Electro-optic device

• US 4,671,619 A
• Filed: 07/09/1985
• Issued: 06/09/1987
• Est. Priority Date: 07/24/1984
• Status: Expired due to Term

• Current Assignee: AGC Flat Glass Company Limited (AGC, Inc.)
• Original Assignee: Asahi Glass Company, Limited (AGC, Inc.)
• Inventors: Nagai, Junichi, Mizuhashi, Mamoru, Kamimori, Tadatoshi
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US06/753,150
• Time in Patent Office: 700 Days
• Field of Search: 350/357
• US Class Current: 359/275
• CPC Class Codes: G02F 1/1525 characterised by a particular ion transporting layer, e.g. electrolyte

Abstract

An electro-optical device containing an electrochromic material layer and electrolytic solution interposed between mutually opposed base plates, each having an electrode on the surface thereof, wherein said electrolytic solution consists essentially of (a) an iodide source material as a redox reaction promoter selected from the group consisting of metal iodides and ammonium iodides, and (b) a lactone solvent capable of dissolving the redox reaction promoter, with the proviso that when the iodide ion source material is not also a metal cation source, a cation source material capable of generating H⁺ or Li⁺ is further added.

Claims

1. An electro-optical device comprising an electrochemical material layer and an electrolytic solution interposed between mutually opposed base plates, each having an electrode on the surface thereof, wherein said electrolytic solution consists essentially of:

(a) an iodide source material as a redox reaction promoter selected from the group consisting of metal iodides an ammonium iodides, and

(b) a lactone solvent capable of dissolving the redox reaction promoter, with the proviso that when the iodide ion source material is not also a metal cation source, a cation source material which is capable of generating H⁺ or Li⁺ ions is further added.

2. The electro-optical device according to claim 1, wherein said metal iodide is selected from the group consisting of LiI and NaI;

and said ammonium iodide is selected from the group consisting of NH₄ I, (CH₃)₄ NI and (C₂ H₅)₄ NI.

3. The electro-optical device according to claim 2, wherein said metal iodide is lithium iodide.

4. The electro-optical device according to claim 1, wherein said lactone solvent is a β

-, γ

- or δ

-lactone solvent.

5. The electro-optical device according to claim 4, wherein said lactone solvent is γ

-butyrolactone.

6. The electro-optical device according to claim 1, wherein said electrochromic material layer is a material layer selected from the group consisting of WO₃, MoO₃, TiO₂ and Ir₂ O₃ layers.

7. An electro-optical device comprising an electrochemical material layer and a gelled electrolytic solution interposed between neutrally opposed base plates, each having an electrode on the surface thereof, wherein said gelled electrolytic solution consists essentially of:

(a) an iodide ion source material as a redox reaction promoter selected from the group consisting of metal iodides and ammonium iodides, and

(b) a lactone solvent capable of dissolving the redox reaction promoter, with the proviso that when the iodide source material is not also a metal cation source, a cation source material capable of generating H⁺ or Li⁺ ions is further added, and wherein a polymer is added to the electrolytic solution to increase the viscosity thereof, to form a gel of said electrolytic solution.

8. The electro-optical device according to claim 7, in which said polymer is a polyvinyl acetal polymer.

9. The electro-optical device according to claim 8, in which said polymer is polyvinyl butyral.

10. The electro-optical device according to claim 7, in which said polymer is urethane.

11. The electro-optical device according to claim 7, in which said polymer is an acrylic polymer.

12. The electro-optical device according to claim 7, wherein said metal iodide is selected from the group consisting of LiI and NaI, and said ammonium iodide is selected from the group consisting of NH₄ I, (CH₃)₄ NI and (C₂ H₅)₄ NI.

13. The electro-optical device according to claim 7, wherein when an ammonium iodide is used as the redox reaction promoter, LiClO₄ is added as a cation source material.

14. The electro-optical device according to claim 7, wherein said lactone solvent is a β

-, γ

- or δ

-lactone solvent.

15. The electro-optical device according to claim 14, wherein said lactone solvent is γ

-butyrolactone.

16. The electro-optical device according to claim 7, wherein said electrochromic material layer is a material layer selected from the group consisting of WO₃, MoO₃, TiO₂ and Ir₂ O₃ layers.