Absorbent article

• US 4,666,983 A
• Filed: 04/19/1983
• Issued: 05/19/1987
• Est. Priority Date: 04/19/1982
• Status: Expired due to Term

• Current Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
• Original Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.
• Inventors: Irie, Yoshio, Shimomura, Tadao, Tsubakimoto, Tsuneo
• Primary Examiner(s): Schofer, Joseph L.
• Assistant Examiner(s): Lipman, Bernard
• Application Number:
  US06/486,318
• Time in Patent Office: 1,491 Days
• Field of Search: 525/329.7, 525/329.9, 525/119, 525/123, 527/314
• US Class Current: 525/119
• CPC Class Codes: A61L 15/60 Liquid-swellable gel-forming materials, e.g. super-absorbents
• CPC Class Codes: B01J 20/26 Synthetic macromolecular compounds
• CPC Class Codes: C08F 220/06 Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
• CPC Class Codes: C08F 8/00 Chemical modification by after-treatment graft polymers, block polymers, crosslinking with unsaturated monomers or with polymers C08F251/00 - C08F299/00; of conjugated diene rubbers C08C
• CPC Class Codes: C09K 3/32 for absorbing liquids to remove pollution, e.g. oil, gasoline, fat

Abstract

An absorbent article obtained by mixing 100 parts by weight of an absorbent resin powder having a carboxyl group with 0.001 to 10 parts by weight of a crosslinking agent having at least two functional groups capable of reacting with the carboxyl group per molecule and reacting the absorbent resin powder with the crosslinking agent to crosslink the molecular chains existing at least in the vicinity of the surface of the absorbent resin powder.

Claims

1. An absorbent article obtained by mixing 100 parts by weight of a powder of an absorbent resin having a carboxyl group selected from the group consisting of hydrolyzate of starch/acrylonitrile graft copolymer;

partial neutralization product of starch/acrylic acid graft copolymer;

saponification product of vinyl acetate/acrylic ester copolymer;

hydrolyzate of acrylonitrile copolymers;

hydrolyzate of acrylamide copolymer;

crosslinked product of any of the foregoing copolymers;

partial neutralization product of polyacrylic acid; and

crosslinked partial neutralization product of polyacrylic acid;

with 0.001 to 10 parts by weight of a crosslinking agent having at least two functional groups capable of reacting with the carboxyl group per molecule and reacting the absorbent resin powder with the crosslinking agent to crosslink the molecular chains existing at least in the vicinity of the surface of the absorbent resin powder.

3. The absorbent article of claim 1 wherein the absorbent resin powder contains at least 70% by weight of particles which pass through a 60-mesh sieve.

4. The absorbent article of claim 1 wherein the crosslinking agent is a polyhydric alcohol compound.

5. The absorbent article of claim 4 which is obtained by reacting the absorbent resin powder with the polyhydric alcohol compound at 90°

to 300°

C.

6. The absorbent article of claim 1 wherein the crosslinking agent is a polyglycidyl ether compound.

7. The absorbent article of claim 6 which is obtained by reacting the absorbent resin powder with the polyglycidyl ether compound at 50°

to 300°

C.

8. The absorbent article of claim 1 wherein the crosslinking agent is a polyfunctional aziridine compound.

9. The absorbent article of claim 8 which is obtained by reacting the absorbent resin powder with the polyfunctional aziridine compound at 10°

to 300°

C.

10. The absorbent article of claim 1 wherein the crosslinking agent is a polyfunctional amine compound.

11. The absorbent article of claim 10 which is obtained by reacting the absorbent resin powder with the polyfunctional amine compound at 90°

to 300°

C.

12. The absorbent article of claim 1 wherein the crosslinking agent is a polyfunctional isocyanate compound.

13. The absorbent article of claim 12 which is obtained by reacting the absorbent resin powder with the polyfunctional isocyanate compound at 10°

to 300°

C.

23. The absorbent article of claim 1 wherein the absorbent resin is obtained by dispersing an aqueous solution of acrylic acid, an alkali metal acrylate containing a water-soluble radical, or mixtures thereof, and containing a water-soluble radical polymerization initiator in a hydrocarbon solvent selected from the group consisting of alicyclic hydrocarbon, aliphatic hydrocarbon, and mixtures thereof, in the presence of a surface-active agent having a hydrophile-lipophile (HLB) balance of 3 to 12, and subjecting the mixture to suspension polymerization.

24. The absorbent article of claim 1 wherein the absorbent resin is a saponification product of a copolymer of a vinyl ester and an ethylenically unsaturated carboxylic acid or derivative thereof.

25. The absorbent article of claim 1 wherein the absorbent resin is a polymer obtained by polymerizing starch, cellulose, or a mixture thereof in an aqueous medium with a monomer having a carboxyl group or a monomer capable of forming a carboxyl group upon hydrolysis and a crosslinking monomer or the hydrolyzate of said polymer.

26. The absorbent article of claim 1 wherein the absorbent resin is the reaction product of an alkaline substance with a maleic anhydride-type copolymer composed of maleic anhydride and at least one monomer selected from the group consisting of alpha-olefins and vinyl compounds or the reaction product thereof with a polyepoxy compound.

2. An absorbent article obtained by mixing 100 parts by weight of a powder of an absorbent resin having a carboxyl group with 0.001 to 10 parts by weight of a crosslinking agent having at least two functional groups capable of reacting with the carboxyl groups per molecule and reacting the absorbent resin powder with the crosslinking agent to crosslink the molecular chains existing at least in the vicinity of the surface of the absorbent resin powder;

wherein the absorbent resin having a carboxyl group is an alkali metal acrylate-type polymer obtained by copolymerizing 100 parts by weight of an acrylic acid salt-type monomer composed of 1 to 50 mole% of acrylic acid and 50 to 99 mole% of an alkali metal acrylate and 0 to 5 parts by weight of a crosslinkable monomer in aqueous solution in a monomer concentration of at least 20% by weight, and drying the resulting gel-like hydrous polymer under heat.

14. The absorbent article of claim 2 wherein the crosslinking agent is a compound selected from the group consisting of glycerol, polyethylene glycol, triethanolamine, sorbitan monolaurate, polyoxyethylene sorbitan monostearate, trimethylol propane, and sorbitol.

15. The absorbent article of claim 14 wherein the amount of the crosslinking agent is about 0.3 part by weight per 100 parts by weight of the absorbent resin powder.

16. The absorbent article of claim 2 wherein the crosslinking agent is selected from the group consisting of 2,2-bishydroxymethylbutanol-tris[3-(1-aziridinyl)propionate], ethylene glycol diglycidyl ether, 2,4-tolylene diisocyanate and triethylene tetraamine.

17. The absorbent article of claim 2 wherein the absorbent resin powder is crosslinked with 0.05 part by weight, per 100 parts of the absorbent resin powder of 2,2-bishydroxymethylbutanol-tri[3-(1-aziridinyl)propionate] or ethylene glycol diglycidyl ether.

18. The absorbent article of claim 2 wherein the absorbent resin powder is crosslinked with 1 part by weight, per 100 parts by weight of the absorbent resin powder, of 2,4-tolylene diisocyanate or triethylene tetraamine.

19. An absorbent article which is a reaction product of 100 parts by weight of a powder of an absorbent resin which is a saponified copolymer of vinyl acetate and methylacrylate with 0.001 to 10 parts by weight of a crosslinking agent which is trimethylol propane wherein at least the molecular chains existing at least in the vicinity of the surface of the absorbent resin powder are crosslinked.

21. The absorbent article of claim 19 wherein 1 part of the crosslinking agent is used per 100 parts of the absorbent resin powder.

20. An absorbent article which is a reaction product of 100 parts by weight of a powder of an absorbent resin which is a crosslinked copolymer of isobutylene and maleic anhydride with 0.001 to 10 parts by weight of a crosslinking agent which is polyethylene glycol wherein at least the molecular chains existing at least in the vicinity of the surface of the absorbent resin powder are crosslinked.

22. The absorbent article of claim 20 wherein the crosslinking agent is used in an amount of 0.5 part per 100 parts by weight of the absorbent resin powder.