Wetness indicating hot-metal adhesives

• US 4,681,576 A
• Filed: 03/17/1986
• Issued: 07/21/1987
• Est. Priority Date: 03/17/1986
• Status: Expired due to Fees

• Current Assignee: Swift Adhesives Limited
• Original Assignee: Malcolm Nicol & Company
• Inventors: Maletsky, Albert, Colon, Herman
• Primary Examiner(s): Foelak, Morton
• Assistant Examiner(s): NOT, DEFINED
• Application Number:
  US06/839,943
• Time in Patent Office: 491 Days
• Field of Search: 524/271, 524/272, 524/275, 524/322, 524/718, 128/284, 604/287, 604/290 R, 604/361
• US Class Current: 604/361
• CPC Class Codes: A61F 13/42 with wetness indicator or alarm
• CPC Class Codes: A61L 15/56 Wetness-indicators or colourants
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/34 Oxygen-containing compounds, including ammonium and metal salts
• CPC Class Codes: C09J 139/06 Homopolymers or copolymers of N-vinyl-pyrrolidones
• CPC Class Codes: C09J 2301/304 the adhesive being heat-activatable, i.e. not tacky at temperatures inferior to 30°C

Abstract

A wetness indicating hot-melt adhesive which changes color quickly in response to the presence of moisture is disclosed which contains 20 to 70 wt. % of polymer, 35 to 100 wt. % of which is water sensitive polymer; 27 to 60 wt. % of organic acid which is selected from a high acid number fatty acid or a combination of a high acid number fatty acid and other high acid number organic acids; 0 to 30 wt. % of water soluble wax and a wetness indicating agent which changes the color of the composition rapidly in response to moisture therein.

Claims

1. A wetness indicating hot-melt adhesive composition comprising:

(A) 20 to 70 wt.% of total polymer components, said polymer components comprising 35 to 100 wt.% of water sensitive polymer selected from vinyl pyrrolidone homopolymer, vinyl pyrrolidone/vinyl acetate copolymer or a mixture thereof, any balance comprising at least one polymer selected from the group consisting of ethylene/vinyl acetate copolymer, ethylene/acrylic acid copolymer and polyamide,

(B) 27 to 60 wt.% of organic acid selected from the group of

(a) at least one free monobasic saturated or unsaturated fatty acid having an acid number above 137, and wherein the proportion of said free monobasic saturated or unsaturated fatty acid to said total polymer components in the composition is such that the pH of the composition, when moist is within a range of 3 to 7;

(b) 15 to 50 wt.% of the fatty acid in combination with 10 to 55 wt.% of at least one other organic acid having an acid number above 130;

(C) 0 to 30 wt.% of a water soluble wax;

(D) a wetness indicating agent capable of causing the composition to change color in response to the presence of moisture in the composition and within said pH range of 3 to 7 in a relatively rapid time compared to that of broadly similar prior art, and in an amount effective to provide the composition with a readily visible color when wet which is distinct from the color of the dry composition.

2. The wetness indicating hot-melt adhesive composition according to claim 1, wherein said other organic acid having an acid number above 130 is selected from the group consisting of rosin, hydrogenated rosin and tall oil acid.

3. The wetness indicating hot-melt adhesive composition according to claim 1, which contains 27 to 60 wt.% of the free monobasic saturated or unsaturated fatty acid.

4. The wetness indicating hot-melt adhesive composition according to claim 1, in which the ratio of said free monobasic saturated or unsaturated fatty acid to said total polymer components is about 1:

2 to 2;

1.

5. The wetness indicating, hot-melt adhesive composition according to claim 1, in which the wetness indicating agent is Bromophenol Blue.

6. The wetness indicating hot-melt adhesive composition according to claim 1 which contains about 5 to 25 wt.% of water soluble wax.

7. The wetness indicating hot-melt adhesive composition according to claim 1 which contains about 10 to 20 wt.% of water soluble wax.

8. An article comprising a substrate and a coating of the wetness indicating hot-melt adhesive composition according to claim 1 on at least one surface of said substrate.

9. The article according to claim 8, wherein said substrate is a foil substrate.

10. A diaper comprising a moisture absorbent substrate, a water resistant covering for said absorbent substrate, and the wetness indicating hot-melt adhesive according to claim 1 coated on at least a portion of an inner surface of the water resistant covering.

11. A wetness indicating hot-melt adhesive composition comprising:

(A) 20 to 70 wt.% of total polymer components, said polymer components comprising 35 to 100 wt.% of water sensitive polymer selected from vinyl pyrrolidone homopolymer, vinyl pyrrolidone/vinyl acetate copolymer or a mixture thereof, any balance comprising at least one polymer selected from the group consisting of ethylene/vinyl acetate copolymer, ethylene/acrylic acid copolymer and polyamide,

(B) 27 to 60 wt.% of organic acid selected from the group of

(a) at least one free monobasic saturated or unsaturated fatty acid having an acid number above 137, and wherein the proportion of said fatty acid to said total polymer components in the composition is such that the pH of the composition, when moist is within a range of 3 to 7;

(b) 15 to 50 wt.% of the fatty acid in combination with 10 to 55 wt.% of at least one other organic acid having an acid number above 130;

(C) 0 to 30 wt.% of a water soluble wax including polyoxyethylene glycol; and

(D) a wetness indicating agent capable of causing the composition to change color in response to the presence of moisture in the composition and within said pH range of 3 to 7 in a relatively rapid time compared to that of broadly similar prior art, and in an amount effective to provide the composition with a readily visible color when wet which is distinct from the color of the dry composition.

12. A diaper comprising a moisture absorbent substrate, a water resistant covering for said absorbent substrate, and the wetness indicating hot-melt adhesive according to claim 11 coated on at least a portion of an inner surface of the water resistant covering.

13. A wetness indicating hot-melt adhesive composition comprising:

(A) 20 to 70 wt.% of total polymer components, said polymer components comprising 35 to 100 wt.% of water sensitive polymer selected from vinyl pyrrolidone homopolymer, vinyl pyrrolidone/vinyl acetate copolymer or a mixture thereof, any balance comprising at least one polymer selected from the group consisting of ethylene/vinyl acetate copolymer, ethylene/acrylic acid copolymer and polyamide,

(B) 27 to 60 wt.% of organic acid selected from the group of

(a) at least one free monobasic saturated or unsaturated fatty acid having an acid number above 137, and wherein the proportion of said fatty acid to said total polymer components in the composition is such that the pH of the composition, when moist is within a range of 3 to 7;

(b) 15 to 50 wt.% of the fatty acid in combination with 10 to 55 wt.% of at least one other organic acid having an acid number above 130;

(C) 0 to 30 wt.% of a water soluble wax including polyoxyethylene glycols; and

(D) a wetness indicating agent including Bromophenol Blue capable of causing the composition to change color in response to the presence of moisture in the composition and within said pH range of 3 to 7 in a relatively rapid time compared to that of broadly similar prior art, and in an amount effective to provide the composition with a readily visible color when wet which is distinct from the color of the dry composition.

14. A diaper comprising a moisture absorbent substrate, a water resistant covering for said absorbent substrate, and the wetness indicating hot-melt adhesive according to claim 13 coated on at least a portion of an inner surface of the water resistant covering.