Liquid crystal information storage device

• US 4,702,558 A
• Filed: 09/10/1984
• Issued: 10/27/1987
• Est. Priority Date: 09/14/1983
• Status: Expired due to Fees

• Current Assignee: Victoria University of Manchester The Oxford Road Manchester M13 9PL England An Institution Constituted To Royal Charter
• Original Assignee: The Victoria University of Manchester
• Inventors: Simon, Richard, Coles, Harry J.
• Primary Examiner(s): NOT, DEFINED
• Assistant Examiner(s): NOT, DEFINED
• Application Number:
  US06/648,519
• Time in Patent Office: 1,142 Days
• Field of Search: 252/299.01, 252/299.1, 252/299.66, 252/299.67, 350/350 R, 350/350 S, 350/351, 350/349, 350/330
• US Class Current: 349/22
• CPC Class Codes: C09K 19/02 characterised by optical, electrical or physical properties of the components, in general
• CPC Class Codes: C09K 19/408 Polysiloxanes
• CPC Class Codes: G02F 1/132 Thermal activation of liquid crystals exhibiting a thermo-optic effect
• CPC Class Codes: G02F 1/133362 Optically addressed liquid crystal cells G02F1/135 takes precedence
• CPC Class Codes: G02F 1/133365 Cells in which the active layer comprises a liquid crystalline polymer
• CPC Class Codes: G02F 1/13725 based on guest-host interaction G02F1/13762, G02F1/13737, take precedence
• CPC Class Codes: G02F 1/13762 containing luminescent or electroluminescent additives
• CPC Class Codes: G11B 13/00 Recording simultaneously or selectively by methods covered by different main groups among G11B3/00, G11B5/00, G11B7/00 and G11B9/00; Record carriers therefor not otherwise provided for; Reproducing therefrom not otherwise provided for G11B9/14, G11B11/002 take precedence; driving or moving of heads G11B3/02, G11B5/48, G11B7/08, G11B21/02
• CPC Class Codes: G11B 7/0045 Recording G11B7/006, G11B7/0065 take precedence
• CPC Class Codes: G11B 7/00555 involving liquid crystal media
• CPC Class Codes: G11B 7/245 containing a polymeric component
• CPC Class Codes: G11B 7/25 containing liquid crystals
• CPC Class Codes: Y10S 359/90 Methods

Abstract

A liquid crystal information storage device comprising a layer of material containing a side chain polymeric liquid crystal. At least a part of the material is heated from a viscous state above its glass transition temperature, to a fluid region in which the liquid crystalline material can readily undergo field-induced alignment. The material is addressed in this fluid region so as to achieve the selective variation in texture and orientation of molecules within the material and so record information, and the material is subsequently cooled and returned to its viscous state whereupon the information is retained.

Claims

1. A liquid crystal information storage device comprising a layer of material containing a side chain polymeric liquid crystal of a type having a glass transition temperature Tg less than ambient temperature Ta normally experienced atmospherically, and a further temperature Tr at which the viscosity suddenly decreases and above which the material becomes fluid while remaining in the same mesophase up to Tm, corresponding to the point at which the isotropic or clear phase first begins to appear, and is biphasic until Tc at which temperature the material becomes fully isotropic where Tc>

Tm>

Tr>

Ta>

Tq, means for effecting a thermal transition of at least a part of the material from a viscous state in which its temperature is in the range Tg to Tr, to the fluid region above Tr, and means for addressing at least a part of the material in the fluid region so as to achieve a selective variation in texture and orientation of molecules within the material and so record information, which information is retained on allowing the material to cool out of the fluid region and return to the viscous state.

2. A device according to claim 1, in which said layer of material contains a smectogenic side chain polymeric liquid crystal.

3. A device according to claim 1, wherein said polymeric liquid crystal is of the polysiloxane type having cyano-biphenyl side chains.

4. A device according to claim 3, wherein said polymeric liquid crystal contains benzoic ester side chains.

5. A device according to claim 4, in which said polymeric liquid crystal has a structure given by the formula ##STR14##

6. A device according to any preceding claim, in which said addressing means includes means for applying an electric field to the material thus to effect field-induced alignment in the form of a sine wave at a frequency of 2 to 4 kHz.

7. A device according to claim 1, in which said addressing means includes means for applying a magnetic field to the material.

8. A device according to claim 1, wherein said addressing means includes means for applying an optical field to the material.

9. A device according to claim 1, in which said layer of material is contained as a thin film between two superimposed transparent supporting plates.

10. A device according to claim 9, wherein transparent conductive films are deposited on the inner surface of said supporting plates.

11. A device according to claim 10, wherein said conductive films are etched to provide a desired display pattern.

12. A device according to claim 1, wherein said layer of material is provided as a surface coating on a backing sheet.

13. A device according to claim 1, wherein said polymeric liquid crystal has a temperature T_r in excess of 70°

C. and a clearing temperature in excess of 100°

C.

14. A device according to claim 1, wherein said polymeric liquid crystal has a molecular weight in excess of 3000.

15. A device according to claim 1, wherein said material contains a dye.

16. A device according to claim 15, wherein said material contains a dichroic or pleochroic dye.

17. A device according to claim 15, in which said material contains a fluorescent or non-linear dye.

18. A device according to claim 1, including a laser to serve as said means for effecting said thermal transition and said addressing means, and acting simultaneously to heat and optically address at least part of said material to record said information.

19. A method of producing a liquid crystal information storage device, comprising the steps of providing a layer of material containing a side chain polymeric liquid crystal of a type having a glass transition temperature Tg less than ambient temperature Ta normally experienced atmospherically, and a further temperature Tr at which the viscosity suddenly decreases and above which the material becomes fluid while remaining in the same mesophase up to Tm, corresponding to the point at which the isotropic or clear phase first begins to appear, and is biphasic until Tc at which temperature the material becomes fully isotropic where Tc>

Tm>

Tr>

Ta>

Tg, effecting a thermal transition of at least a part of the material from a viscous state in which its temperature is in the range Tg to Tr, to the fluid region above Tr, addressing at least a part of the material in the fluid region so as to achieve a selective variation in texture and orientation of molecules within the material and so record information, and allowing the material to cool out of the fluid region and return to the viscous state whereupon said information is retained.

20. A method according to claim 19, wherein said addressing is effected by field-induced alignment of the material at an elevated temperature below the inherent clearing temperature of said polymeric liquid crystal, said material being cooled to said viscous state prior to removing said field.

21. A variable transmission device in which there is provided an area of material containing a side chain polymeric liquid crystal of a type having a glass transition temperature Tg less than ambient temperature Ta normally experienced atmospherically, and a further temperature Tr at which the viscosity suddenly decreases and above which the material becomes fluid while remaining in the same mesophase up to Tm, corresponding to the point at which the isotropic or clear phase first begins to appear, and is biphasic until Tc at which temperature the material becomes fully isotropic where Tc>

Tm>

Tr>

Ta>

Tq, said crystal being disposed between two transparent surfaces, means to raise the temperature of at least a part of said material above Tr, means to address at least a part of the area containing the polymer to convert it to a transmitting from a less-transmitting state when above Tr which state is retained on allowing the material to cool to a temperature below Tr without an applied field.