Process of fractionating gas feeds and apparatus for carrying out the said process

• US 4,689,063 A
• Filed: 03/04/1986
• Issued: 08/25/1987
• Est. Priority Date: 03/05/1985
• Status: Expired due to Term

• Current Assignee: Compagnie Francaise D'Etudes et de Construction Technip
• Original Assignee: Compagnie Francaise D'Etudes et de Construction Technip
• Inventors: Vasseur, Alain, Parfait, Herve, Castel, Joelle, Paradowski, Henri
• Primary Examiner(s): Capossela, Ronald C.
• Application Number:
  US06/836,140
• Time in Patent Office: 539 Days
• Field of Search: 62/23, 62/27, 62/28, 62/32, 62/40, 62/42
• US Class Current: 62/627
• CPC Class Codes: C07C 7/09 by fractional condensation
• CPC Class Codes: F25J 2200/04 in a dual pressure main column system
• CPC Class Codes: F25J 2200/50 using multiple (re-)boiler-condensers at different heights of the column
• CPC Class Codes: F25J 2200/70 Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
• CPC Class Codes: F25J 2200/74 Refluxing the column with at least a part of the partially condensed overhead gas
• CPC Class Codes: F25J 2200/76 Refluxing the column with condensed overhead gas being cycled in a quasi-closed loop refrigeration cycle
• CPC Class Codes: F25J 2200/78 Refluxing the column with a liquid stream originating from an upstream or downstream fractionator column
• CPC Class Codes: F25J 2205/04 in the feed line, i.e. upstream of the fractionation step
• CPC Class Codes: F25J 2230/60 the fluid being hydrocarbons or a mixture of hydrocarbons
• CPC Class Codes: F25J 2235/60 the fluid being (a mixture of) hydrocarbons
• CPC Class Codes: F25J 2240/02 Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
• CPC Class Codes: F25J 2270/02 Internal refrigeration with liquid vaporising loop
• CPC Class Codes: F25J 2270/12 External refrigeration with liquid vaporising loop
• CPC Class Codes: F25J 2270/66 Closed external refrigeration cycle with multi component refrigerant [MCR], e.g. mixture of hydrocarbons
• CPC Class Codes: F25J 2270/902 Details about the refrigeration cycle used, e.g. composition of refrigerant, arrangement of compressors or cascade, make up sources, use of reflux exchangers etc.
• CPC Class Codes: F25J 3/0209 Natural gas or substitute natural gas
• CPC Class Codes: F25J 3/0233 separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0238 separation of CnHm with 2 carbon atoms or more
• CPC Class Codes: F25J 3/0242 separation of CnHm with 3 carbon atoms or more

Abstract

The present invention relates to a process and an apparatus for cryogenic fractionation of gas feeds, the apparatus comprising essentially a contact purifying-refrigerating column associated with a fractionating column, an exchange system, a plurality of ducts with valves connecting the above three elements and two closed end independent refrigerating circuits integrated to the exchange system.

Claims

1. A process for fractionating a gas feed comprising methane and hydrocarbons heavier than methane in which said heavier hydrocarbons are recovered from said gas feed comprising the steps of:

(a) Partially condensing said gas feed (106) in a heat-exchange system (103) and feeding said partially condensed feed to the bottom of a contact purifying-refrigerating column (101);

(b) Withdrawing a residual gas stream (133) from the top of said contact purifying-refrigerating column (101);

(c) Withdrawing liquid (125) from the bottom of said contact-purifying refrigerating column (101), and feeding said liquid to a fractionation column (102);

(d) Withdrawing a gaseous distillate (116) from the top of said fractionation column (102), and feeding said distillate to said contact purifying-refrigerating column (101); and

(e) Withdrawing from the bottom of said fractionation column (102) a stream of hydrocarbons heavier than methane,

and selectively producing as said stream of hydrocarbons heavier than methane a stream selected from the group consisting of compounds heavier than methane (C₂ + cut) and compounds heavier than ethane (C₃ + cut) by, when a C₃ + cut is desired;

(a) Feeding all of said feed gas (106) to said contact purifying-refrigerating column (101);

(b) Feeding all of the liquid withdrawn from the bottom of said contact purifying-refrigerating column (101) to said fractionation column (102) at a point between its top and bottom; and

(c) Partially condensing the gaseous distillate withdrawn from the top of said fractionation column (102) in said heat-exchange system (103) and feeding the uncondensed portion of said distillate to the top of said contact purifying-refrigerating column (101); and

when a C₂ + cut is desired;

(a) Compressing (135) at least part of said residual gas stream (133) and feeding said compressed gas stream (137) to the top of said contact purifying-refrigerating

column (101);

when a C₂ + cut is desired;

(a) Compressing (135) at least part of said residual gas stream (133) and feeding said compressed gas stream (137) to the top of said contact purifying-refrigerating column (101);

(b) Feeding all of the liquid (125) withdrawn from the bottom of said contact purifying-refrigerating column (101) to the top of said fractionating column (102); and

(c) Feeding all of said gaseous distillate (116) withdrawn from the top of said fractionation column (102), without condensation, to the bottom of said contact purifying-refrigeration column (101).

2. A process according to claim 1, in which, if the cut to be recovered is C₂ + cut, the gas feed (106) is at least partially condensed (108) in an exchange system (103), the condensed gas feed is separated (109) into a liquid phase (111) and a gaseous phase (112), said liquid phase (111) is injected into the middle of said fractionating column (102), said gaseous phase (112) is at least partially condensed (113) in said exchange system and then injected (114) into said purifying-refrigerating column (101), and if the cut to be recovered is a C₃ + cut, said gas feed (106) is partially condensed (108, 113) in said refrigerating exchange system and then injected (114) directly and without separation into said purifying-refrigerating column (FIG. 1).

3. A process according to claims 1 or 2, wherein cooling in said heat-exchange system (103) is effected by a single refrigerating circuit (105) with several pressure levels and, if the cut to be recovered is a C₂ + cut, by a second distinct refrigerating circuit (104) with a single pressure level.

4. A process according to claim 3 wherein the medium in said single refrigerating circuit (105) is a pure hydrocarbon having 3 carbons or a mixture of hydrocarbons having a molecular weight in the range of from 30 to 40.

5. A process according to claim 3 wherein the medium in said second refrigerating circuit (104) is a mixture of light hydrocarbons having a molecular weight ranging from 26 and 36, or is a pure hydrocarbon having 2 carbons.

6. A process according to claim 1 in which, if the cut to be recovered is a C₂ + cut, the gas feed (200, 202) is separated into a first portion (205) and a second portion (203), said first portion (205) is used for the purpose of reboiling (206) said fractionating column (l02), said second portion (203) is partially condensed (204) in said heat-exchange system (103), said first and second portions are then mixed (208) and the resulting mixture is separated (207) into a liquid phase and a gaseous phase, the liquid phase is subcooled (211) in said exchange system (103), and the gaseous phase (213) is expanded (214) and then mixed (216) with the said subcooled liquid phase (211) to form a combined phase, said combined phase is injected (217) into said purifying-refrigerating column (101), having an upper packing layer (L₁), a middle packing layer (L₂) and a lower packing layer, at a location below said upper packing layer (L₁), and, in which, if the cut to be recovered is a C₃ + cut, the entire gas feed (200) is partially condensed (204) in said exchange system (103), and then separated (207) to form a gaseous phase (213) and a liquid phase (210, 212), said gaseous phase (213) is expanded (214) and then injected directly (215, 217) into said column (101) under said upper packing layer, and said liquid phase (210, 212) is injected directly into said purifying-refrigerating column (101) at a location below said middle packing layer (L₂) (FIG. 2).

7. A process according to claim 6, wherein additional cooling is provided through a refrigerating circuit having several pressure levels in combination with said expansion (214).

8. A process according to claim 1, wherein said fractionating column (102) operates at a pressure higher than that of said purifying-refrigerating column (101) so as to ensure the injection of the distillate issued from the fractionating column into said purifying-refrigerating column.

9. An apparatus comprising:

(a) a contact purifying-refrigerating column (101);

(b) a fractionating column (102);

(c) a heat-exchange system (103); and

(d) a compressor (135;

232, 235,

     236);

having

(e) a duct (125, 130, 131, 132;

247, 249, 251, 252

     253) communicating between the bottom (101b) of said contact purifying-refrigerating column (101) and said fractionating column (102) and passing through said heat-exchange system (103);

(f) a duct (116, 118, 119, 120;

227, 228,

     229) communicating between the top (102a) of said fractionating column (102) and the top (101a) of said contact purifying-refrigerating column (101) and passing through said heat-exchange system (103);

(g) a duct (133, 134;

230,

     231) communicating between the top (101a) of said contact purifying-refrigerating column (101) and said compressor (135;

232,

     235) and passing through said heat-exchange system (103);

(h) a duct (137, 138, 120;

244, 245,

     246) communicating between said compressor (135;

232, 235,

     236) and the top (101a) of said contact purifying-refrigerating column (101) and passing through said heat exchange system (103);

(i) a duct (124;

220,

     221) communicating between the top (102a) of said fractionating column (102) and the bottom (101b) of said contact refrigerating-purifying column (101) and not passing through said heat-exchange system (103); and

(j) a duct (125, 127, 129;

247, 249,

     250) communicating between the bottom (101b) of contact purifying-refrigerating column (101) and the top (102a) of said fractionating column (102) and not passing through said heat-exchange system (103).

10. An apparatus according to claim 9, having a gas feed duct (106, 108) passing through said exchange system (103) and communicating with a separator (109), a duct (111) communicating between the bottom of said separator (109) and the middle of said fractionating column (102), a duct (112, 114) communicating between the top of said separator (109) and said purifying-refrigerating column (101) and which passes through said exchange system (103), and a valve means (V₁, V₂ in said gas feed duct (108) to bypass said separator (FIG. 1).

11. An apparatus according to claims 9 and 10, wherein said exchange system (103) includes two closed and independent refrigerating circuits (105, 104) one circuit operating at a single pressure level and the other circuit operating at one or several pressure levels (FIG. 1).

12. An apparatus according to claim 9, having a gas feed duct (202), which is subdivided into first and second gas feed ducts (205 and 203), said first gas feed duct (205) passing through a reboiling system (206) associated with said fractionating column (102), and then joining said second gas feed duct (203, 204) at a junction point (208), a duct (209) communicating between said junction point (208) and a separator (207), a duct (210) connected to the bottom of said separator (207) and communicating with a third and a fourth duct (211, 212), said third duct (211) passes through said exchange system (103) and then communicates with a fifth duct (217) to form a second junction point (216) and said fourth duct (212) communicates directly with said purifying-refrigerating column (101), a duct (213) communicating between the top of said separator (207) and the inlet of a turbine-expander (214), a duct communicating between the outlet of said turbine expander (214) and said second junction point (216), said fifth duct (217) communicating between said second junction point and said purifying-refrigerating column (101) (FIG. 2).

13. An apparatus according to claim 12, having a refrigerating circuit in said heat-exchange system (103) having several pressure levels.

14. An apparatus according to claim 9, wherein said exchange system (103) comprises at least one plate exchanger in which the descending fluids are cooled and the rising fluids are heated.

15. An apparatus according to claim 9, which further comprises a reboiler (159, 160;

219,

     219) associated with said purifying-refrigerating column (101) and forming part of said exchange system (103).

16. An apparatus according to claim 9, having means (V₇, V₃) to selectively direct material removed from the bottom (101b) of said contact purifying-refrigerating column (101) either through said heat-exchange system (103) and to said fractionating column (102), or to the top (102a) of said fractionating column without passing through said heat-exchange system;

means (V₄, V₈) for selectively directing material removed from the top (102b) of said fractionating column (102), either to the top (101a) or to the bottom (101b) of contact purifying-refrigerating column (101); and

means (V₅) to open or close said duct communicating between said compressor (135) and the top (101a) of said contact purifying-refrigerating column (101).