Polyethylene composites containing a phase change material having a C14 straight chain hydrocarbon

• US 4,711,813 A
• Filed: 11/22/1985
• Issued: 12/08/1987
• Est. Priority Date: 11/22/1985
• Status: Expired due to Term

• Current Assignee: University of Dayton
• Original Assignee: University of Dayton
• Inventors: Salyer, Ival O.
• Primary Examiner(s): Lilling, Herbert J.
• Application Number:
  US06/801,127
• Time in Patent Office: 746 Days
• Field of Search: 428/402, 524/8, 524/409, 524/411, 524/476, 524/477, 524/487, 524/464, 523/205, 252/70
• US Class Current: 428/402
• CPC Class Codes: C08K 5/01 Hydrocarbons C08K5/0091 takes precedence
• CPC Class Codes: C08L 23/06 Polyethene
• CPC Class Codes: C08L 2312/06 by radiation
• CPC Class Codes: C08L 91/06 Waxes
• CPC Class Codes: F28D 20/023 the latent heat storage material being enclosed in granular particles or dispersed in a porous, fibrous or cellular structure
• CPC Class Codes: Y02E 60/14 Thermal energy storage
• CPC Class Codes: Y10T 428/2982 Particulate matter [e.g., sphere, flake, etc.]

Abstract

A composite useful in thermal energy storage, said composite being formed of a polyethylene matrix having a straight chain alkyl hydrocarbon incorporated therein, said polyethylene being crosslinked to such a degree that said polyethylene matrix is form stable and said polyethylene matrix is capable of absorbing at least 10% by weight of said straight chain alkyl hydrocarbon; the composite is useful in forming pellets or sheets having thermal energy storage characteristics.

Claims

1. A composite useful in thermal energy storage, said composite being formed of a polyethylene matrix containing at least about 10% by weight of a straight chain alkyl hydrocarbon phase change material having at least 14 carbon atoms incorporated therein, said polyethylene being crosslinked to such a degree that said polyethylene matrix is capable of absorbing at least 10% by weight of said straight chain alkyl hydrocarbon phase change material.

2. The composite of claim 1 wherein said polyethylene is high density polyethylene.

3. The composite of claim 2 wherein said composite is a pellet.

4. The composite of claim 3 wherein said high density polyethylene is electron beam or gamma irradiation crosslinked.

5. The composite of claim 3 wherein said pellet contains about 40 to 80% by weight of said straight chain alkyl hydrocarbon.

6. The composite of claim 3 wherein said pellet ranges from about 1 micron to 2 mm in its largest dimension.

7. The composite of claim 3 wherein said high density polyethylene has a density of about 0.940 to 0.970 g/cc.

8. The composite of claim 3 wherein the crystalline alkyl hydrocarbon contains greater than 90% by weight of a single alkyl hydrocarbon having a heat of fusion greater than 50 cal/g.

9. The composite of claim 3 wherein said pellet contains a blend of at least two crystalline straight chain alkyl hydrocarbons having 14 or more carbon atoms and heats of fusion greater than 30 cal/g.

10. The composite of claim 9 wherein said blend has a melting and a freezing point in the range of 18°

to 33°

C.

11. The composite of claim 10 wherein said blend also contains a flame-retardant additive consisting of a halogenated hydrocarbon.

12. The composite of claim 11 wherein said blend additionally contains antimony oxide.

13. The composite of claim 11 wherein said halogenated hydrocarbon is a chlorinated alkyl hydrocarbon.

14. The composite of claim 9 wherein said composite essentially exhibits a single crystalline alkyl hydrocarbon phase change, plus that of high density polyethylene.

15. The composite of claim 9 wherein said composite exhibits two distinct crystalline alkyl hydrocarbon phase changes, plus that of high density polyethylene.

34. The composite of claim 1 wherein said composite is a sheet useful as a wall or floor covering.

35. The composite of claim 3 wherein said polyethylene has a gel content of at least 30%.

16. A thermal energy storage material comprising a non-polymeric cementitious matrix having pellets containing a phase change material dispersed therein, said pellets being formed from polyethylene matrix containing at least about 10% by weight of a straight chain alkyl hydrocarbon phase change material having at least 14 carbon atoms, said polyethylene matrix being crosslinked to such a degree that said pellets are form stable and are capable of absorbing at least 10% by weight of said straight chain alkyl hydrocarbon phase change material.

17. The material of claim 16 wherein said polyethylene is high density polyethylene.

18. The material of claim 17 wherein said high density polyethylene is electron beam or gamma irradiation crosslinked.

19. The material of claim 16 wherein said pellets contain about 40 to 80% by weight of said straight chain alkyl hydrocarbon.

20. The material of claim 16 wherein said pellets range from about 1 micron to 2 mm in their largest dimension.

21. The material of claim 17 wherein said high density polyethylene has a density of 0.940 to 0.970 g/cc.

22. The material of claim 16 wherein said concrete material contains about 5 to 25% by weight of said pellets.

23. The material of claim 16 wherein said pellets contain a blend of at least two crystalline straight chain alkyl hydrocarbons having 14 or more carbon atoms and heats of fusion greater than 30 cal/g.

24. The material of claim 23 wherein said blend has a melting point in the range of 18°

to 33°

C.

25. The material of claim 24 wherein said blend contains a flame-retardant halogenated alkyl hydrocarbon.

26. The material of claim 23 wherein said flame-retardant hydrocarbon is a chlorinated hydrocarbon.

27. The material of claim 16 wherein said nonpolymeric cementitious matrix is hydraulic cement, gypsum, plaster of Paris, or lime.

28. The material of claim 16 wherein said material is a block.

29. The material of claim 16 wherein said material is a brick.

30. The material of claim 16 wherein said material is a slab.

31. The material of claim 16 wherein said material is dry wall.

32. The material of claim 16 wherein said material is a cured cement product.

33. The material of claim 16 wherein said material is a cured plaster.

36. The material of claim 17 wherein said polyethylene has a gel content of at least 30%.