Natural gas desulphurizing apparatus and method

• US 4,722,799 A
• Filed: 09/17/1985
• Issued: 02/02/1988
• Est. Priority Date: 04/24/1985
• Status: Expired due to Fees

• Current Assignee: Quinetics Corporation, VRTX Technologies, LLC
• Original Assignee: Clifford L. Ashbrook
• Inventors: Scarborough, Douglas B., Ashbrook, Clifford L.
• Primary Examiner(s): Fisher, Richard V.
• Assistant Examiner(s): Jones, W. Gary
• Application Number:
  US06/776,830
• Time in Patent Office: 868 Days
• Field of Search: 422/170, 55/228, 423/224, 423/225, 423/231, 423/242, 423/573 R, 423/573 G, 210/86, 210/104, 210/188, 210/194, 210/195.1, 210/257.1, 210/695, 210/744, 210/750, 210/758, 210/760, 210/800, 210/805, 210/807, 210/721, 210/722
• US Class Current: 210/722
• CPC Class Codes: C02F 1/34 with mechanical oscillations
• CPC Class Codes: C02F 1/482 located on the outer wall of the treatment device, i.e. not in contact with the liquid to be treated, e.g. detachable
• CPC Class Codes: C02F 1/78 with ozone C02F1/4672 takes precedence
• CPC Class Codes: C02F 2301/024 Turbulent
• CPC Class Codes: C02F 2301/026 Spiral, helicoidal, radial

Abstract

A desulphurization apparatus and method for natural gas in which red iron oxide is reacted with the sulphur compounds found in natural gas to remove these compounds from the gas. The treating solution is then recycled to regenerate the red iron oxide solution with elemental sulphur formed as a byproduct for removal.

Claims

1. A method for continuously desulphurizing natural gas and continuously regenerating a reaction solution, comprising the steps of:

reacting natural gas in a substantially closed tower by contacting said gas with a metallic oxide solution so as to substantially oxidize the sulphurous compounds in said gas;

degassing said reaction solution by transporting said reaction solution through a colloid mill and venting entrained gases released therefrom;

continuously regenerating said reaction solution by treating said reaction solution with an oxidizing agent to reduce the sulphur in said reaction solution to cause it to precipitate for collection and recycling said solution to said tower for additional reactions.

2. The method as set forth in claim 1, wherein:

said recycling step is comprised of removing said solution from a collector tank and pumping said solution through one side of a colloid mill simultaneous to said oxidizing agent being pumped through the other side of said colloid mill.

3. The method of claim 1 wherein:

said oxidizing agent is oxygen.

4. The method of claim 1 wherein:

said oxidizing agent is ozone.

5. An apparatus for continuously desulphurizing natural gas and regenerating a reaction solution comprising:

a contacting means comprised of a tower and solution removal means, said contacting means for contacting natural gas with said reaction solution to substantially oxidize sulphurous compounds in said natural gas;

a treating means comprised of a collector tank and a recycling means, said recycling means operably connected to said contacting means and said collector tank, said treating means for continuously regenerating said reaction solution, said recycling means for circulating said reaction solution through said contacting means and said treating means;

a degassing means operably connected to said contacting means and said treating means, said degassing means for removing entrained gases from said reaction solution;

said degassing means is comprised of a colloid mill;

said recycling means reducing sulphurous compounds in said solution and causing sulphur to precipitate from said solution, said sulphur being removed by a removal mechanism.

6. The apparatus of claim 5 wherein:

said recycling means is comprised of a colloid mill.

7. The apparatus of claim 5 wherein:

said tower is comprised of packing material placed on a plurality of vertically spaced trays;

said packing material is comprised of raschies;

said tower having a nozzle for introducing said reaction solution into said tower and a gas inlet for introducing natural gas into said tower and contacting said natural gas with said reaction solution through said packing material.

8. The apparatus of claim 5 wherein:

said removal mechanism is comprised of a filter.

9. The apparatus of claim 5 wherein:

said removal mechanism is comprised of a drain valve.

10. The apparatus of claim 5 wherein:

said collector tank is a substantially closed, hollow structure comprised of at least two sections partially separated by partitions, said sections being a used solution section receiving solution from said degassing means and a recycled solution section providing said reaction solution to said contacting means.

11. An apparatus for continuously desulphurizing natural gas and regenerating a reaction solution comprising:

a contacting means comprised of a tower and solution removal means, said contacting means for contacting natural gas with said reaction solution to substantially oxidize sulphurous compounds in said natural gas;

a treating means comprised of a collector tank and a recycling means, said recycling means operably connected to said contacting means and said collector tank, said treating means for continuously regenerating said reaction solution, said recycling means for circulating said reaction solution through said contacting means and said treating means;

a degassing means operably connected to said contacting means and said treating means, said degassing means for removing entrained gases from said reaction solution;

said recycling means is comprised of a colloid mill;

said recycling means reducing sulphurous compounds in said solution and causing sulphur to precipitate from said solution, said sulphur being removed by a removal mechanism.

12. The apparatus of claim 11 wherein:

said degassing means is comprised of a colloid mill.

13. The apparatus of claim 11 wherein:

said tower is comprised of packing material placed on a plurality of vertically spaced trays;

said packing material is comprised of raschies;

said tower having a nozzle for introducing said reaction solution into said tower and a gas inlet for introducing natural gas into said tower and contacting said natural gas with said reaction solution through said packing material.

14. The apparatus of claim 11 wherein:

said removal mechanism is comprised of a filter.

15. The apparatus of claim 11 wherein:

said removal mechanism is comprised of a drain valve.

16. The apparatus of claim 11 wherein:

said collector tank is a substantially closed, hollow structure comprised of at least two sections partially separated by partitions, said sections being a used solution section receiving solution from said degassing means and a recycled solution section providing said reaction solution to said contacting means.