Method and compositions relating to the activation of fluorescent whitening agents

• US 4,670,183 A
• Filed: 11/14/1984
• Issued: 06/02/1987
• Est. Priority Date: 11/15/1983
• Status: Expired due to Fees

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Corbett, Peter J., Louman, Hendrik W.
• Primary Examiner(s): Williams, Howard S.
• Application Number:
  US06/671,528
• Time in Patent Office: 930 Days
• Field of Search: 252/301.35
• US Class Current: 252/301.35
• CPC Class Codes: D06L 4/664 Preparations of optical brighteners; Optical brighteners in aerosol form; Physical treatment of optical brighteners
• CPC Class Codes: D21H 19/58 Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
• CPC Class Codes: D21H 21/30 Luminescent or fluorescent substances, e.g. for optical bleaching D21H21/40 takes precedence

Abstract

A fluorescent whitening agent is activated using a polymer of a hydroxyalkyl (meth)acrylate such as poly(2-hydroxyethyl acrylate).

Claims

1. A composition comprising a fluorescent whitening agent and an activating amount of

(1) a homopolymer of a hydroxyalkyl(meth)acrylate, or

(2) a copolymer of two or more hydroxyalkyl (meth)acrylates, or

(3) a copolymer comprising more than 70 weight percent, in polymerized form, of one or more hydroxyalkyl (meth)acrylate(s)

whereby said composition appears whiter than in the absence of said (1), (2), or (3).

2. The composition of claim 1 wherein the ratio of the polymer activator to the whitening agent is 100:

1 to 1;

1 and the composition further comprises an aqueous liquid carrier in which the fluorescent whitening agent and polymer activator are soluble.

4. The composition of claim 1 wherein the polymeric activator is a homopolymer of 2-hydroxyethyl acrylate or a copolymer of 2-hydroxyethyl acrylate and hydroxypropyl acrylate.

5. The composition of claim 1 containing from 10 to 80 weight percent based on the total weight of the coating color of fillers and/or pigments;

up to 10 weight parts of the polymeric activator and from 0.01 to 1.5 weight parts of the fluorescent whitening agent per 100 weight parts of the fillers and pigments.

6. The composition of claim 5 wherein from 0.5 to 5 weight parts of the polymeric activator and from 0.03 to 1 weight part of the fluorescent whitening agent are employed per 100 weight parts of the fillers and pigments and the ratio of polymeric activator to fluorescent whitening agent is 50:

1 to 2;

1, and the composition further comprises from 4 to 35 weight parts of a copolymer binder per 100 weight parts of the fillers and pigments, and a thickener.

7. The composition of claim 6 wherein the thickener is a synthetic polymer thickener derived from an α

,β

-ethylenically unsaturated carboxylic acid, a C₁ -C₄ alkyl ester of an unsaturated carboxylic acid.

8. The composition of claim 7 wherein said thickener additionally comprises other comonomers.

3. The composition of 5 wherein the liquid carrier is water and the aqueous solution contains from 0.1 to 60 weight percent of the fluorescent whitening agent and polymer activator.

9. A composition comprising a fluorescent whitening agent and a homopolymer of hydroxyethyl acrylate and a synthetic polymer thickener, the polymer thickener being employed in an amount of from 0.6 to 10 weight parts of acrylate homopolymer per weight part of synthetic polymer thickener.

10. A method for activating a fluorescent whitening agent with a polymeric activator which comprises contacting the fluorescent whitening agent with an activating amount of

(1) a homopolymer of a hydroxyalkyl (meth)acrylate,

(2) a copolymer of two or more hydroxyalkyl (meth)acrylates or

(3) a copolymer comprising more than 70 weight percent in polymerized form of one or more hydroxyalkyl (meth)acrylates.