Composite facestocks and liners

• US 4,713,273 A
• Filed: 04/18/1986
• Issued: 12/15/1987
• Est. Priority Date: 02/05/1985
• Status: Expired due to Term

• Current Assignee: Avery Dennison Corporation
• Original Assignee: Avery Dennison Corporation
• Inventors: Freedman, Melvin S.
• Primary Examiner(s): HERBERT JR, THOMAS
• Application Number:
  US06/853,772
• Time in Patent Office: 606 Days
• Field of Search: 428/202, 428/40, 428/41, 428/343, 428/352, 428/354, 428/409, 428/516, 428/518, 428/213, 428/323, 428/319.3, 428/324, 156/244.11, 156/244.24
• US Class Current: 428/41.8
• CPC Class Codes: B29K 2995/0072 Roughness, e.g. anti-slip
• CPC Class Codes: B29K 2995/0081 Tear strength
• CPC Class Codes: B32B 2307/538 Roughness
• CPC Class Codes: B32B 2307/734 Dimensional stability
• CPC Class Codes: B32B 2310/14 Corona, ionisation, electrical discharge, plasma treatment
• CPC Class Codes: B32B 2327/06 PVC, i.e. polyvinylchloride
• CPC Class Codes: B32B 2329/00 Polyvinylalcohols, polyvinylethers, polyvinylaldehydes, polyvinylketones or polyvinylketals
• CPC Class Codes: B32B 2519/00 Labels, badges
• CPC Class Codes: B32B 2590/00 Signboards, advertising panels, road signs
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/20 using fillers, pigments, thixotroping agents
• CPC Class Codes: B32B 27/286 comprising polysulphones; polysulfides
• CPC Class Codes: B32B 27/302 comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
• CPC Class Codes: B32B 27/304 comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
• CPC Class Codes: B32B 27/306 comprising vinyl acetate or vinyl alcohol (co)polymers
• CPC Class Codes: B32B 27/308 comprising acrylic (co)polymers
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 27/34 comprising polyamides
• CPC Class Codes: B32B 27/365 comprising polycarbonates
• CPC Class Codes: B32B 27/40 comprising polyurethanes
• CPC Class Codes: B32B 37/12 : characterised by using adhesives
• CPC Class Codes: B32B 38/0008 : Electrical discharge treatment, e.g. corona, plasma treatment; wave energy or particle radiation heat treatment B32B38/0036
• CPC Class Codes: B32B 7/06 : permitting easy separation
• CPC Class Codes: C09J 2203/334 : as a label
• CPC Class Codes: C09J 2301/162 : the carrier being a laminate constituted by plastic layers only
• CPC Class Codes: C09J 2301/302 : the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
• CPC Class Codes: C09J 2423/006 : in the substrate
• CPC Class Codes: C09J 2427/006 : in the substrate
• CPC Class Codes: C09J 2431/006 : in the substrate
• CPC Class Codes: C09J 7/243 : Ethylene or propylene polymers
• CPC Class Codes: C09J 7/245 : Vinyl resins, e.g. polyvinyl chloride [PVC]
• CPC Class Codes: C09J 7/29 : Laminated material metallised plastics C09J7/22
• CPC Class Codes: G09F 2003/0202 : printed before use
• CPC Class Codes: G09F 2003/021 : Indicia behind the front foil
• CPC Class Codes: G09F 2003/023 : Adhesive
• CPC Class Codes: G09F 2003/0233 : Resistance to humidity
• CPC Class Codes: G09F 2003/0241 : Repositionable or pressure sensitive adhesive
• CPC Class Codes: G09F 3/02 : Forms or constructions layered products B32B
• CPC Class Codes: Y10S 428/914 : Transfer or decalcomania
• CPC Class Codes: Y10T 428/1476 : Release layer
• CPC Class Codes: Y10T 428/2495 : Thickness [relative or absolute]
• CPC Class Codes: Y10T 428/249991 : Synthetic resin or natural rubbers
• CPC Class Codes: Y10T 428/25 : Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
• CPC Class Codes: Y10T 428/251 : Mica
• CPC Class Codes: Y10T 428/28 : Web or sheet containing structurally defined element or component and having an adhesive outermost layer
• CPC Class Codes: Y10T 428/2839 : with release or antistick coating
• CPC Class Codes: Y10T 428/2848 : Three or more layers
• CPC Class Codes: Y10T 428/31 : Surface property or characteristic of web, sheet or block
• CPC Class Codes: Y10T 428/31913 : Monoolefin polymer
• CPC Class Codes: Y10T 428/3192 : Next to vinyl or vinylidene chloride polymer

Abstract

Film-forming means are coextruded to form all plastic multilayer liners and facestocks for pressure-sensitive labels, tapes, decals, signs, bumper stickers, and other products formed from sheet and roll stock. Fill means in a charge for the liner coextrusion affects stiffness and dimensional stability of the liner and/or affects the roughness of a liner face or faces. The film materials of the layers of the constructions are selected according to the cost/benefit characteristics of candidate materials considering the functional or operational requirements of the layer in question.

Claims

1. A liner comprising a multilayer web construction for use with label, tape or sign stock, said web construction comprising a coextrudate in the form of at least two firmly adhered layers, at least one of said layers comprising a multiphase layer including a continuous phase of polymeric film material and a discontinuous phase of filler material, said liner having at least one face that is roughened at least in part by the mechanical effect of the filler material contained in said coextrudate, to a roughness of at least about 10 Sheffield units, a release face provided on one face of said liner.

2. A liner as in claim 1, wherein said release face comprises a release coating.

3. A liner as in claim 1, wherein at least two layers of the coextrudate contain filler.

4. A liner as in claim 1, wherein the roughness of each face of said liner is at least about 10 Sheffield units.

5. A liner as in claim 4, wherein each of said faces is roughened at least in part by the mechanical effect of the filler.

6. A liner as in claim 1, wherein said web construction comprises a core or base layer, a first skin layer on the side of said core or base layer associated with a first face, a second skin layer on the side of said core or base layer associated with a second face, and release means at said second face, said core or base layer comprising said at least one multiphase layer with its filler therein, and said first skin layer also having filler therein.

7. A liner as in claim 6, wherein said second face is roughened at least in part by the mechanical effect of the filler in said core or base, acting through said second skin.

8. A liner as in claim 6, wherein said filler in said core or base layer comprises between about 5% and 40% by weight.

9. Roll or sheet stock for pressure-sensitive labels, tapes, signs, or other graphics comprising a liner web construction as in claim 1 combined with face-stock by a pressure-sensitive adhesive layer which is releasably supported on said release means.

10. Roll or sheet stock as in claim 9, wherein the face of said adhesive adjoining said release means is roughened at least in part by said mechanical effect of said filler in said coextrudate, whereby upon separation of said pressure-sensitive adhesive and facestock from said liner web construction the exposed face of said adhesive exhibits the surface roughness imposed by said filler.

11. A liner comprising a multilayer web construction for use with label, tape, or sign stock, said web construction comprising a coextrudate in the form of a multiphase core or base layer and a skin layer on at least one side of the core or base layer, said core or base layer including a continuous phase of polymeric film material and a discontinuous phase of filler material, said filler material comprising by weight a minority of the total core composition, both said phases being dimensionally stable under conditions of moisture absorption or desorption, both said layers being substantially free of connected voids, whereby dimensional stability of said construction is independent of humidity conditions, and said construction therefore remains flat under varying humidity conditions as encountered at different geographic locations or at the same location at different times, and under varying web temperature conditions as encountered in hot air drying of inks or coatings for face-stocks with which the liner is used.

12. A liner as in claim 11, the filler in said core or base layer acting through said skin layer to contribute to roughening of the face of said release layer.

13. A liner as in claim 11, said skin layer comprising a polymeric film effective to receive and anchor a release layer while acting as a stop against absorption of said release layer into said core or base layer, and a release layer on said skin layer.

14. A liner as in claim 13, having a skin layer on each side of said core or base layer.

15. A liner as in claim 14, the filler in said core or base layer acting through the skin layer on the side identified with said release layer to contribute to roughening the face of said release layer.

16. A liner as in claim 15, said face of said release layer being roughened to a roughness of at least about 10 Sheffield units.

17. As an article of manufacture, a multiphase thermoplastic flexible extruded film comprising a continuous phase of film-forming plastic compound, a discontinuous phase of filler particles including high-aspectratio filler particles oriented at least in the machine direction, and a phase of voids each located adjacent to or around its own associated filler particle and in isolated relationship to other voids.

18. An article of manufacture as in claim 17, in which said filler includes mica platelets.

19. A multilayer facestock for use in pressure-sensitive label, tape or sign applications comprising a coextrudate of cojoined layers comprising a relatively thick core or base layer of polymeric film material of a stiffness of between 10 and 100 Gurley and which contributes the majority of the dimensional stability and stiffness of labels or signs cut or formed from the facestock, and at least one relatively thin skin layer, said skin layer being on the face side of the coextrudate and having an ink-printable surface, and a pressure-sensitive adhesive layer combined at the side of said coextrudate opposite said face side.

20. Stock as in claim 19, including a second skin layer on the core or base layer between the core or base layer and the adhesive layer.

21. Stock comprising the adhesive bearing face stock of claim 19 combined on its adhesive side with a releasable liner.

22. Stock as in claim 19, in which said core or base material is polyethylene of a specific gravity of between about 0.890 and 0.965 or a polypropylene polymer or copolymer with a flex modulus range of between 130,000 and 250,000 psi at 73°

F.

23. Stock as in claim 22, in which said skin layer comprises polyethylene vinyl acetate or polyvinyl chloride.

24. Stock as in claim 19, said coextrudate having a tie layer between said core or base layer and said at least one skin layer.

25. Stock as in claim 24, said coextrudate having a tie layer between said core layer and each skin layer.

26. A liner comprising a multilayer web construction for use with label, tape and sign stock, said web construction comprising oriented stretched coextrudate in the form of at least two firmly adhered layers, at least one of said layers comprising a multi-phase layer including a continuous phase of polymeric film material, a discontinuous phase of solid filler material and a discontinuous phase of voids associated with and partly surrounding particles of said solid filler material.

27. A liner as in claim 26, said solid filler material including particles whose major dimension exceeds a majority of the thickness of the layer in which they are received.

28. A liner as in claim 27, said solid filler material including high-aspect-ratio particles oriented in the lengthwise direction and lumpy particles which on the average occupy a greater proportion of the thickness of the coextrudate than do the high-aspect-ratio particles.

29. A liner as in claim 28, said lumpy particles including particles whose major dimension exceeds the majority of the thickness of the layer in which they are received.

30. A multilayer stock for use in pressure-sensitive label, tape or sign applications comprising a facestock and a releasable liner, said facestock comprising a coextrudate of cojoined layers comprising a relatively thick core or base layer of polymeric film material of a stiffness of between 10 and 100 Gurley and which contributes the majority of the dimensional stability and stiffness of labels or signs cut or formed form the facestock, and at least one relatively thin skin layer, said skin layer being on the face side of the coextrudate and having an ink-printable surface, and a pressure-sensitive adhesive layer combined at the side of said coextrudate opposite said face side, said releasable liner being combined on the adhesive side of said facestock, said releasable liner comprising a multilayer web liner construction, said multilayer web liner construction comprising a coextrudate in the form of at least two firmly adhered layers, at least one of said layers comprising a multiphase layer including a continuous phase of polymeric film material and a discontinuous phase of filler material, said liner having at least one face that is roughened at least in part by the mechanical effect of the filler material contained in said coextrudate, to a roughness of at least about 10 Sheffield units, and a release face provided on one face of said liner for releasable contact with said pressure-sensitive adhesive layer of said facestock.