Highly-refractive plastic lens

• US 4,721,377 A
• Filed: 02/25/1987
• Issued: 01/26/1988
• Est. Priority Date: 09/19/1984
• Status: Expired due to Fees

• Current Assignee: Toray Industries Incorporated
• Original Assignee: Toray Industries Incorporated
• Inventors: Saito, Masami, Fukuda, Tadanori, Sakamoto, Sadayuki
• Primary Examiner(s): HENDERSON JR, CHRISTOPHER A
• Application Number:
  US07/020,156
• Time in Patent Office: 335 Days
• Field of Search: 350/409, 350/410, 351/159, 351/160
• US Class Current: 351/159
• CPC Class Codes: C08L 33/16 Homopolymers or copolymers of esters containing halogen atoms
• CPC Class Codes: G02B 1/04 made of organic materials, e.g. plastics G02B1/08 takes precedence
• CPC Class Codes: G02B 1/041 Lenses

Abstract

A plastic lens formed from a copolymer of three components. A first component which is a vinyl monomer having a nucleus-halogen-substituted aromatic ring. A second component which is selected from at least one member of the group consisting of aliphatic diacrylate, dimethacrylate, triacrylate, and trimethacrylate. A third component is chosen from mono-acrylate or mono-methacrylate having a nucleus-halogen substituted aromatic ring. The components are present in the weight ratio of 20/15/0 to 85/80/60 weight percent, respectively.

Claims

1. A plastic lens which comprises a copolymer of (A) 20 to 85 percent by weight of dibromostyrene with (B) 15 to 80 percent by weight of at least one member selected from the group consisting of aliphatic diacrylate, dimethacrylate, triacrylate and trimethacrylate, and (C) less than 60 percent by weight of mono-acrylate, or monomethacrylate having a nucleus-halogen substituted aromatic ring, said copolymer being in the form of a lens.

2. A plastic lens according to claim 1, wherein the component C is at least one member selected from the group represented by the following general formulae V and VI ##STR7## wherein X is chlorine, bromine or iodine, R₅ is a methyl group or hydrogen, W is one of ##STR8## and r is an integer of from 1 to 5.

3. A plastic lens according to claim 1, wherein the polymer is formed by cast-polymerization.

4. A plastic lens according to claim 1, wherein component B is ethylene glycol dimethacrylate.

5. A plastic lens according to claim 1, wherein component B is aliphatic diacrylate and/or dimethacrylate represented by the following general formulae II. ##STR9## wherein R₁ is a methyl group hydrogen, Y is one being selected out of groups ##STR10## whereby b is an integer of from 3 to 10, l is an integer of from 1 to 10.

6. A plastic lens according to claim 1, wherein component C is a monomer represented by the following general formulae VI ##STR11## wherein X is chlorine, bromine, or iodine, R₅ is a methyl group or hydrogen, W is one being selected out of groups ##STR12## and r is an integer of from 1 to 5, and S in an integer of from 1 to 4.

7. A plastic lens according to claim 1, wherein component B is ethylene glycol dimethacrylate.

8. A plastic lens according to claim 1, wherein component C is 2,3,4,5,6-pentabromophenoxyethyl acrylate.