Nylon copolymer and nylon blends and films made therefrom

• US 4,683,170 A
• Filed: 01/21/1986
• Issued: 07/28/1987
• Est. Priority Date: 06/29/1984
• Status: Expired due to Term

• Current Assignee: Pechiney Plastic Packaging Incorporated (Rio Tinto Limited)
• Original Assignee: United States Gypsum Company (GEBR Knauf Verwaltungsgesellschaft KG)
• Inventors: Galloway, Deane E., Tse, Samuel W.
• Primary Examiner(s): Buffalow, Edith
• Application Number:
  US06/820,350
• Time in Patent Office: 553 Days
• Field of Search: 428/35, 428/349, 428/354, 428/516, 428/474.4, 428/475.8, 428/476.3, 525/432
• US Class Current: 428/349
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: C08L 77/02 Polyamides derived from omega-amino carboxylic acids or from lactams thereof C08L77/10 takes precedence
• CPC Class Codes: Y10T 428/2826 Synthetic resin or polymer
• CPC Class Codes: Y10T 428/2848 Three or more layers
• CPC Class Codes: Y10T 428/31725 Of polyamide
• CPC Class Codes: Y10T 428/31743 Next to addition polymer from unsaturated monomer[s]
• CPC Class Codes: Y10T 428/3175 Next to addition polymer from unsaturated monomer[s]
• CPC Class Codes: Y10T 428/31913 Monoolefin polymer

Abstract

A novel composition of matter having surprising physical properties when fabricated into multiple layer films is disclosed. The composition is generally a blend of nylon 6 with a nylon copolymer comprised of nylon 6 and a second nylon polymer. The second nylon polymer is 2.5 to 10 mole percent of the overall composition. The remaining 97.5% to 90% of the composition is the nylon 6 and the nylon 6 component of the copolymer. The nylon composition may be comprised entirely of a nylon copolymer having 90% to 97.5% nylon 6 and 10% to 2.5% of a second nylon polymer. The multiple layer films fabricated with the nylon compositions show unexpected range of thermoforming and heat sealing capabilities and good heat resistance, similar to that of nylon 6.

Claims

1. A multiple layer film having two surfaces and comprising a first heat sealable layer on one surface thereof and a second nylon layer on the other surface thereof, and wherein the composition of said nylon layer is a blend of 40% to 75% by weight nylon 6 and 60% to 25% by weight of a nylon copolymer wherein the copolymer is 80% to 90% moieties of a first polymer of nylon 6 and 20% to 10% moieties of a second polymer of nylon;

the overall composition of the blend comprising 2.5% to 10% moieties of said second polymer of nylon.

2. A multiple layer film as in claim 1 wherein the overall composition of the blend in said nylon surface layer is 5% to 7.5% moieties of said second polymer of nylon, said second polymer of nylon being chosen from the group consisting of nylon 66 and nylon 12.

3. A multiple layer film as in claim 1 and including a functionally adhesive polymer layer between said first and second layers.

4. A multiple layer film as in claim 2 and including a functionally adhesive polymer layer between said first and second layers.

5. A multiple layer heat sealable film having two surfaces, said film comprising:

(a) a first heat sealable layer on one surface of the film;

(b) a second nylon layer on the other surface of the film;

(c) a third polymeric layer of ethylene vinyl alcohol copolymer between said first and second layers; and

(d) a fourth adhesive layer between said first and third layers, said second layer comprising a blend of nylon polymer and nylon copolymer;

said blend being 40% to 75% by weight nylon 6 and 60% to 25% by weight of a nylon copolymer wherein said copolymer is 80% to 90% moieties of a first polymer of nylon 6 and 20% to 10% moieties of a second polymer of nylon,

the overall composition of said blend comprising 2.5% to 10% moieties of said second polymer of nylon.

6. A multiple layer film as in claim 5 and wherein said second polymer of nylon is chosen from the group consisting of nylon 66 and nylon 12.

7. A multiple layer film as in claim 5 and including a fifth layer of polyethylene or polypropylene interposed between said second and third layers.

8. A multiple layer film as in claim 5 and including a sixth layer of a polymer or copolymer of a polypropylene or polyethylene between said first and fourth layers.

9. A multiple layer film as in claim 6 and including a fifth layer of a polyethylene or polypropylene between said second and third layers.

10. A multiple layer film as in claim 6 and including a sixth layer of a polymer or copolymer of a polyethylene or polypropylene between said first and fourth layers.

11. A multiple layer film as in claim 7 and including a sixth layer of a polymer or copolymer of a polyethylene or polypropylene between said first and fourth layers.

12. A multiple layer film as in claim 8 wherein said second polymer of nylon comprises nylon 66 and is present as 5.0% to 5.5% of the overall blend composition of said second layer.

13. A multiple layer film as in claim 10 wherein said second polymer of nylon comprises nylon 66 and is present as 5.0% to 5.5% of the overall blend composition of said second layer.

14. A multiple layer film as in claim 7 wherein said second polymer of nylon comprises nylon 66 and is present as 7.25% to 7.75% of the overall blend composition of said second layer.

15. A multiple layer film as in claim 9 wherein said second polymer of nylon comprises nylon 66 and is present as 7.25% to 7.75% of the overall blend composition of said second layer.

16. A multiple layer film as in claim 5 wherein said fourth layer is an adhesive based on an ethylene polymer or copolymer.

17. A multiple layer film as in claim 6 wherein said fourth layer is an adhesive based on an ethylene polymer or copolymer.

18. A multiple layer film as in claim 7 wherein said fourth layer is an adhesive based on an ethylene polymer or copolymer.

19. A multiple layer film as in claim 8 wherein said fourth layer is an adhesive based on an ethylene polymer or copolymer.

20. A multiple layer film as in claim 9 wherein said fourth layer is an adhesive based on an ethylene polymer or copolymer.

21. A multiple layer film as in claim 10 wherein said fourth layer is an adhesive based on an ethylene polymer or copolymer.

22. A multiple layer film as in claim 11 wherein said fourth layer is an adhesive based on an ethylene polymer or copolymer.

23. A multiple layer film as in claim 12 wherein said fourth layer is an adhesive based on an ethylene polymer or copolymer.

24. A multiple layer film as in claim 13 wherein said fourth layer is an adhesive based on an ethylene polymer or copolymer.

25. A multiple layer film as in claim 15 wherein said fourth layer is an adhesive based on an ethylene polymer or copolymer.

26. A multiple layer film as in claim 7 said first layer comprising surlyn;

said second layer being a blend of equal parts by weight of nylon 6 and a copolymer of nylon 6,66, said copolymer comprising 85 mole percent nylon 6 and 15 mole percent nylon 66;

said fifth layer comprising a low density polyethylene adhesive.

27. A multiple layer film as in claim 19 and wherein the composition of said sixth layer is chosen from the group consisting of low density polyethylene and ethylene vinyl acetate copolymer.

28. A multiple layer film as in claim 27 and wherein the composition of said second layer is a blend of about 65% by weight nylon 6 and 35% by weight of a copolymer of nylon, said copolymer being about 85 mole percent nylon 6 and 15 mole percent nylon 66, and wherein the composition of said first layer comprises surlyn.

29. A multiple layer film as in claim 8 wherein said second polymer of nylon comprises nylon 66 and is present as 7.25% to 7.75% of the overall blend composition of said second layer.

30. A multiple layer film as in claim 29 wherein said fourth layer is an adhesive based on an ethylene polymer or copolymer.

31. A multiple layer film as in claim 30 and wherein the composition of said sixth layer is chosen from the group consisting of low density polyethylene and ethylene vinyl acetate copolymer.

32. A multiple layer film having two surfaces and comprising a first heat sealable layer on one surface thereof and a second nylon layer on the other surface thereof, and wherein the composition of said second nylon layer is 90 to 97.5 mole percent nylon 6 and 10 to 2.5 mole percent of a second polymer of nylon.

33. A multiple layer film as in claim 32 wherein said second polymer of nylon is chosen from the group consisting of nylon 66 and nylon 12.

34. A multiple layer film as in claim 32 wherein the composition of said second nylon layer is 92.5 to 95 mole percent nylon 6 and 7.5 to 5 mole percent of said second polymer of nylon.

35. A multiple layer film as in claim 33 wherein the composition of said second nylon layer is 92.5 to 95 mole percent nylon 6 and 7.5 to 5 mole percent of said second polymer of nylon.

36. A multiple layer film as in claim 32 and further comprising a third polymeric layer of ethylene vinyl alcohol copolymer between said first and second layers and a fourth adhesive layer between said first and third layers.

37. A multiple layer film as in claim 33 and further comprising a third polymeric layer of ethylene vinyl alcohol copolymer between said first and second layers and a fourth adhesive layer between said first and third layers.

38. A multiple layer film as in claim 32 and wherein the composition of said first layer is surlyn, the composition of said second nylon layer is 92.25 to 92.75 mole percent nylon 6 and 7.75 to 7.25 mole percent of said second nylon polymer, said film further comprising a fourth adhesive layer between said first and third layers, said adhesive layer being based on a polymer chosen from the group consisting of ethylene vinyl acetate copolymer and low density polyethylene;

and a fifth layer between said second and third layers, said fifth layer being based on a polymer chosen from the group consisting of polyethylene and polypropylene.

39. A multiple layer film as in claim 38 and wherein said fourth adhesive layer is based on ethylene vinyl acetate copolymer and said fifth layer is based on a low density polyethylene.

40. A multiple layer film as in claim 32 and wherein the composition of said first layer is surlyn, the composition of said second nylon layer is 94.5 to 95 mole percent nylon 6 and 5 to 5.5 mole percent of said second nylon polymer, said film further comprising a fourth adhesive layer between said first and third layers, said adhesive layer being based on a polymer from the group consisting of ethylene vinyl acetate copolymer and low density polyethylene;

and a sixth layer between said first and fourth layers, said sixth layer being a polymer or copolymer of polypropylene or polyethylene.

41. A multiple layer film as in claim 40 and wherein said fourth adhesive layer is based on ethylene vinyl acetate copolymer and said sixth layer is based on an ethylene vinyl acetate.