Method and apparatus for cryogenic fractionation of a gaseous feed

• US 4,690,702 A
• Filed: 09/25/1985
• Issued: 09/01/1987
• Est. Priority Date: 09/28/1984
• Status: Expired due to Term

• Current Assignee: Compagnie Francaise D'Etudes et de Construction Technip
• Original Assignee: Compagnie Francaise D'Etudes et de Construction Technip
• Inventors: Parfait, Herve B., Castel, Joelle H., Paradowski, Henri
• Primary Examiner(s): Capossela, Ronald C.
• Application Number:
  US06/779,811
• Time in Patent Office: 706 Days
• Field of Search: 62/27, 62/28, 62/23, 62/24, 62/38, 55/48
• US Class Current: 62/621
• CPC Class Codes: C07C 7/09 by fractional condensation
• CPC Class Codes: F25J 2200/02 in a single pressure main column system
• CPC Class Codes: F25J 2200/74 Refluxing the column with at least a part of the partially condensed overhead gas
• CPC Class Codes: F25J 2200/78 Refluxing the column with a liquid stream originating from an upstream or downstream fractionator column
• CPC Class Codes: F25J 2205/04 in the feed line, i.e. upstream of the fractionation step
• CPC Class Codes: F25J 2210/12 Refinery or petrochemical off-gas
• CPC Class Codes: F25J 2240/02 Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
• CPC Class Codes: F25J 2270/12 External refrigeration with liquid vaporising loop
• CPC Class Codes: F25J 2270/60 Closed external refrigeration cycle with single component refrigerant [SCR], e.g. C1-, C2- or C3-hydrocarbons
• CPC Class Codes: F25J 2270/902 Details about the refrigeration cycle used, e.g. composition of refrigerant, arrangement of compressors or cascade, make up sources, use of reflux exchangers etc.
• CPC Class Codes: F25J 2290/40 Vertical layout or arrangement of cold equipments within in the cold box, e.g. columns, condensers, heat exchangers etc.
• CPC Class Codes: F25J 3/0209 Natural gas or substitute natural gas
• CPC Class Codes: F25J 3/0219 Refinery gas, cracking gas, coke oven gas, gaseous mixtures containing aliphatic unsaturated CnHm or gaseous mixtures of undefined nature
• CPC Class Codes: F25J 3/0233 separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0242 separation of CnHm with 3 carbon atoms or more

Abstract

The invention relates to a method and an apparatus for cryogenic fractionation of a gaseous feed comprising a contact purifying-refrigerating column into the bottom of which is injected a partially condensed gaseous feed, the said column producing in its head portion a residual gas and in its bottom portion a liquid which is injected into a fractionating column producing in its head portion a distillate which is at least partially condensed and injected into the head portion of the column to thus recover in the bottom liquid of this column the heavy compounds contained in the vaporized fraction of the gaseous feed.

Claims

1. A method of cryogenic fractionation of a gaseous feed into a residual gas containing the most volatile compounds of the feed and into a liquid product containing the heaviest compounds of the feed, comprising the steps of:

injecting said feed in a partially condensed state into the bottom portion of a contact purifying-refrigerating column, which column produces in its head portion at least some of said residual gas, and in its bottom portion, a liquid;

withdrawing said liquid from said contact purifying-refrigerating column and injecting said liquid into a fractionating column to obtain in the bottom portion thereof a liquid product containing the heaviest compounds of the feed, and in the head portion thereof, a distillate;

withdrawing said distillate from said fractionation column, and partially condensing and injecting said distillate as head supply into the said purifying-refrigerating column and recovering from the bottom of the fractionating column a liquid containing the heavy compounds contained in the vaporized fraction of a gaseous feed.

2. A method according to claim 1 wherein the head supply to the said purifying-refrigerating column is constituted by the vapor distillate from the fractionating column, either partially or wholly condensed in an exchange system, and/or by the liquid distillate from the said fractionating column, either subcooled or not subcolled in the said exchange system.

3. A method according to claim 1 wherein the said fractionating column operates at a higher pressure than that of the contact purifying-refrigerating column to allow the injection of the distillate from the fractionating column into the purifying-refrigerating column without compression of the said distillate.

4. A method according to claim 1, wherein a complimentary amount of cold at a low temperature level, necessary for the cooling of the gaseous feed to a low temperature and for its partial condensation prior to injection into the purifying-refrigerating column, necessary for the cooling of the fractionating column distillate or distillates, and necessary also to the condensation system of this column, is supplied by a refrigeration system.

5. A method according to claim 4, wherein the refrigeration system is constituted by a compression refrigeration cycle in which a refrigerating fluid including one or several pure substances is compressed to a high pressure in a compressor and then condensed and subcooled at the said pressure and lastly expanded to a pressure or to pressures compatible with the temperature levels of the exchange systems of the process in order to be vaporized in the said systems.

6. A method according to claim 4, wherein the said refrigeration system is constituted by the expansion of the residual gas leaving the purifying-refrigerating column in order to lower its temperature to a level compatible with the temperatures of the exchange systems of the process, the said expansion being, if suitable, associated with the said refrigeration cycle.

7. A method according to claim 4, wherein the said refrigeration system is constituted by the expansion of the gaseous feed in a turbine expander ensuring a partial condensation of the said feed and producing mechanical energy which is used to drive a rotary machine, a complementary amount of cold being provided by the said refrigeration cycle.

8. An apparatus for cryogenic fractionation of a gaseous feed, comprising a contact purifying-refrigeration column having a head and bottom;

a fractionating column;

means for transferring liquid from the bottom of said contact purifying-refrigerating column to said fractionating column, and means to transfer distillate from said fractionating column to the head of said contact purifying-refrigerating column.

9. An apparatus according to claim 8, wherein at least one distillate supply conduit 16, 18;

38, 40 connecting the head portion of the fractionating column 2, 11 to the head portion of the purifying-refrigerating column 1 after passing (17,

     39) through an exchange system 3 upstream of the latter, and by a conduit 9 connecting the bottom portion of the purifying-refrigerating column to the fractionating column after passing (12) through the said exchange system.

10. An apparatus according to claim 9, wherein the said exchange system 3 is associated, with a refrigerating fluid circuit 28.

11. An apparatus according to claim 9, wherein the head portion 11a of the fractionating column 11 proper is equipped with a condenser 41 to which cold is supplied through a refrigerating fluid circuit associated with the said exchange system.

12. An apparatus according to claim 9, wherein the head portion 11a of the said fractionating column is provided with a vapor distillate conduit 71 passing through the said exchange system and leading into a liquid-distillate reflux drum 15 connected to said column, which reflux drum is provided with a gaseous-distillate supply conduit 16, 17, 18 passing through the said exchange system and leading into the head portion 1a of the purifying-refrigerating column 1.

13. An apparatus according to claim 12, wherein the gaseous-feed intake conduit 4 which, after passing (5, 62) through the exchange system 3, leads into a separator 66 provided at its bottom with a liquid fraction outflow path 69 leading into the the bottom portion of the purifying-refrigerating column 1, and provided at its top with a gaseous-fraction passageway 78 leading to the inlet of a turbine expander 67 whose outlet is connected (68) to the bottom portion of the said column 1.

14. An apparatus according to claim 13, wherein the said turbine expander 67 drives at least one rotary machine, such as a compressor 75, connected to the residual gas discharge conduit 74.

15. An apparatus according to claim 8, wherein at least one gaseous-feed intake conduit 4 connected to the bottom portion of the purifying-refrigerating column 1 and by a residual gas discharge conduit 23 connected to the head portion 1a of the said column, both of these conduits passing through the said exchange system 3.

16. An apparatus according to claim 8, wherein in that the head portion of the said fractionating column is provided with a condenser C and a reflux drum 15 provided, on the one hand, with a first, gaseous-distillate supply conduit 16, 17, 18 passing through the exchange system 3 and leading into the head portion 1a of the purifying-refrigerating column 1, and on the other hand, with a second, liquid reflux conduit 29 leading into the head portion 11a of the fractionating column proper, the said second conduit being connected to the head portion of the purifying-refrigerating column through a conduit 20, 21, 22 passing through the said exchange system, so as to supply the said column 1 with a subcooled liquid distillate.