Process for making electrically conductive textile filaments

• US 4,704,311 A
• Filed: 12/04/1985
• Issued: 11/03/1987
• Est. Priority Date: 12/04/1985
• Status: Expired due to Term

• Current Assignee: Shakespeare Conductive Fibers LLC (Newell Brands Inc.)
• Original Assignee: BASF Corporation (BASF SE)
• Inventors: Smith, Thomas E., Gusack, James A., Sanders, John H., Lindsay, John W., Streetman, William E., Pursoo, Johnson L., Paton, George A., Nichols, Sterling M., Pickering, Trevor P.
• Primary Examiner(s): Lawrence, Evan K.
• Application Number:
  US06/804,562
• Time in Patent Office: 699 Days
• Field of Search: 427/122, 427/175, 427/393.1, 427/177, 427/428, 118/234, 28/274
• US Class Current: 427/393.1
• CPC Class Codes: D06M 11/74 with carbon or graphite; with carbides; with graphitic acids or their salts
• CPC Class Codes: D06M 15/59 Polyamides; Polyimides

Abstract

This process for making antistatic filaments utilizes a specific mixture of compounds in order to suffuse electrically conductive particles into a filamentary polymeric substrate by forwarding the substrate through a grooved roll-type mix applicator. The mixture comprises a dispersion of the electrically conductive particles in liquid solvent which is a mixture of formic acid and a member selected from the group consisting of an amide, a carboxylic acid other than formic acid, an alcohol, an ester, a ketone, an ether, and a hydrocarbon. The process provides advantages over the prior art in permitting the use of high processing speeds, enabling easy stringup, and allowing the use of knotty and/or slubby filamentary substrates.

Claims

1. In a process of preparing an electrically conductive textile fiber from a moving non-conductive, filamentary polymer substrate in which a dispersion of finely-divided electrically-conductive particles is applied to the filamentary substrate in an amount sufficient to render the electrical resistance of the textile not more than about 10⁹ ohms/cm. in a liquid which is a solvent for the substrate but does not react with the electrically conductive particles, and the solvent is removed from the substrate after a desired degree of penetration has taken place in the annular region located at the periphery of the filament and before the structural integrity of the substrate has been destroyed, the improvement which comprises:

applying a mix to the nonconductive filamentary substrate with a grooved, roll-type mix applicator, the mix being comprised of a dispersion of electrically conductive particles in a liquid solvent wherein the liquid solvent will dissolve the substrate and will flash evaporate at 150°

C., and wherein the solvent is a mixture of formic acid and a member selected from the group consisting of;

(a) an amide;

(b) a carboxylic acid other than formic acid;

(c) an alcohol;

(d) an ester;

(e) a ketone;

(f) an ether; and

(g) a hydrocarbon.

2. A process as described in claim 1 wherein the solvent is a mixture of formic acid and a member selected from the group consisting of (a) dimethylformamide;

(b) dimethylacetamide; and

(c) acetic acid, the mix further comprising between 0.1% and 5% compatible polymer dissolved in the solvent.

3. A process as described in claim 2 wherein the solvent is a mixture of formic acid and acetic acid, and the solvent mixture comprises between 20% and 30% formic acid, and the filamentary polymer substrate is a monofilament having a denier between 7 and 20.

4. A process as described in claim 2 wherein the solvent is a mixture of formic acid and acetic acid, and the solvent mixture comprises between 30% and 40% formic acid, and the filamentary polymer substrate is a monofilament having a denier between 20 and 120.

5. A process as described in claim 2 wherein the filamentary polymeric substrate is forwarded at a speed greater than 2000 meters per minute.

6. A process as described in claim 2 wherein the solvent is a mixture of formic acid and acetic acid, and the acidic solvent mixture comprises between 20% and 40% formic acid.

7. A process as described in claim 6 wherein said compatible polymer is a corresponding polymer.

8. A process as described in claim 7 wherein both the filamentary polymer substrate and the corresponding polymer are nylon 6.

9. A process as described in claim 1 wherein the filamentary polymeric substrate is forwarded at a speed of at least 500 meters per minute.

10. A process as described in claim 1 wherein the solvent is removed from the filamentary polymeric substrate while the substrate is being forwarded in a substantially horizontal position.

11. A process as described in claim 1 wherein a supporting multifilamentary substrate is interlaced with the filamentary polymeric substrate after said solvent is removed.

12. A process as described in claim 1 wherein the roll-type mix applicator comprises a grooved roller member, the grooves of which a "V" cross-section and have both an apex angle between 50 and 100 degrees, and a depth between 0.010 inches and 0.030 inches.

13. A process as described in claim 12 wherein the grooved roller member has a diameter between 0.75 inches and 3.0 inches.

14. A process as described in claim 1 wherein the substrate has a denier between 5 and 5000.

15. A process as described in claim 1 wherein an evaporation tube and a counter-current flow of air having a temperature between 100°

C. and 200°

C. are utilized for solvent removal.

16. A process as described in claim 15 wherein the evaporation tube has a length between 10 and 20 feet.

17. A process as described in claim 1 wherein the roll-type mix applicator comprises a grooved roller member which has an outer surface made from a fiberglass-reinforced polytetrafluoroethylene material.

18. A process as described in claim 17 wherein the roll-type mix applicator comprises a steel stator member.