Fluid treatment apparatus and heat exchanger

• US 4,671,351 A
• Filed: 07/17/1985
• Issued: 06/09/1987
• Est. Priority Date: 07/17/1985
• Status: Expired due to Term

• Current Assignee: Bow Valley Resource Services Limited
• Original Assignee: VerTech Treatment Systems, Inc.
• Inventors: Rappe, Gerald C.
• Primary Examiner(s): Cline, William R.
• Assistant Examiner(s): Ford, John K.
• Application Number:
  US06/755,880
• Time in Patent Office: 692 Days
• Field of Search: 165/133, 165/142, 165/135, 165/45, 165/155, 165/47, 210/761, 210/762, 210/177, 210/178, 210/170
• US Class Current: 165/133
• CPC Class Codes: C02F 11/08 Wet air oxidation
• CPC Class Codes: C02F 11/083 using deep well reactors
• CPC Class Codes: F24T 10/17 using tubes closed at one end, i.e. return-type tubes
• CPC Class Codes: F28D 7/12 the surrounding tube being closed at one end, e.g. return type F28D7/14 takes precedence
• CPC Class Codes: F28F 1/003 Multiple wall conduits, e.g. for leak detection leak-detection in metal cooled nuclear reactor steam generators F22B1/066
• CPC Class Codes: F28F 13/18 by applying coatings, e.g. radiation-absorbing, radiation-reflecting; by surface treatment, e.g. polishing
• CPC Class Codes: Y02E 10/10 Geothermal energy

Abstract

The heat exchanger, which forms a part of the fluid treatment apparatus of this invention, includes an insulated tubular having concentric telescopically nested spaced tubes, wherein the space between the tubes is sealed and filled with an inert gas. The surfaces of the tubes are coated with a hydrogen permeation barrier preferably comprising an aluminum-iron alloy, nickel or copper which limits atomic hydrogen permeation into the space between the tubes, which would combine to form hydrogen gas and result in heat loss. The insulated tubular is telescopically nested in a pipe, forming a fluid heat exchanger and the heat exchanger is telescopically nested in fluid waste circulation pipes, forming the fluid treatment apparatus of this invention. The preferred fluid heat exchanger is a vertically extending deep well reactor suitable for wet oxidation reaction of fluid wastes including municipal sludge.

Claims

1. An elongated heat exchanger, comprising an elongated insulated tubular having an open end generally concentric with telescopically nested in and surrounded by a second pipe having a closed end adjacent said open end of said insulated tubular and communicating therewith, said insulated tubular having a first inner metal tube and a second outer metal tube generally concentric with and surrounding said first tube in spaced relation, the space between said first and second tubes sealed and filled with an inert gas, a hot heat transfer fluid received in one end of said insulated tubular and flowing through said insulated tubular, said heat transfer fluid cooling and returning through said second pipe for heating and recirculation, and a hydrogen permeation barrier on the inner and outer surfaces of said first and second tubes of said insulated tubular, said hydrogen permeation barrier comprising a metal coating selected from the group consisting of aluminum, nickel and copper, said permeation barrier reducing the flow of atomic hydrogen into said space between said first and second tubes of said insulated tubular, thereby reducing heat losses from said heat transfer fluid in said insulated tubular to the returning heat transfer fluid in said second pipe.

2. The heat exchanger defined in claim 1, characterized in that said first and second tubes of said insulated tubular are steel and said hydrogen diffusion barrier consists of a diffusion coating of aluminum on said inner and outer surfaces, forming an iron-aluminum alloy.

3. The heat exchanger defined in claim 1, characterized in that said hydrogen diffusion barrier comprises an electroplated coating selected from the group consisting of nickel and copper.

4. A continuous fluid treatment apparatus for treatment of fluids at elevated temperatures, said fluid treatment apparatus including an elongated fluid heat exchanger surrounded by fluid circulation pipes containing the fluid to fbe treated, said heat exchanger comprising a first pipe having a closed end and an insulated tubular generally concentric with and telescopically nested within said first pipe in spaced relation having an open end adjacent said closed end of said first pipe, said insulated tubular comprising generally concentric telescopically nested spaced metal tubes, the space between said tubes sealed and filled with an inert gas, a hot heat transfer fluid flowing through said insulated tubular in one direction, cooling and returning through said first pipe in the opposite direction around said insulated tubular, and said circulation pipes comprising a second pipe telescopically surrounding said first pipe in spaced relation receiving the fluid to be treated in contact with said first pipe, and a third pipe generally concentric with and surrounding said second pipe in spaced relation recirculating the treated fluid, the heat from said heat transfer fluid thereby heating said fluid to be treated, and said insulated tubular having a hydrogen permeation barrier, said hydrogen permeation barrier comprising a coating means on the exterior and interior surfaces of said nested metal tubes limiting permeation of atomic hydrogen into said space between said tubes and hydrogen gas build-up in said space, said barrier reducing heat losses from the hot heat transfer fluid in said insulated tubular to the returning heat transfer fluid in said first pipe and providing a predetermined heating zone for the fluid being treated in said second pipe adjacent said closed end of said first pipe.

5. The continuous fluid treatment apparatus defined in claim 4, characterized in that said tubes of said insulated tubular are steel and said hydrogen diffusion barrier consists of a diffusion coating of aluminum on said inner and outer surfaces, forming an iron-aluminum alloy limiting diffusion of atomic hydrogen through said tubes.

6. The continuous fluid treatment apparatus defined in claim 4, characterized in that said hydrogen diffusion barrier comprises an electroplated coating on said surfaces selected from the group consisting of nickel and copper.