Process for producing electrically conductive composite polymer article

• US 4,699,804 A
• Filed: 12/17/1985
• Issued: 10/13/1987
• Est. Priority Date: 12/28/1984
• Status: Expired due to Fees

• Current Assignee: Hoechst Gosei Kabushiki Kaisha
• Original Assignee: Hoechst Gosei Kabushiki Kaisha
• Inventors: Miyata, Seizo, Ozio, Takeaki
• Primary Examiner(s): Morgenstern, Norman
• Assistant Examiner(s): Bell, Janyce A.
• Application Number:
  US06/809,814
• Time in Patent Office: 665 Days
• Field of Search: 427/302, 427/84, 427/267, 427/255.6, 427/322, 427/108
• US Class Current: 438/99
• CPC Class Codes: C08G 61/123 derived from five-membered heterocyclic compounds
• CPC Class Codes: C08G 73/0616 with only two nitrogen atoms in the ring
• CPC Class Codes: H01B 1/127 comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
• CPC Class Codes: H01B 1/128 comprising six-membered aromatic rings in the main chain, e.g. polyanilines, polyphenylenes
• CPC Class Codes: H01L 31/0224 Electrodes
• CPC Class Codes: H01L 31/07 the potential barriers being only of the Schottky type
• CPC Class Codes: H10K 85/111 comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
• CPC Class Codes: Y02E 10/50 Photovoltaic [PV] energy

Abstract

A process for producing an electrically conductive composite polymer article, which comprises contacting at least one polymerizable compound selected from the group consisting of heterocyclic compounds, derivatives thereof, aniline and aniline derivatives with a polymer article containing a polymerization catalyst for the polymerizable compound, and polymerizing the polymerizable compound to prepare an electrically conductive polymer on the surface of the polymer article or on the surface and in the polymer article. Schottky-barrier diodes and patterned electrodes can also be produced by utilizing the process. According to the process, process steps can be simplified, and various devices having excellent conductivity and transparency can be produced.

Claims

1. A process for producing a transparent electrically conductive composite polymer article, which comprises contacting a polymerizable compound with a catalyst-containing transparent polymer article, and polymerizing the polyerizable compound to prepare an electrically conductive polymer on at least the surface of the polymer article;

said polymerizable compound being selected from the group consisting of pyrrole, pyrrole derivatives, aniline and aniline derivatives; and

said catalyst-containing polymer article being prepared by casting a solution comprising a polymer which form a transparent article and a polymerization catalyst for the polymerizable compound.

2. The process of claim 1, wherein the pyrrole derivative is an N-alkylpyrrole.

3. The process of claim 1, wherein the aniline derivative is a member selected from the group consisting of an N-alkylaniline and an N-dialkylaniline.

4. The process of claim 1, wherein the polymerization is vapor state polymerization.

5. The process of claim 1, wherein the polymerization is liquid state polymerization.

6. A process for producing a Schottky-barrier diode, which comprises:

a step wherein a transparent, electrically conductive composite polymer article is produced by contacting a polymerizable compound with a catalyst-containing transparent polymer article, and polymerizing the polymerizable compound to prepare an electrically conductive polymer on at least the surface of the polymer article; and

a step wherein a Schottky-barrier contact is formed on the transparent electrically conductive composite polymer article;

said polymerizable compound being at least one selected from the group consisting of pyrrole, pyrrole derivatives, aniline and aniline derivatives; and

said catalyst-containing polymer article being prepared by casting a solution comprising a polymer which forms a transparent article and a polymerization catalyst for the polymerization compound.

7. A process for producing a patterned electrode, which comprises contacting a polymerizable compound with a patterned insulating substrate, and polymerizing the polymerizable compound to prepare a transparent electrically conductive polymer in the pattern;

said polymerizable compound being at least one member selected from the group consisting of pyrrole, pyrrole derivatives, aniline and aniline derivatives; and

said patterned insulating substrate being prepared by forming a pattern on an insulating substrate by using a solution comprising a polymer which forms a transparent article which a polymerization catalyst for the polymerizable compound.