Preparation and use of catalysts comprising mixtures of tungsten oxide and silica on alumina

• US 4,692,428 A
• Filed: 12/31/1985
• Issued: 09/08/1987
• Est. Priority Date: 12/31/1985
• Status: Expired due to Fees

• Current Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Original Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Inventors: Polizzotti, Richard S., Murrell, Lawrence L., Dispenziere, Nicholas C. Jr.
• Primary Examiner(s): DEES, CARL
• Application Number:
  US06/815,201
• Time in Patent Office: 616 Days
• Field of Search: 502/254, 502/263
• US Class Current: 502/254
• CPC Class Codes: B01J 23/30 Tungsten
• CPC Class Codes: C10G 11/04 Oxides

Abstract

Useful cracking catalysts and catalyst supports comprising mixtures of tungsten oxide and silica supported on alumina are prepared by forming a composite of a mixture of (a) particles of tungsten oxide or one or more suitable tungsten oxide precursors, (b) particles of silica and (c) particles of porous alumina and steaming said composite at a temperature of at least about 500° C. in a non-reducing environment for a time sufficient for at least a portion of the tungsten oxide and silica to disperse over the alumina surface. The mixture of silica and tungsten oxide wets, spreads out and reacts with the surface hydroxyl groups of the alumina.

Claims

1. As a composition of matter, a compound prepared by (i) forming a composite of a mixture of (a) tungsten-containing particles selected from the group consisting of tungsten oxide, tungstic acid, tungsten compounds capable of being converted to tungsten oxide when treated with steam, and mixtures thereof, (b) silicon-containing particles selected from the group consisting of silica, silicic acid and silicon compounds insoluble in polar and non-polar solvents and which are capable of being converted to silica when treated with steam in a non-reducing atmosphere and (c) particles of porous alumina, and (ii) steaming said composite at an elevated temperature of at least about 500°

C. in a non-reducing environment and in the presence of steam for a time sufficient for at least a portion of the tungsten oxide and silica to react with the alumina surface.

2. The composition of claim 1 wherein at least a portion of the tungsten oxide has dispersed over the alumina surface.

3. The composition of claim 2 wherein at least a portion of the silica has dispersed over the alumina surface.

4. The composition of claim 3 wherein the combined amount of silica and tungsten oxide ranges from between about 1-50 wt. % of the total composition.

5. The composition of claim 4 wherein the elevated temperature employed in forming said composition is at least about 700°

C.

6. The composition of claim 5 wherein the amount of steam employed in forming the composition ranges between from about 1-90% of the non-reducing environment.

7. A process for preparing a composition comprising a mixture of silica and tungsten oxide supported on the surface of alumina comprising (i) forming a composite of a mixture of (a) tungsten-containing particles selected from the group consisting of tungsten oxide, tungstic acid, tungsten compounds capable of being converted to tungsten oxide when treated with steam, and mixtures thereof, (b) silicon-containing particles selected from the group consisting of silica, silicic acid and silicon compounds insoluble in polar and non-polar solvents and which are capable of being converted to silica when treated with steam in a non-reducing atmosphere and (c) particles of porous alumina, and (ii) steaming said composite at an elevated temperature of at least about 500°

C. in a non-reducing environment and in the presence of steam for a time sufficient for at least a portion of the tungsten oxide and silica to react with the alumina surface.

8. The process of claim 7 wherein said steaming of said composite is continued for a time sufficient for at least a portion of the tungsten oxide has dispersed over the alumina surface.

9. The process of claim 8 wherein said steaming is continued for a time sufficient for at least a portion of the silica has dispersed over the alumina surface.

10. The process of claim 9 wherein the combined amount of silica and tungsten oxide ranges from between about 1-50 wt. % of the total composition.

11. The process of claim 10 wherein the composite is steamed at an elevated temperature of at least about 700°

C.

12. The process of claim 11 wherein the amount of steam employed ranges between from about 1-90% of the non-reducing environment.