Thermal conversion of wastes

• US 4,668,435 A
• Filed: 03/20/1984
• Issued: 05/26/1987
• Est. Priority Date: 12/20/1982
• Status: Expired due to Term

• Current Assignee: Rockwell International Corporation
• Original Assignee: Rockwell International Corporation
• Inventors: Grantham, LeRoy F.
• Primary Examiner(s): Terapane, John F.
• Assistant Examiner(s): Caress, Virginia B.
• Application Number:
  US06/591,778
• Time in Patent Office: 1,162 Days
• Field of Search: 252/631, 252/632, 252/626, 110/237, 110/238, 110/342, 110/343, 110/346, 110/348, 159/4.01, 159/4.02, 159/48.1, 159/DIG. 12, 34/10, 34/57 R
• US Class Current: 588/19
• CPC Class Codes: G21F 9/14 by incineration; by calcination, e.g. desiccation
• CPC Class Codes: G21F 9/32 by incineration

Abstract

Wastes, in the form of liquids, solids and slurries, are converted to a mixture of a gas and an inorganic ash by introducing the waste as a finely atomized spray into a zone heated by means of a hot gas. Contact of the spray particles with the hot gas results in drying the waste and calcining and combusting the dried waste. The process is particularly useful with wastes containing hazardous materials such as radioactive substances.

Claims

1. A process for the thermal conversion of a radioactive waste material which comprises the sequential steps of:

introducing said radioactive waste material in the form of a finely atomized spray into the top of a spray dryer zone heated, by means of a hot gas produced externally of said zone on combustion of a fuel and air and introduced into the top of said zone, to a temperature of about 500°

to 1000°

C. to convert said radioactive waste material, by contact with said hot gas, into a mixture of products including a non-radioactive gas comprising gaseous H₂ O, CO₂ and nitrogen and a radioactive inorganic ash;

removing said mixture of products from the bottom of said zone, and

separating said radioactive inorganic ash from said mixture of products, the ratio of the volume of said radioactive waste material to the volume of said ash being in the range of about 7;

1 to 70;

1.

2. A process according to claim 1 wherein said waste contains sodium nitrate and the nitrate content of said radioactive ash is reduced by at least about 98% from the nitrate content of said waste.

3. A process according to claim 1 wherein said zone is heated to a temperature in the range of about 600°

to 850°

C.

4. A process according to claim 1 wherein the temperature within said zone is not permitted to fall below about 600°

C.

5. A process according to claim 1 wherein said hot gas is produced by combustion of a fuel in an excess of an oxidizing gas.

6. A process according to claim 1 wherein said hot gas comprises a mixture of oxygen, nitrogen and the oxidation products of natural gas.

7. A process according to claim 1 wherein said radioactive waste material comprises a complexing aid selected from the group consisting of citric acid, EDTA and a sodium salt of EDTA.