Use of degradable ball sealers to seal casing perforations in well treatment fluid diversion

• US 4,716,964 A
• Filed: 12/10/1986
• Issued: 01/05/1988
• Est. Priority Date: 08/10/1981
• Status: Expired due to Fees

• Current Assignee: Exxon Production Research Company (Exxon Mobil Corporation)
• Original Assignee: Exxon Production Research Company (Exxon Mobil Corporation)
• Inventors: Cooke, Claude E. Jr., Epstein, Michael M., Erbstoesser, Steven R., Sinclair, Richard G.
• Primary Examiner(s): Novosad, Stephen J.
• Application Number:
  US06/940,193
• Time in Patent Office: 391 Days
• Field of Search: 166/284, 166/295, 528/354, 528/355, 528/361
• US Class Current: 166/284
• CPC Class Codes: C08G 63/08 Lactones or lactides
• CPC Class Codes: C09K 8/50 Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls compositions for consolidating loose sand or the like around wells C09K8/56

Abstract

Plugging perforations in casing in a wellbore penetrating a subterranean formation using degradale ball sealers. The ball sealer used is composed of a polyester polymer which is substantially insoluble in the wellbore fluid. The polymer degrades in the presence of water at an elevated temperature to form small molecules which are soluble in a fluid in the subterranean formation. After the polymer degrades, the flow through the perforation returns to substantially its initial value.

Claims

1. A method of plugging the perforations in a casing which has been set in a wellbore which penetrates a subterranean formation comprising:

(a) flowing down said casing a wellbore fluid having dispersed therein a plurality of ball sealers, said ball sealers being sized to seal said perforations and being comprised of a polyester polymer which is substantially insoluble in said wellbore fluid and degradable in the presence of water at the formation temperature to oligomers which are at least partially soluble in a formation fluid, and

(b) continuing the flow of said wellbore fluid until at least a portion of said perforations are sealed by said ball sealers.

2. A method of plugging the perforations in a casing which has been set in a wellbore which penetrates a subterranean formation comprising:

(a) flowing down said casing a wellbore fluid having dispersed therein a plurality of ball sealers, said ball sealers being sized to seal said perforations and being comprised of a polymer having the repeating unit;

##STR3## wherein R is H, C₁ to C₄ alkyl and n is sufficiently large to form a solid polymer, said polymer being substantially insoluble in said wellbore fluid and degradable in the presence of water at an elevated temperature to oligomers which are at least partially soluble in oil or water; and

(b) continuing the flow of said wellbore fluid until at least a portion of said perforations are sealed by said ball sealers.

3. The method of claim 2 wherein said polymer is selected from the group consisting of poly (D,L-lactide) crosslinked poly (D,L-lactide) and copolymers of glycolide and D, L-lactide.

4. The method of claim 2 wherein said ball sealers are substantially spherical with a diameter greater than one-quarter inch.

5. The method of claim 4 wherein the diameter is in the range one-half inch to one inch.