Spectrophotometric image scrambler for full aperture microspectroscopy

• US 4,712,912 A
• Filed: 03/10/1986
• Issued: 12/15/1987
• Est. Priority Date: 03/10/1986
• Status: Expired due to Fees

• Current Assignee: Spectra-Physics Incorporated (MKS Instruments Incorporated)
• Original Assignee: Spectra-Tech, Inc. (Thermo Fisher Scientific Incorporated)
• Inventors: Messerschmidt, Robert G.
• Primary Examiner(s): Evans, F. L.
• Assistant Examiner(s): Samuels, Fred
• Application Number:
  US06/837,672
• Time in Patent Office: 645 Days
• Field of Search: 356/73, 356/300, 356/303, 356/319, 356/320, 356/323, 356/324, 356/325, 356/330, 356/346, 356/445, 356/447, 356/448
• US Class Current: 356/73
• CPC Class Codes: G01J 3/02 Details
• CPC Class Codes: G01N 21/255 Details, e.g. use of specially adapted sources, lighting or optical systems
• CPC Class Codes: G01N 21/474 Details of optical heads therefor, e.g. using optical fibres
• CPC Class Codes: G01N 2201/0806 Light rod

Abstract

The optical system of the present invention comtemplates directing a beam of radiant energy to either an aperture beam splitter or polarizing beam splitter. Radiant energy from the beam splitter forms a first remote image at an entrance to an image scrambler so that any image information which the beam contains is destroyed. The output of the scrambler fills the full aperture of a focusing objective that reproduces the image of the output of the scrambler onto a sample. A mask, positioned at a remote image between the output of the scrambler and focusing objective, determines the geometrical shape of the sample image. The focusing objective images the radiant energy that is reflected from the sample to a second remote image at the scrambler so that the scrambler destroys image information while retaining spectroscopic information. The beam splitter reflects a portion of the radiant energy from the scrambler to the detector. The absence of image information in the radiant energy from the sample reduces measurement errors by producing a predictable dispersion of radiant energy at the detector.

Claims

1. An optical system for a spectrophotometer that has a source of a beam of radiant energy and a detector for the radiant energy, said optical system directing radiant energy from the source to a sample along an optical path, comprising:

means for scrambling the beam of radiant energy from the source said scrambling means being positioned to scramble a segment of the radiant energy from the source;

means for forming a sample image with the scrambled radiant energy from the source;

means for collecting radiant energy reflected from the sample, said radiant energy having image information about the sample;

said means for scrambling being positioned to also scramble said reflected radiant energy to destroy said sample image; and

means for directing said scrambled reflected radiant energy to the detector.

2. An optical system as claimed in claim 1, further comprising:

means for forming a first remote image with the segment of radiant energy from the source between the source and scrambling means along said optical path so that said scrambling means destroys said first image;

means for forming a second remote image with said scrambled radiant energy from the source; and

said means for forming the sample image forms an image corresponding to said second remote image at the sample.

3. An optical system as claimed in claim 2, further comprising means for masking said second remote image so that said sample image includes an image of said masking means.

4. An optical system as claimed in claim 2, further comprising a beam splitter positioned between the source and said scrambling means along the optical path, said scrambling means destroying any image imposed on the source by the beam splitter, said beam splitter directing a segment of the radiant energy from the source to the sample.

5. An optical system as claimed in claim 4, wherein:

said means for forming the sample image forms an image of the sample at the second remote image with radiant energy reflected from the sample;

said scrambling means being positioned to destroy said sample image; and

said beam splitter being positioned to reflect a portion of said reflected radiant energy to the detector.

6. An optical system as claimed in claim 5, wherein the radiant energy from the source and said reflected radiant energy are superimposed in space.

7. An optical system as claimed in claim 5, wherein said beam splitter comprises a facet splitter, said facet splitter having facets that are spaced apart by an average distance that is greater than the wavelength of the incident radiant energy, each of said facets having an incident and reflective face.

8. An optical system as claimed in claim 7, wherein

said incident face of said facets form an angle of substantially 67.5°

relative to a normal to the facet splitter; and

said reflective face of said facets form an angle of substantially 67.5°

relative to a normal to the facet splitter.

9. An optical system as claimed in claim 7, further comprising means for condensing the radiant energy from the source after it is reflected from said reflective face of said facets.

10. An optical system as claimed in claim 9 wherein said means for condensing the radiant energy comprises a tapered light pipe, said tapered light pipe having first and second ends positioned at said first and second remote images, respectively, said first end having a larger cross sectional area than said second end.

11. An optical system as claimed in claim 5, wherein said beam splitter comprises an intercepting mirror positioned to intercept half of the beam of radiant energy from the source.

12. An optical system as claimed in claim 5, wherein said beam splitter comprises a polarizing screen.

13. An optical system as claimed in claim 5, wherein said beam splitter comprises an island splitter, said island splitter having reflective surfaces that have an average size that is comparable to or greater than the wavelength of the radiant energy.

14. An optical system as claimed in claim 5, wherein said means for forming said sample image comprises means for directing the radiant energy from the source to the sample at grazing angles and receiving radiant energy reflected from the surface at grazing angles.

15. An optical system as claimed in claim 2, wherein

said means for scrambling the radiant energy comprises a light pipe having first and second ends, said first end being positioned at said first remote image so that the radiant energy diverging from said first image reflects from the sides of said light pipe;

and

said second end being positioned at said second image focus to scramble the radiant energy reflected from the sample.

16. An optical system as claimed in claim 15, wherein said light pipe comprises a total internal reflectance crystal.

17. An optical system as claimed in claim 15, wherein said light pipe comprises reflective surfaces arranged to form a hollow inner chamber, said reflective surfaces specularly reflecting radiant energy.

18. An optical system as claimed in claim 1, wherein

said means for collecting radiant energy emitted from the sample is positioned to collect radiant energy that is transmitted through the sample.

19. A method for obtaining a spectrum with a spectrophotometer that has a source of a beam of radiant energy and a detector for the radiant energy, including the steps of directing radiant energy from the source to a sample along an optical path, comprising the steps of:

scrambling a segment of the beam of radiant energy from the source;

forming a sample image with the scrambled radiant energy from the source;

collecting radiant energy reflected from the sample, said radiant energy having image information about the sample;

scrambling said reflected radiant energy to destroy said sample image; and

directing said scrambled radiant energy to the detector.

20. The method as claimed in claim 19, wherein the step of forming the sample image further comprises the steps of:

forming a first remote image with the segment of radiant energy from the source between the source and scrambling means along said optical path so that said scrambling means destroys said first image;

forming a second remote image with said scrambled radiant energy from the source; and

forming an image at the sample corresponding to said second remote image.

21. The method as claimed in claim 20, further comprising the step of masking said second remote image so that said sample image includes an image of said masking means.

22. The method as claimed in claim 20 further comprising the steps of directing a segment of the radiant energy from the source to the sample with a beam splitter, said beam splitter being positioned betwen the source and scrambling means so that the scrambling means destroys any image imposed on the source by the beam splitter.

23. The method as claimed in claim 20, further comprising the steps of:

forming the sample image at the second remote image with radiant energy reflected from the sample;

scrambling said sample image; and

reflecting a portion of said emitted radiant energy to the detector with a beam splitter.

24. The method as claimed in claim 23, wherein said radiant energy from the source and said reflected radiant energy from the sample are superimposed in space.

25. The method as claimed in claim 20 further comprising the steps of:

directing of radiant energy to a bottom surface of the sample to form said sample image; and

collecting radiant energy that is transmitted through the sample and emitted from a top surface of the sample.