Removal of water and carbon dioxide from atmospheric air

• US 4,711,645 A
• Filed: 02/10/1986
• Issued: 12/08/1987
• Est. Priority Date: 02/10/1986
• Status: Expired due to Fees

• Current Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Inventors: Kumar, Ravi
• Primary Examiner(s): SPITZER, ROBERT H
• Application Number:
  US06/828,008
• Time in Patent Office: 666 Days
• Field of Search: 55/25, 55/26, 55/31, 55/33, 55/35, 55/58, 55/62, 55/68, 55/74, 55/75
• US Class Current: 95/98
• CPC Class Codes: B01D 2253/104 Alumina
• CPC Class Codes: B01D 2253/108 Zeolites
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2257/80 Water
• CPC Class Codes: B01D 2259/40062 Four
• CPC Class Codes: B01D 2259/402 using two beds
• CPC Class Codes: B01D 2259/4146 Contiguous multilayered adsorbents
• CPC Class Codes: B01D 53/047 Pressure swing adsorption
• CPC Class Codes: B01D 53/261 by adsorption
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

Reduction in energy consumption is had in a system for adsorptive removal of moisture and CO₂ from atmospheric air by passing the feed air through consecutive beds of adsorbent comprising first alumina then molecular sieve zeolite, at near ambient temperature during adsorption of these impurities and subsequent regeneration of the sorbent laden beds by pressure reduction to about atmospheric level and purge at that level with product gas freed of water and CO₂.

Claims

1. The method of removing moisture and carbon dioxide from atmospheric air which comprises the steps of:

(a) passing the air at an inlet temperature in the range of about 70°

-120°

F. and at an inlet pressure in the range of about 50 to 150 psia through a first bed of adsorbent selective in removal of water from an air stream and then through a second bed of adsorbent effective in selective removal of carbon dioxide;

then regenerating said first and second adsorbent beds by

(b) reducing the pressure in said beds by gas withdrawal therefrom in a direction opposite that of step (a) to about atmospheric pressure level;

(c) and at the attained pressure level of step (b) purging both said beds with a gas stream freed of water and carbon dioxide, said gas stream being introduced into and passed through said second bed into and through said first bed;

followed by

(d) repressuring both said beds to a level in the range of 50-150 psia with product gas freed of water and carbon dioxide, passed into said beds in the same flow direction as step (c).

2. The method as defined in claim 1 wherein said first bed adsorbent is alumina.

3. The method as defined in claim 2 wherein said second bed adsorbent is a molecular sieve zeolite.

4. The method as defined in claim 1 wherein said first and second adsorbent beds comprise separate layers in a single adsorption column.

5. The method as defined in claim 1 wherein said first and second adsorbent beds are contained respectively in separate columns in direct gas flow communication.

6. The method as defined in claim 1 wherein the total time occupied during steps (b), (c) and (d) is that equal to the time period of step (a).

7. The method as defined in claim 1 wherein the entire sequence of steps (a) through (d) are carried out at close to the same temperature.