Process for the sensitization of an oxidation/reduction photocatalyst, and photocatalyst thus obtained

• US 4,684,537 A
• Filed: 12/27/1985
• Issued: 08/04/1987
• Est. Priority Date: 04/30/1984
• Status: Expired due to Fees

• Current Assignee: Re Stiftung
• Original Assignee: R E. Stiftung
• Inventors: Serpone, Nick, Duonghong, Dung, Graetzel, Michael
• Primary Examiner(s): Newsome, John H.
• Application Number:
  US06/824,694
• Time in Patent Office: 585 Days
• Field of Search: 427/53.1, 427/54.1, 427/217, 427/215, 204/157.4, 204/157.41, 204/157.5, 204/157.52
• US Class Current: 427/554
• CPC Class Codes: B01J 23/462 Ruthenium
• CPC Class Codes: C01B 3/042 Decomposition of water
• CPC Class Codes: C09K 9/02 Organic tenebrescent materials
• CPC Class Codes: G03F 7/029 Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
• CPC Class Codes: Y02P 20/133 Renewable energy sources, e.g. sunlight

Abstract

A photocatalyst for photodecomposition of liquids is sensitized to visible light by chemically bonding to the catalyst a complex of a transition metal with a bipyridyl or phenanthrolyl type ligand.

Claims

1. A process for the sensitization of a titanium oxide-based oxidation/reduction photocatalyst, which comprises chemically bonding to its surface a chromophore consisting of a fragment of a complex of a transition metal with a ligand of the bipyridyl or phenanthrolyl type, causing the light absorption band of the catalyst to shift into the visible region.

2. The process as claimed in claim 1, wherein the chromophore consists of a fragment of a ruthenium, chromium or iron complex.

3. The process as claimed in one of claims 1 or 2 wherein the said chromophore consists of a complex fragment of the formula:

space="preserve" listing-type="equation">RuL.sub.2.sup.++

in which the symbol L represents the ligand diisopropyl 2,2'"'"'-bipyridyl-4,4'"'"'dicarboxylate.

4. The process as claimed in claim 3, wherein the photocatalyst is irradiated in the presence of an acid aqueous solution of a complex of the formula:

space="preserve" listing-type="equation">(RuL.sub.3).sup.++ 2X.sup.-

in which the symbol L is defined in claim 6 and X represents a halogen atom.

5. The process as claimed in claim 4, wherein irradiation is carried out at a temperature of between 50°

C. and the boiling point of the solution of complex and wherein the said solution has a pH of between 1 and 3.

8. The process as claimed in claim 4 wherein said chromophore is the product of a reaction involving the loss of at least one ligand from said complex of the formula:

space="preserve" listing-type="equation">RuL.sub.3.sup.++

6. A process for the sensitization of a semiconductor-based oxidation/reduction photocatalyst, which comprises chemically bonding to its surface a chromophore consisting of a fragment of a complex of a transition metal with a ligand of the bipyridyl or phenanthrolyl type, causing the light absorption band of the catalyst to shift into the visible region.

7. A process for the sensitization of a titanium oxide-based oxidation/reduction photocatalyst which comprises chemically bonding to its surface a chromophore consisting of a fragment selected from the group consisting of ruthium, chromium and iron complexes with the ligand diisopropyl 2,2'"'"'-bipyridyl-4,4'"'"'-dicarboxylate, causing the light absorption band of the catalyst to shift into the visible region.