Infrared gas analyzer with automatic zero adjustment

• US 4,687,934 A
• Filed: 01/10/1986
• Issued: 08/18/1987
• Est. Priority Date: 01/10/1986
• Status: Expired due to Term

• Current Assignee: AC Limited (Emirate of Dubai (United Arab Emirates))
• Original Assignee: Andros Anlayzers Incorporated
• Inventors: Griffith, Craig J., Passaro, Robert E., Rogers, Raymond E.
• Primary Examiner(s): FALCONE, JANICE ARRINGTON
• Application Number:
  US06/818,342
• Time in Patent Office: 585 Days
• Field of Search: 250/252.1, 250/338 R, 250/339, 250/341, 250/343, 250/344, 250/345
• US Class Current: 250/343
• CPC Class Codes: G01N 2021/3159 Special features of multiplexing circuits
• CPC Class Codes: G01N 2021/3166 using separate detectors and filters
• CPC Class Codes: G01N 21/274 Calibration, base line adjustment, drift correction
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis
• CPC Class Codes: G01N 2201/126 Microprocessor processing
• CPC Class Codes: G01N 2201/1273 Check triggered by sensing conditions, e.g. ambient changes
• CPC Class Codes: G01N 2201/12769 and adjusting controls, e.g. zero and 100 %

Abstract

Automatic zeroing apparatus zeroes an infrared gas analyzer automatically upon the occurrence of preselected conditions to indicate zero in the absence of absorption of infrared radiation by a gas mixture being analyzed. The gas analyzer has a sample cell for containing a gas mixture to be analyzed. Infrared radiation directed through the sample cell is detected at a preselected wavelength to produce a detection signal. A signal processor outputs a signal systematically related to the difference between the detection signal and a reference signal. For zeroing the sample cell is filled with gas substantially nonabsorbent of infrared radiation at the respective characteristic wavelength. A comparator produces an error signal when the output signal differs from zero. A gain control automatically controls the signal level of the detection signal to reduce the output signal substantially to zero with the nonabsorbent gas filling the sample cell. The preselected conditions may include the passage of a predetermined time and a temperature drift beyond a predetermined limit.

Claims

1. Automatic zeroing apparatus for zeroing an infrared gas analyzer automatically upon the occurrence of preselected conditions to indicate zero in the absence of absorption of infrared radiation by a gas mixture being analyzed, the gas analyzer having a sample cell for containing a gas mixture to be analyzed, source means for directing infrared radiation through the sample cell over a range of wavelengths, direction means responsive to infrared radiation at at least one respective preselected wavelength to produce at least one repective detection signal systematically related to the infrared radiation at the respective preselected wavelength passing through the sample cell from the source means which respective wavelength corresponds to the absorption wavelength characteristic of a respective predetermined gas, and signal processing means responsive to said at least one direction signal for indicating the relative concentration of the respective predetermined gas in the mixture being analyzed, said signal processing means including reference means for producing a reference signal, and output means responsive to said at least one detection signal and said reference signal for outputting an output signal systematically related to the difference between said at least one detection signal and said reference signal, said automatic zeroing apparatus comprising:

means for filling the sample cell with gas substantially nonabsorbent of infrared radiation at the respective characteristic wavelength,

comparator means responsive to said output signal for producing an error signal when said output signal differs from zero, and

gain control means responsive to said error signal for automatically controlling the signal level of said at least one detection signal to reduce said output signal substantially to zero with said substantially nonabsorbent gas filling the sample cell.

2. Automatic zeroing apparatus for zeroing an infrared gas analyzer automatically upon the occurrence of preselected conditions to indicate zero in the absence of absorption of infrared radiation by a gas mixture being analyzed, the gas analyzer having a sample cell for containing a gas mixture to be analyzed, source means for directing infrared radiation through the sample cell over a range of wavelengths, detection means responsive to infrared radiation at at least one respective preselected wavelength to produce at least one respective detection signal systematically related to the infrared radiation at the respective preselected wavelength passing through the sample cell from the source means which respective wavelength corresponds to the absorption wavelength characteristic of a respective predetermined gas, and signal processing means responsive to said at least one detection signal for indicating the relative concentration of the respective predetermined gas in the mixture being analyzed, said signal processing means including reference means for producing a reference signal, and output means responsive to said at least one detection signal and said reference signal for outputting an output signal systematically related to the difference between said at least one detection signal and said reference signal, said automatic zeroing apparatus comprising:

means for filling the sample cell with gas substantially nonabsorbent of infrared radiation at the respective characteristic wavelength;

comparator means responsive to said output signal for producing an error signal when said output signal differs from zero; and

gain control means responsive to said error signal for automatically controlling the signal level of said at least one detection signal to reduce said output signal substantially to zero with said substantially nonabsorbent gas filling the sample cell, said gain control means having a zero mode in which the analyzer is zeroed and a normal mode in which analysis is made and comprising mode control means for placing said gain control means in said zero mode, means for operating said mode control means periodically to place said gain control means in said zero mode periodically, means associated with said zero mode for operating said means for filling to fill said sample cell with said substantially nonabsorbent gas, means in said zero mode responsive to said error signal for adjusting the signal level of said detection signal by a factor to balance said reference signal to reduce said output signal substantially to zero, means for storing a representation of said factor, and means in the normal mode for adjusting the signal level by said factor according to said representation stored from the last preceding zero mode, such that after the zero mode said analyzer remains calibrated in the normal mode in the presence of an absorbing gas being analyzed.

3. Automatic zeroing apparatus according to claim 2 further including means responsive to said output signal for generating a high concentration signal when said output signal exceeds a predetermined limit, and means responsive to said high concentration signal for inhibiting said mode control means from entering said zero mode while the concentration of the respective gas is greater than that corresponding to said predetermined limit.

4. Automatic zeroing apparatus according to claim 3 including electronic calibration means for adding a calibration offset signal to said reference signal during calibration, and means responsive to operation of said electronic calibration means for inhibiting the operation of said mode control means from entering said zero mode during electronic calibration.

5. Automatic zeroing apparatus according to claim 3 wherein said respective gas is carbon dioxide.

6. Automatic zeroing apparatus according to claim 2 further including means under the control of an operator for generating a zero command signal, said mode control means being responsive to said zero command signal to place said gain control means in said zero mode.

7. Automatic zeroing apparatus according to claim 2 wherein said gain control means includes a warm-up mode entered upon start-up of the apparatus and further including means in association with said warm-up mode for operating said means for filling to fill said sample cell with said substantially nonabsorbent gas, means in said warm-up mode responsive to said error signal for periodically adjusting the signal level of said detection signal to drive said output signal substantially to zero, and means responsive to successive adjustments of said signal level for operating said mode control means to place said gain control means in said zero mode when successive adjustments are within a predetermined difference.

8. Automatic zeroing apparatus according to claim 7 wherein said predetermined gas is carbon monoxide.

9. Automatic zeroing apparatus according to claim 2 including electronic calibration means for adding a calibration offset signal to said reference signal during calibration, and means responsive to operation of said electronic calibration means for inhibiting the operation of said mode control means from entering said zero mode during electronic calibration.

10. Automatic zeroing apparatus according to claim 2 further including temperature indicating means responsive to temperature for producing a current temperature signal indicative of ambient temperature, means for storing said temperature signal produced during a zero mode, means responsive to said stored temperature signal for providing first and second temperature offset signals corresponding to the offset of temperature above and below the ambient temperature corresponding to said stored signal by at least one predetermined temperature difference, means operative in the normal mode for comparing said stored temperature offset signal with the current temperature signal to produce a temperature drift signal when said current temperature signal differs from said stored temperature signal stored during the last zero mode by more than said first and second temperature offset signals, and means responsive to said temperature drift signal for operating said mode control means to place said gain control means in said zero mode.

11. Automatic zeroing apparatus according to claim 10 further including means responsive to said output signal for generating a high concentration signal when said output signal exceeds a predetermined limit, and means responsive to said high concentration signal for inhibiting said mode conrol means from entering said zero mode while the concentration of the respective gas is greater than that corresponding to said predetermined limit.

12. Automatic zeroing apparatus according to claim 11 including electronic calibration means for adding a calibration offset signal to said reference signal during calibration, and means responsive to operation of said electronic calibration means for inhibiting the operation of said mode control means from entering said zero mode during electronic calibration.

13. Automatic zeroing apparatus according to claim 11 wherein said respective gas is carbon dioxide.

14. Automatic zeroing apparatus according to claim 10 further including means under the control of an operator for generating a zero command signal, said mode control means being responsive to said zero command signal to place said gain control means in said zero mode.

15. Automatic zeroing apparatus according to claim 10 wherein said gain control means includes a warm-up mode entered upon start-up of the apparatus and further including means in association with said warm-up mode for operating said means for filling to fill said sample cell with said substantially nonabsorbent gas, means in said warm-up mode responsive to said error signal for periodically adjusting the signal level of said detection signal to drive said output signal substantially to zero, and means responsive to successive adjustments of said signal level for operating said mode control means to place said gain control means in said zero mode when successive adjustments are within a predetermined difference.

16. Automatic zeroing apparatus according to claim 15 wherein said predetermined gas is carbon monoxide.

17. Automatic zeroing apparatus according to claim 10 including electronic calibration means for adding a calibration offset signal to said reference signal during calibration, and means responsive to operation of said electronic calibration means for inhibiting the operation of said mode control means from entering said zero mode during electronic calibration.

18. Automatic zeroing apparatus according to any one of claims 2 to 17 wherein there is a plurality of predetermined gases, and said means for adjusting signal level includes means for independently adjusting the signal level in respect to each of said plurality of gases by a respective said factor.

19. Automatic zeroing apparatus according to claim 18 wherein said means for adjusting said signal level comprises a multiplying digital to analog converter for adjusting each said signal level by said respective said factor.

20. Automatic zeroing apparatus according to claim 19 wherein said gain control means includes a digital processor for determining said factors for said multiplying digital to analog converter and for storing said representations of said factors upon completion of zeroing.

21. Automatic zeroing apparatus according to any one of claims 2 to 17 wherein said means for adjusting said signal level comprises a multiplying digital to analog converter for adjusting said signal level by said factor.

22. Automatic zeroing apparatus according to claim 21 wherein said gain control means includes a digital processor for determining said factor for said multiplying digital to analog converter and for storing said representation of said factor upon completion of zeroing.