Method for restoring the lost capacity of nickel batteries and batteries formed thereby

• US 4,680,241 A
• Filed: 02/25/1985
• Issued: 07/14/1987
• Est. Priority Date: 11/29/1983
• Status: Expired due to Term

• Current Assignee: Bell Telephone Laboratories, Inc. (Nokia Corporation)
• Original Assignee: American Telephone & Telegraph Company (AT&T, Inc.)
• Inventors: Dyer, Christopher K.
• Primary Examiner(s): Hearn, Brian E.
• Assistant Examiner(s): Kalafut, Stephen J.
• Application Number:
  US06/705,050
• Time in Patent Office: 869 Days
• Field of Search: 320/14, 320/21, 320/35, 429/49, 429/50, 429/52, 429/223
• US Class Current: 429/49
• CPC Class Codes: H01M 10/44 Methods for charging or discharging circuits for charging H02J7/00
• CPC Class Codes: H02J 7/00711 with introduction of pulses during the charging process
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A method for partially or fully restoring the lost capacities of nickel batteries, as well as the batteries produced by this method, is disclosed.

In accordance with the inventive method, a nickel battery is cycled at least 10 times, with each cycle including a discharging step during which the capacity achieved at the end of the previous cycle is reduced by at least 5 percent, and a charging step. The charging rate employed during the charging step is greater than about C/10 per hour. Moreover, while the ratio of the amount of charge delivered to the battery during the charging step of each cycle to the amount of charge withdrawn from the battery during the previous cycle is greater than one, this ratio is chosen so that the temperature of the electrolyte of the battery does not exceed about 30 degrees Centigrade.

Claims

1. A method for making a battery which includes a nickel positive electrode, a negative electrode, and an electrolyte, said nickel positive electrode having an initial capacity less than a theoretical capacity, C, of said battery, comprising the step of

cycling said battery at least 10 times, each cycle including both a discharging step during which the amount of charge withdrawn from the battery, q_D, is greater than or equal to about 5 percent of the capacity achieved during the previous cycle, and a charging step

in which the charging rate is greater than C/10 per hour, the amount of charge delivered to said battery during said charging step, q_C, is greater than q_D and is chosen so that a temperature of said electrolyte does not exceed about 30 degrees Centigrade.

2. The method of claim 1 wherein q is chosen so that said temperature of said electrolyte does not exceed about 10 degrees Centigrade.

3. The method of claim 1 wherein q_D is greater than or equal to about 20 percent of the capacity achieved during the previous cycle.

4. The method of claim 1 wherein said charging rate is less than about 6C per hour.

5. The method of claim 1 wherein said charging rate ranges from about c/6 per hour to about 2C per hour.

6. The method of claim 1 wherein the ratio of q_C to q_D is greater than or equal to about 1.01 but less than about 1.6.

7. The method of claim 1 wherein said battery is a nickel-hydrogen battery.

8. The method of claim 1 wherein said battery is a nickel-cadmium battery.

9. The method of claim 1 wherein said battery is a nickel-zinc battery.

10. The method of claim 1 wherein said battery is a nickel-iron battery.