Hot melt magnetic sealant, method of making and method of using same

• US 4,724,243 A
• Filed: 12/29/1986
• Issued: 02/09/1988
• Est. Priority Date: 12/29/1986
• Status: Expired due to Term

• Current Assignee: Permacel Kansas City, Inc. (Nitto Denko Corporation)
• Original Assignee: United Technologies Automotive, Inc. (Lear Corporation)
• Inventors: Harrison, Bruce
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US06/947,346
• Time in Patent Office: 407 Days
• Field of Search: 523/400, 523/437, 523/438, 264/174.2, 264/211.12, 264/232, 156/306.9
• US Class Current: 523/400
• CPC Class Codes: C08K 3/10 Metal compounds
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 63/00 Compositions of epoxy resins; Compositions of derivatives of epoxy resins
• CPC Class Codes: C09J 7/10 without carriers

Abstract

A hot melt magnetic sealant that exhibits improved adhesion to oil covered galvanized ferrometallic substrates and to epoxy electrodeposition coated ferrometallic substrates is disclosed. The sealant comprises magnetic filler particles, a hydrocarbon resin, a tackifier resin, a plasticizer, an epoxy resin and an epoxy curing agent. A method for making a hot melt sealant tape comprising mixing a formulation of magnetizable particles, a hydrocarbon resin, a tackifier resin, a plasticizer, an epoxy resin and an epoxy curing agent, extruding the mixture to form a tape and exposing the tape to an electromagnetic field is also disclosed. Methods for using the magnetic sealant tape to seal a joint between ferrometallic members having oil covered galvanized surfaces or epoxy electrodeposition coated ferrometallic members comprising disposing the tape to cover the joint and heating the tape are also disclosed.

Claims

1. A hot melt magnetic sealant, comprising, in weight percent:

about 8% to about 15% hydrocarbon resin, 0% to about 7% tackifier resin, about 5% to about 18% plasticizer, about 65% to about 72% magnetic particles, about 5% to about 15% epoxy resin and about 0.7% to about 2% epoxy curing agent, said sealant providing a durable seal that is strongly adherent to oil-coated, galvanized ferrometallic substrates and to epoxy coated ferrometallic substrates after curing by exposure to elevated temperature in the range of about 240°

F. to about 300°

F.

2. The hot melt sealant of claim 1, wherein the epoxy resin comprises the diglycidal ether of bisphenol A.

3. The hot melt sealant of claim 1, wherein the epoxy curing agent comprises a boron trichloride-amine complex.

4. A method of making a hot melt magnetic sealant tape, comprising:

(a) mixing a magnetic sealant formulation comprising, in weight percent;

about 8% to about 15% hydrocarbon resin, 0% to about 7% tackifier resin, about 5% to about 18% plasticizer, about 65% to about 72% magnetic particles, about 5% to about 15% epoxy resin and about 0.7% to about 2% epoxy curing agent,

(b) extruding the mixture to form an elongated sealant tape,

(c) exposing the sealant tape to an electromagnetic field to magnetize the magnetizable particles in the tape, said magnetic sealant tape providing a durable seal that is strongly adherent to oil-coated, galvanized ferrometallic substrates and is strongly adherent to epoxy coated ferrometallic substrates after curing by exposure to elevated temperature in the range of about 240°

F. to about 300°

F.

5. The method of claim 4, wherein the epoxy resin comprises the diglycidal ether of bisphenol A.

6. The method of claim 4, wherein the epoxy curing agent comprises a boron trichloride-amine complex.