Steam reforming hydrocarbons

• US 4,690,690 A
• Filed: 02/24/1986
• Issued: 09/01/1987
• Est. Priority Date: 03/05/1985
• Status: Expired due to Term

• Current Assignee: Johnson Matthey PLC
• Original Assignee: Imperial Chemical Industries PLC (Nouryon BV)
• Inventors: Doy, Ralph J., Limbach, Antony P. J., Andrew, Sydney P.
• Primary Examiner(s): LACEY, DAVID LYNN
• Application Number:
  US06/832,425
• Time in Patent Office: 554 Days
• Field of Search: 252/373, 422/203, 422/241, 48/196 A, 48/214 R, 48/214 A, 423/651
• US Class Current: 48/214.00A
• CPC Class Codes: B01J 19/2425 in parallel
• CPC Class Codes: B01J 2208/00132 Tubes
• CPC Class Codes: B01J 2208/00176 outside the reactor
• CPC Class Codes: B01J 2208/00495 using insulating materials or refractories
• CPC Class Codes: B01J 2208/0053 Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
• CPC Class Codes: B01J 8/062 being installed in a furnace
• CPC Class Codes: C01B 2203/0816 Heating by flames
• CPC Class Codes: C01B 2203/0844 the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
• CPC Class Codes: C01B 2203/143 Three or more reforming, decomposition or partial oxidation steps in series
• CPC Class Codes: C01B 2203/82 Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
• CPC Class Codes: C01B 3/382 Multi-step processes
• CPC Class Codes: C01B 3/384 the catalyst being continuously externally heated

Abstract

A process for producing a product gas stream containing hydrogen and carbon oxides by incomplete catalytic reaction of a hydrocarbon feedstock with steam and/or carbon dioxide. The process involves passing a reactants stream containing the feedstock and steam and/or carbon dioxide over a catalyst disposed in an elongated, externally heated, zone and withdrawing the product gas stream through a tube within that zone and countercurrently to the flow of the reactants stream over the catalyst. Heat exchange between the product gas stream and the reactants stream across the wall of the tube is limited so that the temperature of the product gas stream leaving the tube is less than that of the stream leaving the elongated zone by at most 100° C. Apparatus for carrying out the process is also disclosed.

Claims

1. A process for producing a product gas stream containing hydrogen, carbon oxides, and methane by incomplete catalytic reaction of a hydrocarbon feedstock with steam and/or carbon dioxide comprising:

passing a reactants stream containing a hydrocarbon feedstock steam and/or carbon dioxide over a catalyst disposed in an elongated zone having an inlet end and an outlet end, said elongated zone being defined by an outer wall and a wall of a tube, disposed within the outer wall and extending from the outlet end of the elongated zone to the inlet end thereof;

externally heating said elongated zone with a heating medium;

withdrawing a product gas stream containing hydrogen, carbon oxides and methane through said tube countercurrently to the flow of said reactants stream over the catalyst; and

cooling the product gas stream by at most 100°

C. by heat exchange with the reactants stream across the wall of said tube as the product gas stream passes through said tube thereby improving heat transfer between the heating medium and reactants stream.

2. A process according to claim 1 wherein said elongated zone is heated by passing a stream of the heating medium, in a direction counter-current to the flow of the reactants stream through the elongated zone, through a sheath surrounding the elongated zone and extending for at least a major part of the length thereof.

3. A process according to claim 2 wherein, at the outlet end region of the elongated zone, the elongated zone beyond the sheath.

4. A process according to claim 1 wherein the outer wall of the elongated zone has, for at least the major part of the length thereof, an extended surface.

5. A process according to claim 4 wherein the extended surface of the elongated zone terminates short of the outlet end thereof.

6. A process according to claim 1 wherein the degree of cooling is such that the product gas stream cools by less than 30°

C. during its passage through the tube.

7. A process according to claim 1 comprising reacting the product gas stream with a gas containing free oxygen in an adiabatic catalyst zone whereby to effect reaction of methane in said product gas stream to produce a hot gas stream containing carbon oxides and hydrogen and using the hot gas stream as the heating medium to heat the elongated zone.

8. A process according to claim 7 wherein the reaction of the product gas stream is effected in a secondary reformer and the product gas stream is cooled during its passage through the tube from the outlet of the elongated zone and to the secondary reformer by no more than 50°

C.

9. A process according to claim 7 wherein, prior to feeding the reactants stream to the elongated zone, heating the reactants stream by heat exchange with the hot gas stream after the latter has been used for heating the elongated zone.

10. A process according to claim 7 wherein the outer wall of the elongated zone has an outer metal surface and the elongated zone is heated by passing the hot gas stream through a region defined by metal surfaces and through which the elongated zone extends, the outer metal surface of the elongated zone and all the metal surfaces of, and within, said region, with which the hot gas stream contacts while in heat exchange with the elongated zone are surfaces of metal having substantially no catalytic activity, whether in metallic or oxide form, for reactions of carbon monoxide.

11. A process according to claim 1 wherein the tube has a layer of insulation on its inner or outer surface.

12. A process for producing a product gas stream containing hydrogen, carbon oxides, and methane by incomplete catalytic reaction of a hydrocarbon feedstock with steam and/or carbon dioxide comprising:

providing a reactants stream containing a hydrocarbon feedstock steam and/or carbon dioxide and passing this stream over a catalyst in an elongated reaction zone from an inlet end thereof to an outlet end thereof to form a product gas stream containing hydrogen, carbon oxides and methane;

passing the resulting product gas stream from the outlet end of said reaction zone back past said reaction zone in countercurrent flow to said reactants stream and in indirect heat exchange relationship with said reactants stream so as to indirectly heat the reactants stream by the heat in said product gas stream,

applying further heat to the reactant stream as it passes through the elongated reaction zone by an external heating medium, and

maintaining insulation between the reactants stream and the product gas stream such that the product gas stream is cooled by at most 100°

C. by said indirect heat exchange thereby improving the efficiency of heat transfer between the external heating medium and the reactants stream.