Fuel cell powerplant employing an aqueous solution

• US 4,670,357 A
• Filed: 06/17/1985
• Issued: 06/02/1987
• Est. Priority Date: 06/17/1985
• Status: Expired due to Fees

• Current Assignee: International Fuel Cells Corporation South Windsor CT
• Original Assignee: International Fuel Cells Corporation (Doosan Corporation)
• Inventors: Taylor, William A.
• Primary Examiner(s): Hearn, Brian E.
• Assistant Examiner(s): KALAFUT, STEPHEN J
• Application Number:
  US06/745,465
• Time in Patent Office: 715 Days
• Field of Search: 423/138, 423/140, 423/151, 423/152, 423/637, 429/12, 429/26
• US Class Current: 429/535
• CPC Class Codes: C01G 49/06 Ferric oxide [Fe2O3]
• CPC Class Codes: H01M 8/04029 Heat exchange using liquids
• CPC Class Codes: H01M 8/0612 from carbon-containing material
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A ferric hydrous oxide of a character that retards the deposition of iron based compounds on the walls of a conduit is prepared by flowing an aqueous solution containing iron-based compounds including magnetite into a vented chamber, and boiling the solution at atmospheric pressure.

Claims

1. A method for forming ferric hydrous oxide of a character that retards the deposition of iron based compounds on the walls of a conduit, comprising:

flowing to a vented chamber an aqueous solution containing iron based compounds which include magnetite, the aqueous solution having an oxygen content which supresses the formation of magnetite and promotes the conversion of a portion of the magnetite to ferric hydrous oxide during boiling of the aqueous solution at atmospheric pressure;

heating the aqueous solution at atmospheric pressure until the aqueous solution boils for a period of time that causes the conversion of at least a portion of said magnetite to ferric hydrous oxide;

cooling a portion of said boiled aqueous solution and disposing said cooled, boiled aqueous solution including said ferric hydrous oxide of a character that retards the deposition of iron based compounds in said conduit.

2. The method for forming ferric hydrous oxide of claim 1 which includes the step of heating the surface which contacts the aqueous solution to cause boiling of the aqueous solution and controlling the heat transferred to the surface such that the temperature of the surface is less than or equal to 300°

F.

3. The method for forming ferric hydrous oxide of claim 1 wherein the aqueous solution is boiled for a period of approximately 24 hours.

4. The method for forming ferric hydrous oxide of claim 3 wherein boiling causes steam to form and wherein the method further includes the step of condensing at least a portion of the steam which is formed and returning the condensate to the aqueous solution.

5. The method for forming ferric hydrous oxide as claimed in claim 4 wherein the step of condensing takes place by contacting the vapor with a surface containing iron and removing heat from the vapor through said surface.

6. A method for forming in a fuel cell powerplant ferric hydrous oxide of a character that retards the deposition of iron based compounds on the walls of a conduit in the powerplant, the powerplant having a fuel cell stack and a cooling system for the fuel cell stack which employs an aqueous coolant, comprising:

flowing to a vented chamber an aqueous solution containing iron based compounds which include magnetite, the aqueous solution having an oxygen content which supresses the formation of magnetite and which promotes the conversion of a portion of the magnetite to ferric hydrous oxide during boiling of the aqueous solution at atmospheric pressure;

flowing heated coolant from the fuel cell stack to the chamber;

transferring heat from the coolant to boil said aqueous solution;

cooling a portion of said boiled aqueous solution and

flowing said cooled, boiled aqueous solution to the cooling system for the fuel cell stack.

7. The method for forming ferric hydrous oxide of claim 6 wherein the aqueous solution is the coolant and wherein the step of flowing an aqueous solution to the chamber includes the step of flowing the aqueous coolant from the cooling system of the fuel cell powerplant to the chamber.

8. The method for forming ferric hydrous oxide of claim 6 wherein the fuel cell powerplant has a feedwater system for supplying feedwater to the cooling system and the step of flowing an aqueous solution to the chamber includes the step flowing a portion of feedwater for the cooling system of the fuel cell powerplant to the chamber.

9. The method for forming ferric hydrous oxide of claim 8 wherein the method includes the step of raising the pH of the aqueous solution such that the pH is greater than 5.5 when boiled.