Gasification of black liquor

• US 4,682,985 A
• Filed: 09/23/1985
• Issued: 07/28/1987
• Est. Priority Date: 04/21/1983
• Status: Expired due to Fees

• Current Assignee: Rockwell International Corporation
• Original Assignee: Rockwell International Corporation
• Inventors: Kohl, Arthur L.
• Primary Examiner(s): Kratz, Peter
• Application Number:
  US06/779,321
• Time in Patent Office: 673 Days
• Field of Search: 48/197 R, 48/203, 48/209, 162/30.1, 162/30.11, 423/207, 423/DIG. 3, 60/39.02
• US Class Current: 48/197.00R
• CPC Class Codes: C10J 2300/093 Coal
• CPC Class Codes: C10J 2300/0943 Coke
• CPC Class Codes: C10J 2300/0946 Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
• CPC Class Codes: C10J 2300/0956 Air or oxygen enriched air
• CPC Class Codes: C10J 2300/0959 Oxygen
• CPC Class Codes: C10J 2300/1671 with the production of electricity
• CPC Class Codes: C10J 2300/1675 making use of a steam turbine
• CPC Class Codes: C10J 2300/1846 Partial oxidation, i.e. injection of air or oxygen only
• CPC Class Codes: C10J 2300/1884 with one stream being synthesis gas
• CPC Class Codes: C10J 2300/1892 with one stream being water/steam
• CPC Class Codes: C10J 3/57 Gasification using molten salts or metals C10J3/02, C10J3/46 take precedence
• CPC Class Codes: C10J 3/74 Construction of shells or jackets
• CPC Class Codes: C10J 3/78 High-pressure apparatus
• CPC Class Codes: Y02E 20/16 Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
• CPC Class Codes: Y02E 20/18 Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
• CPC Class Codes: Y10S 423/03 Papermaking liquor

Abstract

A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediatley above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone.

Claims

1. A process for treating a concentrated aqueous black liquor carbonaceous material and alkali metal sulfur compounds to form a combustible gas and a sulfide-rich melt comprising:

(a) providing a gasifier vessel maintained at a pressure of from about 1 to 50 atmospheres and containing a relatively shallow molten salt pool at its bottom within a sump equipped with an overflow discharge, said vessel having

(I) a black liquor drying zone at its upper parts,

(ii) a black liquor solids gasification zone located below the drying zone, and

(iii) a molten salt sulfur reduction zone comprising said molten salt pool;

(b) introducing into the top of said drying zone the concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds;

(c) evaporating water from said concentrated aqueous black liquor in said drying zone by direct contact of said aqueous black liquor with the hot gas rising from the gasification zone to produce dried black liquor solids, which fall into said gasification zone, and a cooled combustible gas container water vapor said combustible gas being at a temperature below the melting point of entrained droplets of the molten salt causing solification of said droplets;

(d) introducing a first portion of an oxygen-containing gas into the gas space in the gasification zone located below the drying zone immediately above the molten salt pool to partially oxidize and gasify a fraction of the carbonaceous material in said dried black liquor solids falling through said zone to form a hot combustible gas;

(e) introducing a second portion of said oxygen-containing gas beneath the surface of said molten salt pool in an amount sufficient to cause gasification of essentially all carbonaceous material entering the pool from the gasification zone but not sufficent to create oxidizing conditions in the pool, the formed gas rising from said pool, the total amount of said first and second portion of oxygen-containing gas constituting between 25 and 55% of the amount of oxygen-containing gas required for complete combustion of the black liquor feed and representing the total amount of oxygen-containing gas fed to said gasifier vessel;

(f) withdrawing said cooled combustible gas having a higher heating value of at least about 90 Btu/scf (dry basis) from an upper portion of said drying zone; and

(g) withdrawing from said overflow discharge in the molten salt reduction zone a melt in which the sulfur content is predominantly in the form of alkali metal sulfide.

2. The process of claim 1 wherein each of said first and second portions of the oxygen-containing gas constitutes from 30 to 70% of the total amount of oxygen-containing gas fed to the vessel.

3. The process claim 2 wherein said oxygen-containing gas comprises air.

4. The process of claim 1 wherein said gasifier vessel is maintained at a pressure in the range of from about 3 to 30 atmospheres and wherein the concentrated aqueous black liquor fed to the vessel comprises at least 45 wt % solids and has a higher heating value of at least about 3200 Btu/lb.

5. The process of claim 1 wherein the hot gas leaving the gasification zone is at a temperature of 870°

-1200°

C. and the cooled combustible gas leaving the drying zone is at a temperature of 350°

-850°

C.

6. The process of claim 1 wherein the temperature in the reduction zone is 860°

-1100°

C.

7. The process of claim 1 wherein the total heat loss from said gasification and reduction zone is less than about 600 Btu per pound of black liquor fed to the gasifier vessel.