Gas separation by pressure swing adsorption

• US 4,723,966 A
• Filed: 12/11/1986
• Issued: 02/09/1988
• Est. Priority Date: 12/11/1986
• Status: Expired due to Fees

• Current Assignee: UOP Des Plaines IL A NY General Partnership
• Original Assignee: Union Carbide Corporation (Dow, Inc.)
• Inventors: Fuderer, Andrija
• Primary Examiner(s): SPITZER, ROBERT H
• Application Number:
  US06/940,612
• Time in Patent Office: 425 Days
• Field of Search: 55/25, 55/26, 55/58, 55/59, 55/62, 55/68, 55/74, 55/75
• US Class Current: 95/98
• CPC Class Codes: B01D 2253/102 Carbon
• CPC Class Codes: B01D 2253/104 Alumina
• CPC Class Codes: B01D 2253/106 Silica or silicates
• CPC Class Codes: B01D 2253/108 Zeolites
• CPC Class Codes: B01D 2253/304 Linear dimensions, e.g. particle shape, diameter
• CPC Class Codes: B01D 2256/10 Nitrogen
• CPC Class Codes: B01D 2256/16 Hydrogen
• CPC Class Codes: B01D 2256/22 Carbon dioxide
• CPC Class Codes: B01D 2257/104 Oxygen
• CPC Class Codes: B01D 2257/502 Carbon monoxide
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2257/7025 Methane
• CPC Class Codes: B01D 2259/4003 with two sub-steps
• CPC Class Codes: B01D 2259/40032 with three sub-steps
• CPC Class Codes: B01D 2259/40041 with more than three sub-steps
• CPC Class Codes: B01D 2259/40052 Recycled product or process gas
• CPC Class Codes: B01D 2259/40066 Six
• CPC Class Codes: B01D 2259/40067 Seven
• CPC Class Codes: B01D 2259/40071 Nine
• CPC Class Codes: B01D 2259/40073 Ten
• CPC Class Codes: B01D 2259/404 : using four beds
• CPC Class Codes: B01D 2259/4062 : using six beds
• CPC Class Codes: B01D 2259/4066 : using nine beds
• CPC Class Codes: B01D 2259/4146 : Contiguous multilayered adsorbents
• CPC Class Codes: B01D 53/047 : Pressure swing adsorption
• CPC Class Codes: B01D 53/0476 : Vacuum pressure swing adsorption
• CPC Class Codes: Y02C 20/20 : of methane
• CPC Class Codes: Y02C 20/40 : of CO2

Abstract

A pressure swing adsorption process is disclosed wherein binary gas purification is effected from a single adsorbent bed. An adsorbent bed is charged under pressure with a gas mixture having some components that are more adsorbable than others. The process causes the bed to be polarized with one end of the bed containing the more adsorbable components and the other end containing the less adsorbable components. Once charged, the bed is depressurized simultaneously from both ends, thus removing the separated components from their respective ends.

Claims

1. A method for gas separation of adsorbable components from less adsorbable components on fixed adsorbent beds, comprising the steps of:

(a) flowing a feed gas mixture under adsorption pressure to an adsorbent bed to selectively adsorb components from said feed gas onto the adsorbent bed, said bed having a feed end and a product end; and

(b) displacing said feed gas with a gas having a higher concentration of adsorbable components, whereby less adsorbable components are displaced from a portion of the bed; and

(c) depressurizing the bed by taking out gas simultaneously from at least two different locations of the bed to recover essentially pure less adsorbable components at the product end of the bed and to recover the adsorbable components from at least one of the different locations; and

(d) pressurizing the bed.

2. The method of claim 1 wherein the step of depressurizing is simultaneously taking out gas from the feed end and the product end of the bed.

3. The method of claim 1 wherein the step of depressurizing is simultaneously taking out gas at a side takeout of the bed and at the product end of the bed.

4. The method of claim 1 where the step of depressurizing further comprises the steps of simultaneously taking out gas from the product end and the side takeout, and simultaneously taking out gas from the feed end and the product end.

5. The method of claim 1 wherein the step of depressurizing is taking out gas simultaneously from the feed end, product end and a side take-out.

6. The method of claim 1 further comprising the step of purging the bed with the less adsorbable components prior to the step of repressurizing.

7. The method of claim 6 wherein said step of purging is carried out with a purge gas obtained from the product end during said step of depressurizing.

8. The method of claim 1 wherein said steps of flowing and displacing are carried out at essentially the same pressure.

9. The method of claim 1 further comprising the step of depressurizing the bed from a side takeout prior to said step of depressurizing the bed by taking out gas simultaneously.

10. The method of claim 1 further comprising the step of depressurizing said bed in a cocurrent direction, said cocurrent depressurization occurring prior to said step of simultaneously depressurizing.

11. The method of claim 10 wherein said cocurrent depressurization step is performed before said step of displacing.

12. The method of claim 11 where the step of cocurrent depressurizing further comprises the step of repressurizing other beds with a gas obtained from the product end.

13. The method of claim 10 wherein said step of cocurrent depressurization is performed simultaneously with said step of displacing.

14. The method of claim 10 wherein said step of cocurrent depressurization is performed after said step of displacing.

15. The method of claim 10 where the step of cocurrent depressurizing further comprises repressurizing other beds with a gas obtained from the product end.

16. The method of claim 10 wherein the step of cocurrent depressurization is continued to a sufficiently low pressure to position a mass transfer front within said bed for maximum separating efficiency in said step of simultaneously depressurizing.

17. The method of claim 10 wherein the step of displacing further comprises the step of flowing said first component recovered from the feed end onto said bed.

18. The method of claim 17 wherein said first component comprises carbon monoxide, carbon dioxide, or methane and wherein said second component comprises hydrogen or nitrogen.

19. The method of claim 18 wherein said adsorbent bed is a material that contains a member selected from the group consisting of zeolitic molecular sieves, activated carbon, silica gel, activated alumina, and mixtures thereof.

20. The method of claim 1 wherein said step of displacing is performed using fixed position valves.

21. The method of claim 1 wherein said step of displacing is performed using volumetric compressors.

22. The method of claim 1 wherein the number of adsorbent beds is at least four.

23. The method of claim 1 wherein the number of adsorbent beds is five.

24. The method of claim 1 wherein the number of adsorbent beds is six.

25. The method of claim 24 wherein the step of selectively adsorbing components occurs in at least one bed at any given time.

26. A method for gas purification, comprising the steps of:

(a) flowing a feed gas mixture current under pressure through a fixed adsorbent bed, said mixture flowing firstly through a feed end, secondly through said bed, and thirdly out through a product end, said mixture comprising at least two components wherein a first component is more adsorbable than a second component, said first component being selectively adsorbed onto said bed; and

(b) displacing said mixture with a gas having a higher concentration of said first component, whereby said second component is displaced from said feed end; and

(c) depressurizing both of said ends simultaneously by lowering said pressure, whereby said first component is recovered from said feed end in a substantially pure state and said second component is recovered from said product end in a substantially pure state.

27. The method of claim 26 further comprising the step of cocurrently depressurizing said bed to position a mass transfer front within said bed, said cocurrent depressurization step occuring prior to said simultaneous depressurizing step.

28. The method of claim 27 wherein said cocurrent depressurization step is prior to said step of displacing.

29. The method of claim 27 wherein said cocurrent depressurization step is performed subsequent to said step of displacing.

30. The method of claim 27 where said step of cocurrent depressurization further comprises the step of lowering said pressure at said product end.

31. The method of claim 27 where said step of cocurrent depressurization further comprises the step of lowering said pressure at a side take-out located on said bed.

32. The method of claim 31 where said step of displacing further comprises the step of flowing said first component recovered from said feed end into said bed.

33. The method of claim 32 further comprising the step of pressurizing said bed subsequent to the step of simultaneous depressurization.

34. The method of claim 33 wherein said first component comprises carbon monoxide, oxygen, or methane and wherein said second component comprises hydrogen or nitrogen.

35. The method of claim 34 wherein said adsorbent bed is a material that contains a member selected from the group consisting of zeolitic molecular sieves, activated carbon, silica gel, activated alumina, and mixtures thereof.

36. The method of claim 26 wherein said cocurrent depressurization step is performed simultaneously with said step of displacing.