Method the hydrolytic splitting of acid treated comminuted crude cellulose with steam
First Claim
1. Method of acid-catalyzed hydrolytic splitting of cellulose to produce sugar, which method comprises treating comminuted crude cellulose pulp with acid in a concentration of 0.5 to 10% and draining the pulp, wherein the material to be hydrolyzed is drained to 10 to 80% of moisture and heated to a temperature of approximately 100°
- C., placing the heated drained pulp in a reaction vessel, feeding steam into said reaction vessel in three successive discrete reaction stages, and wherein said steam being fed in a first reaction stage I to increase the temperature to 175°
C. and the pressure to approximately 9 bar during a reaction time of about 40 seconds, said steam being successively fed in a second reaction stage to increase the temperature to 225°
C. and the pressure to about 26 bar during a reaction time of about 4.5 seconds, and said steam being successively fed in a third reaction stage to increase the temperature to approximately 260°
C. and the pressure to 48 bar during a reaction time of 1.3 seconds, and effecting a rapid expansion of said steam subsequent to the third reaction stage within about 5 seconds of time, and wherein steam from different expansion stages is conducted to separate pressure reservoirs and the waste steam of a (n+1)st stage is used to control the reaction conditions of a (n)th reaction stage of the respective next complete reaction stage course.
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Abstract
A method for acid-catalyzed hydrolytic splitting of cellulose to give a high yield in sugar with a minimal expenditure in energy, in particular, with the smallest possible charge of live steam. Admission of steam is performed in a plurality of successive, discrete reaction stages having in each case defined temperature and pressure values in such a manner that the temperature rises from one stage to the next while the reaction time decreases and a rapid expansion takes place subsequently to the last reaction stage. A high pressure poured bed reactor is used for performing this method.
33 Citations
1 Claim
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1. Method of acid-catalyzed hydrolytic splitting of cellulose to produce sugar, which method comprises treating comminuted crude cellulose pulp with acid in a concentration of 0.5 to 10% and draining the pulp, wherein the material to be hydrolyzed is drained to 10 to 80% of moisture and heated to a temperature of approximately 100°
- C., placing the heated drained pulp in a reaction vessel, feeding steam into said reaction vessel in three successive discrete reaction stages, and wherein said steam being fed in a first reaction stage I to increase the temperature to 175°
C. and the pressure to approximately 9 bar during a reaction time of about 40 seconds, said steam being successively fed in a second reaction stage to increase the temperature to 225°
C. and the pressure to about 26 bar during a reaction time of about 4.5 seconds, and said steam being successively fed in a third reaction stage to increase the temperature to approximately 260°
C. and the pressure to 48 bar during a reaction time of 1.3 seconds, and effecting a rapid expansion of said steam subsequent to the third reaction stage within about 5 seconds of time, and wherein steam from different expansion stages is conducted to separate pressure reservoirs and the waste steam of a (n+1)st stage is used to control the reaction conditions of a (n)th reaction stage of the respective next complete reaction stage course.
- C., placing the heated drained pulp in a reaction vessel, feeding steam into said reaction vessel in three successive discrete reaction stages, and wherein said steam being fed in a first reaction stage I to increase the temperature to 175°
Specification
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- Resources
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Current AssigneeWerner and Pfleiderer Co.
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Original AssigneeWerner and Pfleiderer Co.
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InventorsHinger, Klaus-Jurgen
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Primary Examiner(s)Alvo, Steve
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Application NumberUS06/683,183Time in Patent Office1,071 DaysField of Search162/68, 162/47, 162/14, 162/15, 162/16, 162/76, 162/19, 162/18, 162/21, 162/22, 162/24, 162/46, 127/37, 127/42, 127/43US Class Current127/37CPC Class CodesC13K 1/02 obtained by saccharificatio...
