Cool water fabric washing process using a particulate detergent containing a nonionic and a fatty acid builder salt

• US 4,695,284 A
• Filed: 06/04/1985
• Issued: 09/22/1987
• Est. Priority Date: 06/15/1984
• Status: Expired due to Term

• Current Assignee: Lever Brothers Company (Unilever PLC)
• Original Assignee: Lever Brothers Company (Unilever PLC)
• Inventors: Hight, Andrew T.
• Primary Examiner(s): ALBRECHT, DENNIS
• Application Number:
  US06/741,042
• Time in Patent Office: 840 Days
• Field of Search: 252/108, 252/109, 252/131, 252/132, 252/134, 8/137
• US Class Current: 8/137
• CPC Class Codes: C11D 1/04 Carboxylic acids or salts thereof soap C11D9/00
• CPC Class Codes: C11D 1/143 Sulfonic acid esters
• CPC Class Codes: C11D 1/22 derived from aromatic compounds
• CPC Class Codes: C11D 1/44 Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
• CPC Class Codes: C11D 1/526 Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 are polyalkoxylated
• CPC Class Codes: C11D 1/66 Non-ionic compounds C11D1/002, C11D1/004, C11D1/008 take precedence
• CPC Class Codes: C11D 1/72 Ethers of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/74 Carboxylates or sulfonates esters of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/83 Mixtures of non-ionic with anionic compounds
• CPC Class Codes: C11D 10/045 based on non-ionic surface-active compounds and soap
• CPC Class Codes: C11D 17/0034 Fixed on a solid conventional detergent ingredient

Abstract

A method for washing fabrics at cold water temperatures is provided wherein fabrics are contacted below 50° C. with built detergent particles comprising from 5 to 50% by weight of nonionic detergent active compound, from 15 to 90% by weight of a saturated fatty acid builder salt and from 5 to 80% carrier material chosen from water-insoluble inorganic materials, water-soluble inorganic materials, water-soluble organic materials, or mixtures thereof. The particles are prepared by distributing the aforementioned components in water, mixing the combination, and evaporating water therefrom to obtain the built particles. These built detergent particles are adapted to promote rapid dissolution or dispersion of the particle on contact with water.

Claims

1. A method for washing fabrics at cold water temperatures comprising contacting said fabrics below 5020 C. with built detergent particles comprising:

(i) from 5 to 50% by weight of a nonionic detergent active compound;

(ii) from 15 to 90% by weight of a saturated fatty acid builder salt containing at least 16 carbon atoms, or mixtures thereof; and

(iii) from 5 to 80% by weight of a carrier material, the carrier material being chosen from water-insoluble inorganic materials, water-soluble inorganic materials, water-soluble organic materials selected from the group consisting of urea, solid polyhydric alcohols, polysaccharides, synthetic polymers, proteins, and mixtures thereof; and

wherein said particles are prepared by distributing said nonionic active, said fatty acid builder salt, and said carrier material in water to form an aqueous solution and/or dispersion, mixing said combination, and evaporating water therefrom to obtain said built particles.

2. The method of claim 1, wherein the nonionic detergent active compound is alkoxylated.

3. The method of claim 1, wherein the nonionic detergent active compound forms from 10 to 40% by weight of the built detergent particles.

4. The method of claim 1, wherein the saturated fatty acid salt contains from 16 to 18 carbon atoms.

5. The method of claim 4, wherein the saturated fatty acid salt is chosen from salts of palmitic acid and stearic acid.

6. The method of claim 1, wherein the saturated fatty acid salt forms from 25 to 80% by weight of the built detergent particles.

7. The method of claim 1, wherein the carrier material is a water-soluble inorganic material chosen from perborates, sulphates, phosphates, chlorides, carbonates and mixtures thereof.

8. The method of claim 7, wherein the carrier material is chosen from sodium and potassium chloride.

9. The method of claim 1, wherein the carrier forms from 15 to 60% by weight of the builder particles.

10. The method of claim 1, wherein the weight ratio in the built detergent particles of nonionic detergent active compound to fatty acid salt is from 2:

1 to 1;

8.

11. The method according of claim 1, wherein the weight ratio in the built detergent particle of fatty acid salts to carrier material is 10:

1 to 1;

4.

12. The method of claim 1, wherein the built detergent particles have an average particle size of from 100 to 1500 μ

m.

13. A method according to claim 1 for washing fabrics employing a detergent product comprising the built detergent composition method particles of claim 1, blended together with other ingredients in an amount up to 75% by weight of the composition, said other ingredients being chosen from:

(a) detergent active compounds, selected from the group consisting of anionic, nonionic, zwitterionic and amphoteric synthetic detergent active material;

(b) detergency builders, selected from the group consisting of precipitating builder materials, sequestering builder materials and ion-exchange builder materials and materials capable of forming such builders in situ;

(c) alkaline materials, selected from the group consisting of alkali metal and ammonium salts of carbonates, silicates, phosphates, citrates, acetates, oleates and alkali metal hydroxides and borates; and

(d) other detergent adjuncts, selected from the following;

lather boosters, lather depressants, waxes, silicones, antiredeposition agents, oxygen-releasing agents, chlorine-releasing agents, peracid bleach precursors, fabric softening agents, inorganic salts, fluorescent agents, perfumes, enzymes, germicides and colourants.

14. A method for washing fabrics at cold water temperatures comprising cntacting said fabrics below 50°

C. with built detergent particles comprising;

(i) from 5 to 50% by weight of nonionic detergent active compound;

(ii) from 15 to 90% by weight of a saturated fatty acid builder salt containing at least 16 carbon atoms, or mixtures thereof; and

(ii) from 5 to 80% by weight of a carrier material, the carrier being a water-insoluble inorganic material selected from the following;

naturally occurring silice, precipitated silica, silica gels, alumina and aluminosilicates, clays and mixtures thereof; and

wherein said particles are prepared by distributing said nonionic active, said fatty acid builder salt, and said carrier material in water to form an aqueous solution and/or dispersion, mixing said combination, and evaporating water therefrom to obtain said built particles.

15. The method of claim 14, wherein the carrier material is bentonite clay.

16. A method for washing fabrics at cold water temperatures comprising contacting said fabrics below 50°

C. with built detergent particles comprising;

(i) from 5 to 50% by weight of a nonionic detergent active compound;

(ii) from 15 to 90% by weight of a saturated fatty acid builder sodium salt containing at least 16 carbon atoms, or mixtures thereof; and

(iii) from 5 to 80% by weight of a carrier material, the carrier material being chosen from water-insoluble inorganic materials, water-soluble inorganic materials, water-soluble organic materials selected from the group consisting of urea, crystalline sugars, polyhydric alcohols, amides, synthetic polymers, proteins and mixtures thereof; and

wherein said particles are prepared by distributing said nonionic active, said fatty acid builder salt, and said carrier material in water to form an aqueous solution and/or dispersion, mixing said combination, and evaporating water therefrom to obtain said built particles.

17. The method of claim 16 wherein the carrier material is sucrose.