High current density cell

• US 4,687,558 A
• Filed: 05/05/1986
• Issued: 08/18/1987
• Est. Priority Date: 07/02/1984
• Status: Expired due to Fees

• Current Assignee: OLIN Corporation
• Original Assignee: OLIN Corporation
• Inventors: Woodard, Kenneth E. Jr., Justice, David D.
• Primary Examiner(s): Niebling, John F.
• Assistant Examiner(s): Chapman, Terryence
• Application Number:
  US06/859,956
• Time in Patent Office: 470 Days
• Field of Search: 204/1 R, 204/59, 204/98, 204/128, 204/252, 204/253, 204/257, 204/258, 204/282, 204/283, 204/290 R, 204/294
• US Class Current: 205/516
• CPC Class Codes: C25B 1/46 in diaphragm cells
• CPC Class Codes: C25B 11/03 perforated or foraminous
• CPC Class Codes: C25B 9/73 of the filter-press type

Abstract

A filter press membrane electrolytic cell having at least one cathode and one anode sandwiched about a permselective ion exchange membrane which employs a cathode having a first layer and a second layer cooperative with the membrane such that the voltage coefficient during operation at current densities greater than 4.0 kiloamperes per square meter is less than about 0.20 volts per kiloampere per square meter.

Claims

1. In a filter press membrane electrolytic cell having at least one cathode and one anode sandwiched about a permselective ion exchange membrane having a first side adjacent the cathode and a second side adjacent the anode, the improvement comprising in combination:

a. a dual cathode having a first layer and a second layer, the first layer being an active surface cooperative with an immediately adjacent the first side of the membrane and the second layer being a supporting structure for the first layer such that an increased number of electrical current flow paths from the cathode to the membrane are provided; and

b. the membrane being surface modified on at least the first side adjacent the cathode so that reduced resistance at the cathode-membrane junction is achieved to permit cell operation at current densities greater than about 4.0 kiloamperes per square meter with a voltage coefficient less than about 0.20 volts per kiloampere per square meter while maintaining a value for the constant in a cell voltage equation equal to the linear extrapolation to zero current density of the slope of the total cell voltage versus current density plot, wherein the cell voltage equation is Vcell=Constant+(Voltage Coefficient)(Current Density).

2. The apparatus according to claim 1 wherein the cathode is a lower overvoltage cathode.

3. The apparatus according to claim 1 wherein the anode is a lower overvoltage anode.

4. The apparatus according to claim 2 wherein the cathode is a low overvoltage cathode with a hydrogen overvoltage of not greater than about 0.3 volts at about 9.5 kiloamperes per square meter.

5. The apparatus according to claim 3 wherein the anode is a low overvoltage anode with a chlorine overvoltage of not greater than about 0.4 volts at about 9.5 kiloamperes per square meter.

6. The apparatus according to claim 1 wherein the voltage coefficient during operation is from about 0.10 to about 0.20 volts per kiloampere per square meter.

7. The apparatus according to claim 1 wherein there is no gap between the first layer of the cathode and the membrane.

8. The apparatus according to claim 1 wherein there is no gap between the anode and the membrane.

9. The apparatus according to claim 1 wherein there is a gap of about 1.0 millimeter or less between the first layer of the cathode and the membrane.

10. The apparatus according to claim 1 wherein the first layer of the cathode is comprised of a first foraminous metal structure from about 0.010 to about 0.045 inches thick.

11. The apparatus according to claim 10 wherein the first foraminous metal structure is selected from the group consisting of nickel, Raney-nickel or Raney-nickel-molybdenum, lanthanum-nickel and lanthanum-pentanickel.

12. The apparatus according to claim 10 wherein the first foraminous metal structure further consists of a coating selected from the group consisting of Raney-nickel, Raney-nickel-molybdenum, lanthanum-pentanickel and lanthanum-nickel.

13. The apparatus according to claim 12 wherein the first foraminous metal structure is a mesh design with a plurality of openings therein.

14. The apparatus according to claim 1 wherein the first layer of the cathode is comprised of a reticulate mat of predetermined thickness.

15. The apparatus according to claim 1 wherein the second layer of the cathode is comprised of a second foraminous metal structure of a thickness greater than the first foraminous metal structure.

16. The apparatus according to claim 15 wherein the second foraminous metal structure is about 0.015 to about 0.045 inches thick.

17. The apparatus according to claim 16 wherein the second foraminous metal structure is of an open mesh design with a plurality of openings therein which are about 0.5 inches by about 1.25 inches.

18. The apparatus according to claim 13 wherein the second foraminous metal structure is of an open mesh design with a plurality of openings therein which are larger than the plurality of openings in the first foraminous metal structure.

19. The apparatus according to claim 1 wherein the second layer of the cathode is comprised of a separator plate of generally rectangular shape having a top and a bottom and a first side and a second side with generally parallel extending support ribs attached to the first side adjacent the first layer of the cathode between the top and the bottom.

20. The apparatus according to claim 19 wherein the second layer further comprises a mesh structure intermediate the support ribs and the first layer.

21. A method of operating a filter press membrane electrolytic cell having at least one cathode and one anode sandwiched about a permselective ion exchange membrane, comprising the steps of

a. operating the cell at greater than a 4.0 kiloampere per square meter current density at about one atmosphere pressure;

b. maintaining the cell at a voltage coefficient less than or equal to about 0.20 volts per kiloampere per square meter; and

c. maintaining a value for a constant in a cell voltage equation equal to the linear extrapolation to zero current density of the total cell voltage versus current density plot wherein the cell voltage equation is Vcell=Constant+(Voltage Coefficient)(Current Density).

22. The method according to claim 21 further comprising maintaining the anolyte temperature less than or equal to 98°

C.

23. The method according to claim 21 further comprising maintaining no gap between the cathode and the membrane.

24. The method according to claim 23 further comprising maintaining no gap between the anode and the membrane.

25. The method according to claim 21 further comprising maintaining a gap of about 1.0 millimeters or less between the cathode and the membrane.

26. The method according to claim 21 further comprising operating the filter press membrane cell with a low overvoltage cathode having a hydrogen overvoltage of not greater than about 0.3 volts at about 9.5 kiloamperes per square meter.

27. The method according to claim 21 further comprising operating the filter press membrane cell with a low overvoltage anode having a chlorine overvoltage of not greater than about 0.4 volts at about 9.5 kiloamperes per square meter.

28. The method according to claim 21 further comprising operating the filter press membrane cell with a cathode having a first layer with an active surface and a second layer supporting the first layer.