High pressure low heat rate phosphoric acid fuel cell stack

• US 4,678,723 A
• Filed: 11/03/1986
• Issued: 07/07/1987
• Est. Priority Date: 11/03/1986
• Status: Expired due to Fees

• Current Assignee: International Fuel Cells Corporation (Doosan Corporation)
• Original Assignee: International Fuel Cells Corporation (Doosan Corporation)
• Inventors: Wertheim, Ronald J.
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US06/926,164
• Time in Patent Office: 246 Days
• Field of Search: 429/17, 429/19, 429/20, 429/120, 429/72, 429/46
• US Class Current: 429/414
• CPC Class Codes: H01M 8/04014 Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
• CPC Class Codes: H01M 8/04022 Heating by combustion
• CPC Class Codes: H01M 8/04119 with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
• CPC Class Codes: H01M 8/0612 from carbon-containing material
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

The fuel cell stack is a phosphoric acid fuel cell stack which can operate at higher pressures because it does not use steam in the operation of the reformer portion. By being able to operate at higher pressures, the stack displays very low system heat rates and thus higher operating efficiency. The higher operating pressure also results in improved fuel cell power density and reduced cost. The stack is cooled by a coolant mixture of air and entrained water droplets comprising cathode exhaust and injected water fog. During the cooling operation, the water droplets in the coolant mixture are vaporized in the cooling passages of the stack. The exhaust from the cooling system after being heated is then delivered to an autothermal reformer where it reacts with a raw fuel reactant to produce hydrogen for operating the fuel cells in the stack. The reformer does not require a separate burner to operate properly.

Claims

1. A high pressure phosphoric acid fuel cell stack assembly comprising:

(a) a stack of fuel cells for producing electricity, said stack including cathode means, anode means, and heat exchange means;

(b) means for delivering pressurized air to said cathode means;

(c) means for delivering a hydrogen rich fuel gas to said anode means for electrochemically reacting with oxygen in the pressurized air to produce electricity and water;

(d) first conduit means connected to said cathode means for exhausting a mixture of oxygen-depleted air and reaction water from said cathode means;

(e) second conduit means connected to said first conduit means for delivering a water fog to said first conduit means for entrainment in said mixture of oxygen-depleted air and reaction water to form a two phase coolant having a gaseous air phase and an entrained water droplet phase;

(f) means for circulating said coolant to said heat exchange means to cool said stack solely through vaporization of said water droplet phase in said heat exchange means whereby a mixed gas exhaust of air and water vapor is exhausted from said heat exchange means; and

(g) means for heating said mixed gas exhaust and delivering the heated mixed gas exhaust at reformer reaction temperatures to an autothermal reformer in said stack assembly for autothermal reaction with a raw fuel to form said hydrogen rich fuel.

2. The stack assembly of claim 1 further comprising catalytic burner means operably connected to said anode means for receiving depleted hydrogen fuel gas exhaust from said anode means;

third conduit means operably connected to said catalytic burner means and to said means for heating and delivering, said third conduit means being operable to deliver a portion of said heated mixed gas exhaust to said catalytic burner means for catalytic combustion with said depleted hydrogen fuel gas to produce a high temperature catalytic burner exhaust; and

means for supplying said high temperature catalytic burner exhaust to said means for heating and delivering whereby said burner exhaust supplies a portion of the heat required for heating said mixed gas exhaust to said reformer reaction temperatures.

3. The stack assembly of claim 2 further comprising condenser means for condensing water out of exhaust gases in said assembly;

fourth conduit means operably interconnecting said means for heating and delivering said condenser means, said fourth conduit means being operable to deliver cooled catalytic burner exhaust from said means for heating and delivering to said condenser means, and said condenser means being operable to condense water fog out of said cooled catalytic burner exhaust; and

wherein said second conduit means is operably connected to said condenser means.

4. The stack assembly of claim 3 further comprising turbine means and operably interconnected compressor means, said fourth conduit means being operable to deliver said cooled catalytic burner exhaust to said turbine means to operate the latter prior to being delivered to said condenser means, and said turbine means being operable to drive said compressor means to enable the latter to supply said pressurized air to said cathode means.

5. The stack assembly of claim 4 further comprising generator means operably connected to said turbine means for generating electricity upon operation of said turbine means.

6. The stack assembly of claim 2 further comprising heat exchanger means interposed between said anode means and said catalytic burner means, said heat exchanger means being operably connected to an exhaust side of said autothermal reformer to receive hot exhausted hydrogen enriched fuel gas from said reformer, and said heat exchanger means being operable to transfer heat from said hot exhausted hydrogen enriched fuel gas to said depleted hydrogen fuel gas exhaust prior to the latter being delivered to said catalytic burner.

7. A high pressure phosphoric acid fuel cell stack assembly comprising:

(a) a stack of fuel cells for producing electricity, said stack including cathode means, anode means, and heat exchange means;

(b) an autothermal reformer for reacting a hydrocarbon fuel with an air-water vapor gaseous mixture exhausted from said heat exchange means, said reformer being operable to produce a high temperature hydrogen enriched fuel gas for said anode means;

(c) a catalytic burner operable to catalytically burn hydrogen-depleted fuel gas exhausted from said anode means and the air-water vapor gaseous mixture to produce a high temperature burner exhaust gas;

(d) turbocompressor means for providing elevated operating pressures for said assembly, said turbocompressor means being driven by said burner exhaust gas;

(e) condenser means for receiving exhaust from said turbocompressor means and operable to condense a water fog coolant component from the turbocompressor exhaust;

(f) first conduit means for delivering compressed air from said turbocompressor means to said cathode means for passage through said cathode means to an exhaust side of said cathode means, whereat oxygen-depleted air and reaction water are exhausted from said cathode means;

(g) second conduit means for delivering oxygen-depleted air and reaction water from said exhaust side of said cathode means to said stack heat exchange means;

(h) third conduit means for delivering the water fog coolant component from said condenser means to said second conduit means whereby the oxygen-depleted air and reaction water are mixed with the water fog coolant component to form a water droplet-air coolant mixture for circulation through said stack heat exchange means whereby the stack is cooled by vaporization of the water droplet component of the coolant mixture, and the air-water vapor gaseous mixture is exhausted from said stack heat exchange means;

(i) first heat exchanger means operable to bring the high temperature enriched fuel gas from said reformer into heat exhange relationship with the hydrogen-depleted fuel gas from said anode means to raise the temperature of the hydrogen-depleted fuel gas prior to the latter entering said catalytic burner;

(j) second heat exchanger means operable to bring the high temperature hydrogen-enriched fuel gas, after passing through said first heat exchanger means, into heat exchange relationship with the air-water vapor gaseous mixture to raise the temperature of the air-water vapor gaseous mixture and to lower the temperature of the fuel gas to that at which it will be reacted in said anode means; and

(k) third heat exchanger means operable to bring the air-water vapor gaseous mixture and the high temperature catalytic burner exhaust gas into heat exchange relationship after said second heat exchanger to raise the temperature of the air-water vapor gaseous mixture to that required for reaction in said catalytic burner and said autothermal reformer, and to lower the temperature of the burner exhaust gas to that required for driving said turbocompressor means.