Surface treated metallic filaments

• US 4,668,578 A
• Filed: 11/13/1984
• Issued: 05/26/1987
• Est. Priority Date: 11/13/1984
• Status: Expired due to Term

• Current Assignee: Composite Materials, LLC
• Original Assignee: American Colloid Company (Minerals Technologies Incorporated)
• Inventors: Luxon, Bruce A.
• Primary Examiner(s): Lusignan, Michael R.
• Application Number:
  US06/670,779
• Time in Patent Office: 924 Days
• Field of Search: 428/364, 428/7, 428/8, 428/378, 428/9, 428/392, 428/5, 428/447, 428/450, 428/391, 428/408, 427/387
• US Class Current: 428/367
• CPC Class Codes: C08J 2363/00 Characterised by the use of epoxy resins; Derivatives of epoxy resins
• CPC Class Codes: C08J 5/06 using pretreated fibrous materials
• CPC Class Codes: D01F 11/12 with inorganic substances ; Intercalation
• CPC Class Codes: D01F 11/127 Metals metal depositing by electrolysis D01F11/16; metal alloys with reinforcing carbon fibres C22C49/14
• CPC Class Codes: D01F 11/14 with organic compounds, e.g. macromolecular compounds
• CPC Class Codes: Y10T 428/2918 including free carbon or carbide or therewith [not as steel]
• CPC Class Codes: Y10T 428/294 including metal or compound thereof [excluding glass, ceramic and asbestos]
• CPC Class Codes: Y10T 428/2962 Silane, silicone or siloxane in coating
• CPC Class Codes: Y10T 428/30 Self-sustaining carbon mass or layer with impregnant or other layer

Abstract

Metallic filaments, esp., metal-coated fibers, are surface treated by a combination of silane and poly (vinyl acetate) and exhibit improved processability when used in the form of filaments, yarns or tows in knitting and weaving machines, and produce composites with thermosetting organic polymers, having enhanced physical properties.

Claims

1. A process for surface treating metallic filaments comprising:

(a) passing the metallic filaments through a medium comprising between about 0.1 and about 2.5 percent by weight of a silane and between about 0.1 and 2.5 percent by weight of a poly(vinyl acetate); and

(b) drying the metallic filaments to set the material on the filaments.

2. A process as defined in claim 1 wherein said medium comprises both the silane and the poly(vinyl acetate).

3. A process as defined in claim 1 wherein the medium is in at least two parts, at least one part comprising the silane and at least a second part comprising the poly(vinyl acetate).

4. A process as defined in claim 1 wherein said medium comprises from about 0.2 to about 1.2 percent by weight of said silane and from about 0.2 to about 1.2 percent by weight of said poly(vinyl acetate).

5. A process as defined in claim 4 wherein said medium comprises about 0.8 percent by weight of said silane and about 0.8 percent by weight of said poly(vinyl acetate).

6. A process as defined in claim 1 wherein said medium is a water based medium.

7. A process as defined in claim 6 wherein the pH of the water based medium is in the range of between about 3.5 and about 9.

8. A process as defined in claim 1 wherein the residence time of the fiber is the medium is at least about 0.5 seconds.

9. A process as defined in claim 1 wherein step (b) is carried out under elevated temperature conditions.

10. A process as defined in claim 1 wherein the silane is coupled to the surface of the metallic filament.

11. A process as defined in claim 1 wherein the metallic filament has a metal oxide surface prior to step (a).

12. A process as defined in claim 11 wherein the metal is nickel having a nickel oxide or silver having a silver oxide surface.

13. A process as defined in claim 1 wherein the filament comprises a metal coated fiber wherein the core fiber comprises carbon or graphite.

14. A process as defined in claim 1 wherein the filament comprises a metal coated fiber wherein the core comprises an aramid fiber.

15. Metallic filaments surface treated by the process of claim 1.

16. Metallic filaments surface treated by the process of claim 4.

17. Metallic filaments surface treated by the process of claim 5.

18. Metal coated filaments wherein the core comprises carbon or graphite surface treated by the process of claim 1.

19. Metal coated filaments wherein the core comprises carbon or graphite surface treated by the process of claim 4.

20. Metal coated filaments wherein the core comprises carbon or graphite surface treated by the process of claim 5.

21. A composite comprising the metallic filaments of claim 18 dispersed in a polymeric matrix.

22. A composite comprising the metallic filaments of claim 19 dispersed in a polymeric matrix.

23. A composite comprising the metallic filaments of claim 20 dispersed in a polymeric matrix.

24. A composite as defined in claim 21 in the form of a laminated sheet.

25. A composite as defined in claim 22 in the form of a laminated sheet.

26. A composite as defined in claim 23 in the form of a laminated sheet.