-b-c/2

sufficient to provide from about 0.5 to 1.0 silicon-bonded hydrogen atoms per silicon-bonded vinyl group in the compositions, where b has a value of from 1.00 to 2.1, c has a value of from about 0.1 to 1.0, and the sum of b and c is from about 2.00 to 2.67, there being at least two silicon-bonded hydrogen atoms per molecule;

(5) from about 0.3 to 100 parts per weight of finely divided aluminum hydroxide per 100 parts of the base coating ingredients 1-4 above inclusive;

and the top coating is produced by immersing the base coated substrate into a formulation comprising;

(1) a liquid vinyl chain-stopped polysiloxane having the formula where m has a value sufficient to provide a viscosity up to about 1,000 centipose at 25°

C.,

(2) a resinous organopolysiloxane copolymer comprising;

(i) (R²) ₃ SiO₀.5 units and SiO₂ units,

(ii) (R²)₃ SiO₀.5 units, (R³)₂ SiO₂ units and SiO₂ units, or

(iii) mixtures thereof, where R² and R³ are selected from the group consisting of vinyl radicals and monovalent hydrocarbon radicals and monovalent hydrocarbon radicals free of aliphatic unsaturation, where from about 1.5 to about 10 mole percent of the silicone atoms contain silicon-bonded vinyl groups, where the ratio of monofunctional units to tetrafunctional units is from about 0.5;

1 to about 1;

1, and the ratios of difunctional units to tetrafunctional units ranges up to about 0.1;

1;

(3) a platinum-containing catalyst, and

(4) a liquid organohydrogenpolysiloxane having the formula;

space="preserve" listing-type="equation">(R.sup.4).sub.d (H).sub.e SiO.sub.4-d-e/2

sufficient to provide from about 0.5 to about 1.0 silicon-bonded hydrogen atoms per silicon-bonded vinyl group, R⁴ is a monovalent hydrocarbon radical free to aliphatic unsaturation, "d" has a value of from about 1.0 to about 2.1, "e" has a value of from about 0.1 to about 1.0, and the sum of "d" and "e" is from about 2.0 to about 2.7, there being at least two silicon-bonded hydrogen atoms per molecule.

13. The method of claim 12 wherein said base coating is applied as a bath and the ingredients (1) (2) and (3) of the base coating are mixed together prior to the addition of the organohydrogen polysiloxane (4).

14. The method of claim 12 when said second liquid polysiloxane is applied at a temperature of about 50°

F.

15. A product produced by the method of claim 11.

16. A product produced by the method of claim 14.