Process for preparing polyisocyanato/polyisocyanurates by catalytic cyclotrimerization of polyisocyanates

• US 4,675,401 A
• Filed: 10/30/1985
• Issued: 06/23/1987
• Est. Priority Date: 10/30/1984
• Status: Expired due to Fees

• Current Assignee: Rhone-Poulenc Specialites Chimiques (Sanofi )
• Original Assignee: Rhone-Poulenc Specialites Chimiques (Sanofi )
• Inventors: Robin, Jean
• Primary Examiner(s): Ford, John M.
• Assistant Examiner(s): Mullins, J. G.
• Application Number:
  US06/792,835
• Time in Patent Office: 601 Days
• Field of Search: 544/222, 544/193, 521/128, 521/902, 526/194, 528/52
• US Class Current: 544/193
• CPC Class Codes: C07D 251/34 Cyanuric or isocyanuric esters
• CPC Class Codes: C08G 18/022 the polymeric products containing isocyanurate groups
• CPC Class Codes: Y10S 521/902 Cellular polymer containing an isocyanurate structure

Abstract

Polyisocyanurate/polyisocyanates of enhanced stability are prepared by partial catalytic cyclotrimerization of a polyisocyanate in the presence of a catalytically effective amount of an aminosilyl catalyst and wherein the cyclotrimerization reaction is terminated when a predetermined desired amount of isocyanurate groups has been attained, by adding to the reaction mixture, after the cooling thereof to a temperature of below 50° C., a reaction terminating amount of an organic catalyst deactivating compound comprising at least one free hydroxyl moiety, or the reaction product of such hydroxylated organic catalyst deactivating compound with an isocyanate.

Claims

1. A process for the preparation of a polyisocyanato-polyisocyanurate by the catalytic cyclotrimerization of an aliphatic or cycloaliphatic polyisocyanate in the presence of a catalytically effective amount of an aminosilyl catalyst and wherein the cyclotrimerization reaction is terminated when a predetermined desired amount of isocyanurate groups has been attained, by adding to the reaction mixture a reaction terminating amount of an organic catalyst deactivating compound comprising at least one free hydroxyl moiety, or the reaction product of such hydroxylated organic catalyst deactivating compound with an isocyanate, the improvement which comprises adding said catalyst deactivating compound to said reaction mixture after the temperature thereof has been cooled to a temperature of below 50°

C.

2. The process as defined by claim 1, comprising adding said catalyst deactivating compound to said reaction mixture after the temperature thereof has been cooled to a temperature of from 15°

to 40°

C.

3. The process as defined by claim 1, said catalyst deactivating compound comprising an enol, alcohol, polyol, phenol, polyphenol, ketoxime, or hydroxysilylated organosilicon compound.

4. The process as defined by claim 3, said catalyst deactivating compound comprising a primary or secondary monoalcohol having from 1 to 8 carbon atoms.

5. The process as defined by claim 4, said monoalcohol having from 3 to 6 carbon atoms.

6. The process as defined by claim 1, wherein the amount of catalyst deactivating compound added, expressed in moles per mole of catalyst, ranges from 0.5 to 2.

7. The process as defined by claim 1, wherein said aminosilyl cyclotrimerization catalyst comprises an aminosilane, diaminosilane, monosilylurea, disilylurea or silazane.