Optical brighteners in golf ball covers

• US 4,679,795 A
• Filed: 04/18/1986
• Issued: 07/14/1987
• Est. Priority Date: 08/01/1983
• Status: Expired due to Term

• Current Assignee: Callaway Golf Company
• Original Assignee: Spalding & Evenflo Companies Incorporated
• Inventors: Nesbitt, R. Dennis, Melvin, Terence
• Primary Examiner(s): Lieberman, Allan M.
• Application Number:
  US06/861,532
• Time in Patent Office: 452 Days
• Field of Search: 273/218, 273/235 A, 273/235 R, 524/908, 524/420, 524/430, 524/432, 524/84, 524/100, 524/110
• US Class Current: 473/356
• CPC Class Codes: A63B 37/0024 Materials other than ionomers or polyurethane
• CPC Class Codes: A63B 37/00373 Colour tone
• CPC Class Codes: A63B 37/0074 Two piece balls, i.e. cover and core
• CPC Class Codes: A63B 37/12 Special coverings , i.e. outer layer material balls with finger holes A63B37/0001, golf ball covers A63B37/0023
• CPC Class Codes: Y10S 524/908 Composition having specified shape, e.g. rod, stick, or ball, and other than sheet, film, or fiber

Abstract

The disclosure relates to golf balls and more particularly, to golf ball cover compositions. The disclosure is concerned primarily with composition and method for the enhancement of the color of a golf ball cover by the use of an optical brightener in conjunction with a pigmented golf ball cover composition. This invention is concerned with the enhancement of the color of white golf ball covers. When used in conjunction with a white pigmentation system, the optical brighteners in question enhance the color in the blue spectrum range in order to give the cover a whiter appearance.

Claims

1. A golf ball which incorporates a polymeric material which contains from about one percent 1% to about ten percent 10% of a white pigment wherein said pigmented polymeric material incorporates from about 0.01 to about 0.50 percent of a compatible optical brightener which increases the whiteness of the surface of said golf ball all percentages to total 100 percent.

2. The golf ball of claim 1 wherein said ball has essentially a uniform cross section.

3. The golf ball of claim 1 wherein said ball has a wound or solid center and a cover.

4. The golf ball of claim 1 wherein said surface is formed from a polymeric material selected from the group consisting of polyurethane resins, polyolefin resins and ionic copolymers which are the metal salts of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms.

5. A golf ball having a core and a cover wherein said cover comprises from about 99 to about 89.50 percent of a natural or synthetic polymer, from about one to about ten percent of a white pigment and from about 0.05 to about 0.25 percent of a compatible optical brightener which increases the whiteness of the cover all percentages to total 100 percent.

9. The golf ball of claim 5 wherein said cover is formed from a polymeric material selected from the group consisting of polyurethane resins, polyolefin resins, ionic copolymers which are metal salts of the reaction product of an olefin having from 3 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 2 to 8 carbon atoms and mixtures of said polymers.

13. The golf ball of claim 5 wherein said cover is formed from a member selected from the group consisting of ionic copolymers which are the sodium salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms and the zinc salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms.

17. The golf ball of claim 5 wherein said cover is formed from a mixture of ionic copolymers selected from the group consisting of ionic copolymers which are the sodium salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms and the zinc salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms.

6. A golf ball having a core and a cover wherein said cover comprises from about 99 to about 94.80 percent of a natural or synthetic polymer, from about 1 to about 5 percent of a white pigment and from about 0.05 to about 0.25 percent of a compatible optical brightener which increases the whiteness of the cover all percentages to total 100 percent.

10. The golf ball of claim 6 wherein said cover is formed from a polymeric material selected from the group consisting of polyurethane resins, polyolefin resins, ionic copolymers which are metal salts of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms and mixtures of said polymers.

14. The golf ball of claim 6 wherein said cover is formed from a member selected from the group consisting of ionic copolymers which are the sodium salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms and the zinc salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms.

18. The golf ball of claim 6 wherein said cover is formed from a mixture of ionic copolymers selected from the group consisting of ionic copolymers which are the sodium salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms and the zinc salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms.

7. A golf ball having a core and a cover wherein said cover comprises from about 99 to about 96.90 percent of a natural or synthetic polymer, from about 1 to about 3 percent of a white pigment and from about 0.05 to about 0.10 percent of a compatible optical brightener which increases the whiteness of the cover all percentages to total 100 percent.

11. The golf ball of claim 7 wherein said cover is formed from a polymeric material selected from the group consisting of polyurethane resins, polyolefin resins, ionic copolymers which are metal salts of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms and mixtures of said polymers.

15. The golf ball of claim 7 wherein said cover is formed from a member selected from the group consisting of ionic copolymers which are the sodium salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms and the zinc salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxyic acid having from 2 to 8 carbon atoms.

19. The golf ball of claim 7 wherein said cover is formed from a mixture of ionic copolymers selected from the group consisting of ionic copolymers which are the sodium salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms and the zinc salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms.

8. A golf ball having a core and a cover wherein said cover comprises about 97.9 percent of a natural or synthetic polymer, about 2 percent of a white pigment and from about 0.05 to about 0.10 percent of a compatible optical brightener which increases the whiteness of the cover all percentages to total 100 percent.

12. The golf ball of claim 8 wherein said cover is formed from a polymeric material selected from the group consisting of polyurethane resins, polyolefin resins, ionic copolymers which are metal salts of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms and mixtures of said polymers.

16. The golf ball of claim 8 wherein said cover is formed from a member selected from the group consisting of ionic copolymers which are the sodium salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms and the zinc salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms.

20. The golf ball of claim 8 wherein said cover is formed from a mixture of ionic copolymers selected from the group consisting of ionic copolymers which are the sodium salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms and the zinc salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms.

21. A golf ball having a center and cover wherein said cover comprises from about 99 to about 89.50 percent of a member selected from the group consisting of ionic copolymers which are the sodium salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 2 to 8 carbon atoms and the zinc salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms, from about 1 to about 10 percent of a white pigment which is a member selected from the group consisting of titanium dioxide, zinc oxide, and zinc sulfide, a trace amount of a blue pigment, and from about 0.01 to about 0.50 percent of an optical brightener which is a member selected from the group consisting of 2,5-Bis(5-tert-butyl-2-benzoxazolyl)thiophene, 4,4'"'"'-Bis(2-benzoxazolyl)stilbene, and 7-(2h-naphthol(1,2-d)-triazol-2-yl)-3-phenyl-coumarin all percentages to total 100 percent.

22. A golf ball having a center and cover wherein said cover comprises from about 99 to about 94.80 percent of a member selected from the group consisting of ionic copolymers which are the sodium salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms and the zinc salt of the reaction product of olefin having from 3 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 2 to 8 carbon atoms, from about 1 to about 5 percent of a white pigment which is a member selected from the group consisting of titanium dioxide, zinc oxide, zinc sulfide, a trace amount of a blue pigment, and from about 0.05 to about 0.25 percent of an optical brightener which is a member selected from the group consisting of 2,5-Bis(5-tert-butyl-2-benzoxazolyl)thiophene, 4,4'"'"'-Bis(2-benzoxazolyl)stilbene, and 7-(2h-naphthol(1,2-d)-triazol-2-yl)-3-phenyl-coumarin all percentages to total 100 percent.

23. A golf ball having a center and cover wherein said cover comprises from about 99 to about 96.90 percent of a member selected from the group consisting of ionic copolymers which are the sodium salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms and the zinc salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms, from about 1 to about 3 percent of a white pigment which is a member selected from the group consisting of titanium dioxide, zinc oxide, and zinc sulfide, a trace amount of a blue pigment, and from about 0.05 to about 0.10 percent of an optical brightener which is a member selected from the group consisting of 2,5-Bis(5-tert-butyl-2-benzoxazolyl)thiophene, 4,4'"'"'-Bis(2-benzoxazolyl)stilbene, and 7-(2h-naphthol(1,2-d)-triazol-2-yl)-3-phenyl-coumarin all percentages to total 100 percent.

24. A golf ball having a center and cover wherein said cover comprises about 97.9 percent of a member selected from the group consisting of ionic copolymers which are the sodium salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms and the zinc salt of the reaction product of olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms, about 2 percent of a pigment which is a member selected from the group consisting of titanium dioxide, zinc oxide, and zinc sulfide, and from about 0.05 to about 0.10 percent of an optical brightener which is a member selected from the group consisting of 2,5-Bis(5-tert-butyl-2-benzoxazolyl)thiophene, 4,4'"'"'-Bis(2-benzoxazolyl)stilbene, and 7-(2h-naphthol(1,2-d)-triazol-2-yl)-3-phenyl-coumarin all percentages to total 100 percent.

25. A golf ball having a center and cover wherein said cover comprises from about 99 to about 89.50 percent of a mixture of ionic copolymers which are the sodium salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms and the zinc salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms, about 1 to about 10 percent of a white pigment which is a member selected from the group consisting of titanium dioxide, zinc oxide, and zinc sulfide, a trace amount of a blue pigment and from about 0.01 to about 0.50 percent of an optical brightener which is a member selected from the group consisting of 2,5-Bis(5-tert-butyl-2-benzoxazolyl)thiophene, 4,4'"'"'-Bis(2-benzoxazolyl)stilbene, and 7-(2h-naphthol(1,2-d)-ytriazol-2-yl)-3-phenyl-coumarin all percentages to total 100 percent.

26. A golf ball having a center and cover wherein said cover comprises from about 99 to 94.80 percent of a mixture of ionic copolymers which are the sodium salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms and the zinc salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 2 to 8 carbon atoms, from about 1 to about 5 percent of a white pigment which is a member selected from the group consisting of titanium dioxide, zinc oxide, and zinc sulfide, a trace amount of a blue pigment and from about 0.05 to 0.25 percent of an optical brightener which is a member selected from the group consisting of 2,5-Bis(5-tert-butyl-2-benzoxazolyl)thiophene, 4,4'"'"'-Bis(2-benzoxazolyl)stilbene, and 7-(2h-naphthol(1,2-d)-triazol-2-yl)-3-phenyl-coumarin all percentages to total 100 percent.

27. A golf ball having a center and cover wherein said cover comprises from about 99 to about 96.90 percent of a mixture of ionic copolymers which are the sodium salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms and the zinc salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms, from about 1 to about 3 percent of a white pigment which is a member selected from the group consisting of titanium dioxide, zinc oxide, and zinc sulfide, a trace amount of blue pigment and from about 0.05 to about 0.25 percent of an optical brightener which is a member selected from the group consisting of 2,5-Bis(5-tert-butyl-2-benzoxazolyl)thiophene, 4,4'"'"'-Bis(2-benzoxazolyl)stilbene, and 7-(2h-naphthol(1,2-d)-triazol-2-yl)-3-phenyl-coumarin all percentages to total 100 percent.

28. A golf ball having a center and cover wherein said cover comprises about 97.0 percent of a mixture of ionic copolymers which are the sodium salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms and the zinc salt of the reaction product of an olefin having from 2 to 8 carbon atoms and an unsaturated monocarboxylic acid having from 3 to 8 carbon atoms, about 2 percent of a white pigment which is a member selected from the group consisting of titanium dioxide and zinc sulfide, a trace amount of blue pigment, and about 0.05 percent of 4,4'"'"'-Bis(2-benzoxazolyl)stilbene all percentages to total 100 percent.