Process for the preparation of fatty acid esters of short-chain alcohols

• US 4,668,439 A
• Filed: 06/05/1985
• Issued: 05/26/1987
• Est. Priority Date: 06/07/1984
• Status: Expired due to Fees

• Current Assignee: Hoechst Aktiengesellschaft (Sanofi )
• Original Assignee: Hoechst Aktiengesellschaft (Sanofi )
• Inventors: Kukla, Bruno, Stuhler, Herbert, Billenstein, Siegfried
• Primary Examiner(s): Reamer, James H.
• Application Number:
  US06/741,639
• Time in Patent Office: 720 Days
• Field of Search: 260/410.9 E, 260/410.9 R, 560/231
• US Class Current: 554/167
• CPC Class Codes: C11C 3/04 by esterification of fats or fatty oils

Abstract

A process for the preparation of fatty acid esters of short-chain primary and secondary alcohols with 1 to 5 carbon atoms by transesterification of glycerides with the said short-chain alcohols is described. In this process, a stream of the gaseous alcohol is passed through the liquid glyceride at temperatures of at least 210° C. and the product mixture of gylcerol and fatty acid alkyl ester is discharged from the reaction zone with this stream and is then subjected to phase separation.

Claims

1. A process for the preparation of fatty acid esters of short-chain primary and secondary alcohols with 1 to 5 carbon atoms by transesterification of glycerides with such short-chain alcohols in the presence of transesterification catalysts at elevated temperatures, which comprises bringing the liquid glyceride into intimate contact with a stream of gaseous alcohol at temperatures of at least 210°

C., the throughput of this stream per unit time being at least such that it is capable of rapidly discharging the resulting product mixture of glycerol and fatty acid ester together out of the reaction zone, after which the product mixture is condensed and subjected to phase separation into a fatty acid ester phase and a glycerol phase and the excess gaseous alcohol is recycled to the reaction zone.

2. The process as claimed in claim 1, wherein the throughput of gaseous alcohol is at least 8 moles/kg of glyceride per hour.

3. The process as claimed in claim 1, wherein up to 30% of an inert gas are also added to the amount of alcohol passed through.

4. The process as claimed in claim 1, wherein the alcohol is ethanol, propanol, isopropanol or methanol.

5. The process as claimed in claim 1, wherein the alcohol is methanol.

6. The process as claimed in claim 1, wherein glyceride is initially introduced into the reactor and the initially introduced amount of glyceride is largely maintained by feeding glyceride in at the rate at which it is consumed during the reaction.

7. The process as claimed in claim 1, wherein the transesterification of the glyceride is carried out under a pressure not exceeding about 5 bar.

8. A process for the preparation of fatty acid esters of short-chain primary and secondary alcohols with 1 to 5 carbon atoms by transesterification of glycerides with such short-chain alcohols in the presence of transesterification catalyst at elevated temperatures, which comprises bringing the liquid glyceride into intimate contact with a stream of gaseous alcohol at temperatures of at least 210°

C. in a reaction zone, the throughput of this stream per unit time being at least such that it is capable of rapidly discharging the resulting product mixture consisting essentially of glycerol and fatty acid ester together out of the reaction zone, passing the stream of gaseous alcohol out of the reaction zone with the said product mixture contained therewithin, and subsequently condensing the product mixture and subjecting the product mixture to phase separation into a fatty acid ester phase and a glyercol phase in a separation zone outside of said reaction zone, and recycling the excess gaseous alcohol to the reaction zone.

9. A process as claimed in claim 8, wherein the throughput of gaseous alcohol is at least 8 moles/kg of glyceride per hour.