Block-form detergent free from alkali hydroxides for use in dishwashing machines and a process for its production

• US 4,690,770 A
• Filed: 05/29/1986
• Issued: 09/01/1987
• Est. Priority Date: 05/30/1985
• Status: Expired due to Term

• Current Assignee: Henkel KGaA (Henkel AG & Co KGaA)
• Original Assignee: Henkel KGaA (Henkel AG & Co KGaA)
• Inventors: Schumann, Klaus, Jeschke, Peter, Jacobs, Jochen, Altenschoepfer, Theodor
• Primary Examiner(s): Barr, Josephine L.
• Application Number:
  US06/868,913
• Time in Patent Office: 460 Days
• Field of Search: 252/174, 252/135, 252/99, 252/102
• US Class Current: 510/224
• CPC Class Codes: C11D 17/0052 Cast detergent compositions
• CPC Class Codes: C11D 3/3958 combined with phosphates

Abstract

A block-form detergent free of alkali metal hydroxides for use in dishwashing machines which contain from 65 to 85% by weight to a mixture of anhydrous sodium metasilicate and anhydrous pentasodium triphosphate in a ratio of from 1:1 to 1:2 and from 0.2 to 4% by weight of uniformly distributed active chlorine donors which are, for example, trichloroisocyanuric acid. The production process comprises heating sodium metasilicate to 45° to 55° C. to obtain a clear melt and then adding other constituents, the pentasodium triphosphate and the active chlorine donor being added last, and pouring the melt into flexible molds in which it is left to solidify into blocks. The detergents are stable for storage with good dissolving power.

Claims

1. A storage stable detergent in the form of fused blocks made from a liquid melt free of alkali metal hydroxide for use in dishwashing machines containing from about 65 to about 85% by weight, based on the weight of the detergent, of a mixture of alkali metal silicates and pentaalkalitriphosphates, said silicates being present in an amount of between about 5 and about 60% by weight, and being selected from sodium metasilicate nonahydrate, sodium metasilicate hexahydrate, sodium metasilicate pentahydrate, sodium metasilicate anhydrous, and mixtures thereof, and homogeneously distributed throughout said detergent from about 0.2 to about 4% by weight of a chlorine donor.

13. The process of claim 1, wherein the chlorine donor is trichloroisocyanuric acid.

17. The storage stable detergent of claim 1 wherein said pentaalkalitriphosphates are selected from pentaalkalitriphosphate hexahydrate, and a mixture of pentaalkalitriphosphate hexahydrate and pentaalkalitriphosphate anhydrous.

18. The storage stable detergent of claim 1 wherein said detergent contains from about 11 to about 34.8% by weight of water, based on the weight of said detergent.

2. An alkali metal hydroxide-free, storage stable detergent in the form of a fused block made from a liquid melt consisting essentially of, based on the total weight of the detergent;

from about 65 to about 85% of a mixture of sodium metasilicates and pentasodium triphosphates, the ratio of said triphosphates to said metasilicates on an anhydrous basis being from about 1;

1 to about 1;

2 wherein said metasilicates are selected from the group consisting of sodium metasilicate nonahydrate, sodium metasilicate hexahydrate, sodium metasilicate pentahydrate, sodium metasilicate anhydrous, and mixtures thereof, from about 11 to about 34.8% of total water, and from about 0.2 to about 4% of an organic chlorine donor homogeneously distributed throughout said detergent.

3. The detergent composition of claim 2, wherein the organic chlorine donor is a chlorinated isocyanuric acid.

4. The detergent composition of claim 3, wherein the chlorine donor is trichloroiscyanuric acid.

5. The detergent composition of claim 3, wherein the chlorine donor is sodium dichloroiscyanurate or its dihydrate.

6. The detergent composition of claim 2, wherein the chlorine donor is Na-monochloroamidosulfonate.

7. The detergent composition of claim 2, wherein the chlorine donor is sodium N-chloro-p-toluene sulfonic acid amide.

8. The detergent composition of claim 2, wherein the amount of said mixture of sodium metasilicates and pentasodiumtriphosphates is from about 70 to about 80%, the ratio of said triphosphates to said metasilicates is from about 1:

1 to about 1;

1.7, the amount of total water is from about 18 to about 29.5%, and the amount of chlorine donor is from about 0.5 to about 2%.

9. The detergent composition of claim 8, wherein the chlorine donor is trichloroisocyanuric acid.

10. The detergent composition of claim 8, wherein the chlorine donor is sodium dichloroisocyanurate dihydrate.

11. A process for preparing a homogeneous alkali metal hydroxide-free, storage stable detergent composition in the form of fused blocks, said composition consisting essentially of, based on the total weight of the detergent;

from about 65 to about 85% of a mixture of sodium metasilicates and pentasodium triphosphates, the ratio of said triphosphates to said silicates on an anhydrous basis being from about 1;

1 to about 1;

2, from about 11 to about 34.8% of total water, and from about 0.2 to about 4% of an organic chlorine donor, homogeneously distributed throughout said detergent which comprises heating sodium metasilicate nonahydrate at about 45°

to about 60°

C. to a clear melt and adding the remaining ingredients with stirring, the pentasodium triphosphate and the chlorine donor being added last and while the mixture is liquid, and pouring the mixture into a mold to cool and solidify.

12. The process of claim 11, wherein the chlorine donor is a chlorinated isocyanuric acid.

14. The process of claim 12, wherein the chlorine donor is sodium dichloroisocyanurate or its dihydrate.

15. The process of claim 11, wherein the chlorine donor is Na-monochloroamidosulfonate.

16. The process of claim 11, wherein the chlorine donor is sodium N-chloro-p-toluene sulfonic acid amide.

19. The process of claim 11 wherein said pentasodium triphosphates are selected from pentasodium triphosphate hexahydrate, and a mixture of pentasodium triphosphate hexahydrate and pentasodium triphosphate anhydrous.

20. The process of claim 11 wherein said sodium metasilicates are present in an amount of between about 5 and about 60% by weight and are selected from the group consisting of sodium metasilicate nonahydrate, sodium metasilicate hexahydrate, sodium metasilicate pentahydrate, sodium metasilicate anhydrous, and mixtures thereof.