Medical electrode for monitoring and diagnostic use

• US 4,674,512 A
• Filed: 02/03/1986
• Issued: 06/23/1987
• Est. Priority Date: 02/03/1986
• Status: Expired due to Term

• Current Assignee: LecTec Corporation
• Original Assignee: LecTec Corporation
• Inventors: Rolf, David
• Primary Examiner(s): Cohen, Lee S.
• Application Number:
  US06/825,751
• Time in Patent Office: 505 Days
• Field of Search: 128/639-641, 128/798, 128/802, 128/803
• US Class Current: 600/391
• CPC Class Codes: A61B 5/259 using conductive adhesive means, e.g. gels
• CPC Class Codes: H01B 1/20 Conductive material dispersed in non-conductive organic material organic macromolecular compounds or compositions C08

Abstract

A medical electrode is provided which includes a flexible tin backing coated with a flexible hydrated gel matrix adapted to contact and conform to the skin. The matrix is composed of a hydrated polysaccharide gum, a liquid hydrating agent such as a polyhydric alcohol and water, an electrolyte including one or more tin salts dissolved in the liquid and preferably a stabilizer present in sufficient quantity to prevent the tin salts from forming insoluble reaction products.

Claims

1. An electrode device for establishing electrical contact with the skin comprising, a flexible electrically conductive metallic layer comprising tin, and electrically conductive flexible substrate attached to said conductive layer comprising a substantially homogeneous, hydrated hydrophilic, stable self supporting matrix sufficiently pliant to conform to the shape of the body contours, said matrix including a dispersed phase comprising about 10 percent to 50 percent of the total weight of the matrix and formed from a hydrophilic natural and/or synthetic polysaccharide gum and/or a hydrophilic synthetic polymer and a liquid phase hydrating the matrix and converting the matrix to a hydrocolloidal suspension, said liquid phase comprising at least one polyhydric alcohol, an electrolyte to render the matrix electrically conductive comprising at least one dissolved tin salt comprising a member selected from the group consisting of SnSO₄, SnCl₂, SnCl₂.2H₂ O and SnF₂ and a thin salt of SnBr₂, a multibasic organic acid distributed throughout the matrix and being present at an exposed surface of the matrix adapted to contact the skin, a stabilizer in sufficient quantity to maintain the tin ions in solution at room temperature thereby preventing the formation of insoluble tin salts, said stabilizer comprising a member selected from the group consisting of tartaric acid, n-alkyl sulfonate wherein n is from 8-16 carbon atoms, citric acid and an alkali metal salt of citric acid, whereby said stabilizer mainstains the pH of the composition, reduces corrosion of the tin layer and lessens skin sensitivity reactions.

2. The electrode of claim 1 wherein the gum comprises karaya gum.

3. The electrode of claim 2 wherein the karaya gum is present in an amount of from about 10-50% by the weight of the matrix.

4. The electrode of claim 1 wherein the hydrophilic synthetic polymer comprises anionic polyacrylamide in an amount of from about 2 to about 20% by weight of the matrix.

5. The electrode of claim 1 wherein the hydrophilic synthetic polymer comprises vinyl acetate based latex adhesive.

6. The electrode of claim 1 wherein the synthetic polymer is polyacrylic acid in the amount of from about 1 to about 20% of weight of the matrix.

7. The electrode device of claim 1 wherein the tin salt comprises SnSO₄ in the amount of about 0.1% to 1% by weight of the matrix.

8. The electrode device of claim 1 wherein the tin salt is SnCl₂ in the amount of about 0.1% to 1% by weight of the matrix.

9. The electrode device of claim 1 wherein the tin salt is SnF₂ in the amount of about 0.1% to 1% by weight of the matrix.

10. The electrode of claim 1 wherein the tin salt is SnCl₂.2H₂ O in the amount of from about 0.1% to 1% by weight of the matrix.