Extruded copper chromite-alumina hydrogenation catalyst

• US 4,666,879 A
• Filed: 09/11/1985
• Issued: 05/19/1987
• Est. Priority Date: 09/11/1985
• Status: Expired due to Term

• Current Assignee: The Harshaw Chemical Company
• Original Assignee: Harshaw/Filtrol Partnership
• Inventors: Kelly, Donald G., Nebesh, Eugene
• Primary Examiner(s): Shine, W. J.
• Application Number:
  US06/774,830
• Time in Patent Office: 615 Days
• Field of Search: 502/306, 502/318, 502/244
• US Class Current: 502/244
• CPC Class Codes: B01J 23/868 copper and chromium
• CPC Class Codes: B01J 35/31 Density
• CPC Class Codes: B01J 35/613 10-100 m2/g
• CPC Class Codes: B01J 35/615 100-500 m2/g
• CPC Class Codes: B01J 37/0009 Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
• CPC Class Codes: C07C 2601/14 The ring being saturated
• CPC Class Codes: C07C 29/141 with hydrogen or hydrogen-containing gases
• CPC Class Codes: C07C 31/12 containing four carbon atoms
• CPC Class Codes: C07C 31/125 containing five to twenty-two carbon atoms
• CPC Class Codes: C07C 31/276 with a six-membered ring

Abstract

An extruded copper chromite-alumina catalyst is prepared by blending together from 40-82% by weight of copper chromite and 18-60% of an extrudable alumina, typically having a pseudoboehmite or α hydroxy boehmite structure. The extruded catalyst after calcining is useful for the liquid and vapor phase hydrogenation and hydrogenolysis of various carbonyl compounds and the functional side groups of aromatic compounds.

The extruded catalyst is characterized as having a surface area of between 20 and 225 square meters per gram and a packed apparent bulk density of between about 0.70 and about 1.20 g/cc.

Claims

1. An extruded copper chromite/alumina catalyst prepared from a blend of between about 40% and about 82% by weight of copper chromite having the formula CuO:

CuCr₂ O₄ and between about 60% and about 18% by weight of an extrudable form of alumina wherein portions or all of the copper oxide and copper chromite are present in the reduced state, said catalyst having a surface area between about 20 m² /g and about 225 m² /g, and a packed apparent bulk density of between about 0.70 and about 1.20 g/cc.

2. The catalyst of claim 1 wherein at least 25% of the extruded alumina is selected from the group consisting of pseudoboehmite and α

hydroxy boehmite.

3. The catalyst of claim 2 wherein the copper chromite is present in an amount of between 60% and 80% and the alumina is present in an amount of between 40% and 20%.

4. The catalyst of claim 3 in which all of the alumina, before calcination, has a pseudoboehmite structure.

5. The catalyst of claim 4 wherein the copper chromite is present in an amount of between about 68% and 72% and the alumina is present in an amount of between 32% and 28%.

6. The catalyst of claim 5 including up to 10% by weight of a stabilizer selected from the group consisting of barium and manganese.

7. The catalyst of claim 1 wherein the reduced copper is stabilized.

8. The catalyst of claim 1 wherein up to 15% of the alumina is replaced by silica.

9. A method of preparing an extruded copper chromite/alumina catalyst comprising:

(a) blending from between about 18% to about 60% by weight alumina capable of being readily extruded, with between about 82% and about 40% by weight of copper chromite, between about 3% and about 7% by weight, based on alumina of a peptizing agent, and sufficient water to give an extrudable mix,

(b) extruding the mix, and

(c) calcining and reducing the extrudate.

10. The method of claim 9 wherein at least 25% of the alumina has a structure selected from the group consisting of a pseudoboehmite structure and an α

hydroxy boehmite structure.

11. The method of claim 9 wherein the catalyst contains up to 10% of a reduction stabilizer consisting of a salt of a metal selected from the group consisting of barium and manganese.

12. The method of claim 9 wherein water is added to step (a) in an amount which will give a loss on ignition of between about 37% and about 39% during calcination.

13. The method of claim 9 wherein the calcined catalyst is reduced following calcination.

14. The method of claim 13 wherein the reduced catalyst is air stabilized.

15. The method of claim 9 wherein the peptizing agent is a mineral acid.

16. The method of claim 9 wherein the peptizing agent is an organic acid.