Polymer article and its use for controlled introduction of reagent into a fluid

• US 4,670,166 A
• Filed: 02/27/1985
• Issued: 06/02/1987
• Est. Priority Date: 02/27/1985
• Status: Expired due to Fees

• Current Assignee: Nalco/Exxon Energy Chemicals L.P. (Exxon Mobil Corporation)
• Original Assignee: Exxon Chemical Patents Inc. (Exxon Mobil Corporation)
• Inventors: Newlove, John C., McDougall, Lee A., Haslegrave, John A.
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US06/707,003
• Time in Patent Office: 825 Days
• Field of Search: 252/8.55 R, 252/8.55 B, 252/8.55 D, 252/8.55 E
• US Class Current: 507/224
• CPC Class Codes: C09K 8/536 characterised by their form or by the form of their components, e.g. encapsulated material
• CPC Class Codes: C09K 8/54 Compositions for in situ inhibition of corrosion in boreholes or wells
• CPC Class Codes: C09K 8/584 characterised by the use of specific surfactants
• CPC Class Codes: C09K 8/68 containing organic compounds
• CPC Class Codes: C09K 8/70 characterised by their form or by the form of their components, e.g. foams
• CPC Class Codes: E21B 43/32 Preventing gas- or water-coning phenomena, i.e. the formation of a conical column of gas or water around wells
• CPC Class Codes: Y10S 166/902 for inhibiting corrosion or coating
• CPC Class Codes: Y10S 507/902 Controlled release agent
• CPC Class Codes: Y10S 507/92 Biocidal
• CPC Class Codes: Y10S 507/922 Fracture fluid
• CPC Class Codes: Y10S 507/927 Well cleaning fluid
• CPC Class Codes: Y10S 507/939 Corrosion inhibitor

Abstract

A solid polymeric body comprising a polymer matrix containing a water-soluble reagent leachable into a fluid containing condensed water, said matrix being reagent permeative and insoluble in said fluid containing condensed water and the said body preferably having a softening point substantially above that of the temperature of the fluid environment in which it is to be employed is useful for the introduction of an additive reagent into said fluid particularly when said fluid is located in a subterranean formation.

Claims

1. A method for the controlled introduction of a water-soluble reagent into an environment containing condensed water which comprises:

(a) suspension copolymerizing a monomer selected from acrylic acid, acrylamide, and acrylonitrile with a difunctional hydrophylic comonomer to form water-insoluble hard solid particles of a polymer having a softening point above said environment, said particles having structural integrity, internal porosity, and a particle size of at least 50 microns and less than 2 millimeters, said monomer with said comonomer having dissolved therein a water soluble reagent which is insoluble in said polymer whereby said reagent remains in the pores of said particles following the copolymerization step, said reagent constituting at least 5 weight percent and not more than 30 weight percent based on the combined weights of the polymer and the reagent;

said reagent being selected from the group consisting of scale inhibitors, surfactants, corrosion inhibitors, biocides, foamers, and oxygen scavengers;

(b) placing said particles in said environment;

(c) flowing water through said particles thereby leaching an effective amount of said water-soluble reagent from said particles forming an aqueous solution of said reagent in said environment, said particles retaining their physical structural integrity; and

(d) flowing said aqueous solution in said environment.

2. The method of claim 1 wherein the scale inhibitors are selected from phosphonates, phosphate esters, inorganic phosphates, polyacrylic acid;

the surfactants are selected from polyoxyalkylene ether and polyalkylene surfactants;

the corrosion inhibitors are selected from amines;

the biocides are selected from 2,2-dibromo-3-nitrilopropionamide, 2-methyl-4-iso-thiazolin-3-one, 5-chloro-2-methyl-4-iso-thiazolin-3-one, dithiocarbamate, and aldehydes;

the foamers are selected from alcohol ether sulfates, sulfonates, ethoxylated polyols, ethoxylated amines, quaternized amines, amine oxides, and ampholytics; and

the oxygen scavengers are selected from sodium bisulfite and hydrazine.

3. The method as defined in claim 1 wherein said water-soluble reagent is removed from said pores of said particles to outside of said body at a leach rate in which fifty percent of the reagent is leached from the particles in up to 3 years by said environment.

4. The method as defined in claim 1 wherein said monomer is acrylamide and said comonomer is a methylene-bisacrylamide and said water-soluble reagent is diethylenetriaminepentakismethylene phosphonic acid or salts thereof.

5. The method as defined in claim 1 wherein the polymer has a softening point temperature ranging upwards from 30°

C.

6. A method according to claim 1 wherein said environment is subterranean.

7. A method according to claim 6 wherein said environment is a substantially hydrocarbon bearing formation.

8. A method according to claim 6 wherein said environment is a substantially water containing formation.

9. A method according to claim 1 wherein the placing of said particles is by means of a stimulation fluid.

10. A method according to claim 9 wherein said fluid is aqueous and said particles are introduced into said fluid in a damp and water-wetted state.

11. A method according to claim 9 wherein said reagent is reactive with at least one component of said stimulation fluid whereby the reaction between said reagent and said component is prevented by said reagents inclusion in said particles.

12. A method according to claim 1 wherein the placing of said bodies is by means of a workover fluid.

13. A method according to claim 1 wherein said reagent is diethylenetriamine pentakismethylene phosphonic acid or its salt.