Production of polyurethane foam

• US 4,696,952 A
• Filed: 07/19/1985
• Issued: 09/29/1987
• Est. Priority Date: 07/26/1984
• Status: Expired due to Fees

• Current Assignee: Bridgestone Corporation, Ikeda Bussan Co., Ltd. (Johnson Controls International plc)
• Original Assignee: Bridgestone Corporation, Ikeda Bussan Co., Ltd. (Johnson Controls International plc)
• Inventors: Shimomura, Kenji, Okuyama, Toru, Kouketsu, Shigeaki, Sato, Take
• Primary Examiner(s): NOT, DEFINED
• Assistant Examiner(s): Moore, M. L.
• Application Number:
  US06/756,800
• Time in Patent Office: 802 Days
• Field of Search: 521/107, 524/130, 524/141, 524/143, 528/65, 528/72
• US Class Current: 521/107
• CPC Class Codes: C08G 18/6511 compounds of group C08G18/3203
• CPC Class Codes: C08K 5/523 with hydroxyaryl compounds
• CPC Class Codes: C08L 75/04 Polyurethanes

Abstract

Flame-retardant polyurethane foam having a very good skin weldability and a very low level of skin staining is produced from a polyhydroxy compound, organic polyisocyanate, blowing agent, catalyst, foam stabilizer, and flame retardant, and other additives, wherein the flame retardant contains a triaryl phosphate ester and the polyhydroxy compound is a mixture composed of 100 parts by weight of high-molecular-weight polyhydroxy compound having a hydroxyl number lower than 100 and 0.5 to 10 parts by weight of low-molecular-weight polyhydroxy compound having a hydroxyl number higher than 560 and having 2 to 4 hydroxyl groups in one molecule.

Claims

1. A process for producing a flexible polyurethane foam which comprises reacting a polyhydroxy compound, organic polyisocyanate compound, blowing agent, catalyst, foam stabilizer, and flame retardant, wherein the flame retardant contains a triaryl phosphate ester presented by the following formula:

##STR6## wherein R₁ to R₆ are substituent groups independently selected from the group consisting of H and C_n H_2n+1 and n is an integer of 1 to 9, with the exception of the instances wherein R₁ =R₃ =R₅ =H and R₂ =R₄ =R₆ =CH₃,

and wherein said polyhydroxy compound is a mixture composed of (1) 100 parts by weight of a high-molecular-weight polyhydroxy compound having a hydroxyl number lower than 100 and (2) 0.5 to 10 parts by weight of a low-molecular-weight polyhydroxy compound having a hydroxyl number higher than 560 and having 2 to 4 hydroxyl groups in each molecule.

2. A process as claimed in claim 1, wherein the content of triaryl phosphate ester in the flame retardant is more than 50% by weight.

3. A process as claimed in claim 1, wherein the flame retardant is used in such an amount that the content of triaryl phosphate ester is 5 to 30 parts by weight for 100 parts by weight of the high-molecular-weight polyhydroxy compound.

4. A process as claimed in claim 1, wherein the triaryl phosphate ester contains 6 to 9.5% by weight of phosphorus.

5. A process as claimed in claim 2, wherein the flame retardant is used in such an amount that the content of triaryl phosphate ester is 5 to 30 parts by weight for 100 parts by weight of the high-molecular-weight polyhydroxy compound.

6. A process as claimed in claim 2, wherein the triaryl phosphate ester contains 6 to 9.5% by weight of phosphorus.

7. A process as claimed in claim 3, wherein the triaryl phosphate ester contains 6 to 9.5% by weight of phosphorus.

8. A process as claimed in claim 1, wherein the flame retardant consists essentially of said triaryl phosphate ester.

9. A process as claimed in claim 8, wherein the flame retardant is used in such an amount that the content of triaryl phosphate ester is 5 to 30 parts by weight for 100 parts by weight of the high-molecular-weight polyhydroxy compound.

10. A process as claimed in claim 1, wherein the flame retardant is selected from the group consisting of triaryl phosphate esters represented by the following formulae:

##STR7##

11. A process as claimed in claim 10, wherein the content of the triaryl phosphate ester in the flame retardant is more than 50% by weight.

12. A process as claimed in claim 10, wherein the content of triaryl phosphate ester in the flame retardant is 100% by weight.

13. A process as claimed in claim 1, wherein the polyhydroxy compound is a mixture composed of 100 parts by weight of a high-molecular-weight polyhydroxy compound and 0.5 to 5 parts by weight of a low-molecular-weight polyhydroxy compound.

14. A process according to claim 1, wherein the ratio of the amount of polyisocyanate used to the total amount of polyhydroxy compounds and other compounds having active hydrogen atoms is 103 to 112.

15. A process as claimed in claim 1, wherein the high-molecular-weight polyhydroxy compound is poly(oxypropylene) triol, the low-molecular-weight polyhydroxy compound is diethylene glycol, the organic polyisocyanate compound is tolylene diisocyanate, the blowing agent is water and trichlormonofluoromethane, the catalyst is triethylenediamine and stannous octoate, the foam stabilizer is a polyalkysiloxane-polyoxyethylene-polyoxypropylene copolymer, and the triaryl phosphate ester is a mixture of esters represented by the following formulae:

##STR8##