Potable water from internal combustion engines

• US 4,725,359 A
• Filed: 02/25/1985
• Issued: 02/16/1988
• Est. Priority Date: 02/25/1985
• Status: Expired due to Fees

• Current Assignee: Bend Research Inc. (Lonza Group AG)
• Original Assignee: Bend Research Inc. (Lonza Group AG)
• Inventors: Ray, Roderick J.
• Primary Examiner(s): SPEAR JR, FRANK
• Application Number:
  US06/704,868
• Time in Patent Office: 1,086 Days
• Field of Search: 55/DIG. 30, 210/640, 60/311
• US Class Current: 210/640
• CPC Class Codes: B01D 53/268 by diffusion
• CPC Class Codes: C02F 1/16 using waste heat from other processes
• CPC Class Codes: Y10S 55/30 Exhaust treatment

Abstract

A method of and apparatus for obtaining potable water from the exhaust of an internal combustion engine is disclosed essentially comprising separating a water vapor permeate containing water vapor and noncondensable gases from the exhaust by a nonporous nonionic hydrophilic membrane, then separating the water vapor from noncondensable gases by either condensing the water vapor or compressing the entire water vapor permeate followed by condensation of the water vapor contained in the permeate.

Claims

1. A method of obtaining substantially pure water from the exhaust stream of an internal combustion engine comprising:

(a) cooling said exhaust stream to a temperature between about 65° and

150°

C.;

(b) separating water vapor from said exhaust stream by contacting said exhaust stream with one side of a nonporous nonionic hydrophilic polymeric membrane that is substantially permeable to water vapor and substantially impermeable to noncondensable components of said exhaust stream so as to form (1) a reject stream comprising a major portion of noncondensable gases and a minor portion of hydrocarbon compounds and (2) a separated water vapor permeate on the permeate side of said membrane, said separated water vapor permeate comprising a major portion of water vapor and a minor portion of noncondensable gases; and

(c) recovering substantially pure water from said separated water vapor permeate by separating said water vapor from said noncondensable gases.

2. The method of claim 1 wherein said recovery of substantially pure water is accomplished by condensation of said water vapor in said separated water vapor permeate followed by compression of said noncondensable gases in said separated water vapor permeate.

3. The method of claim 1 wherein said recovery of substantially pure water is accomplished by compression of said separated water vapor permeate followed by condensation of said water vapor in said separated water vapor permeate.

4. The method of claim 1 wherein said membrane is selected from interfacially-polymerized composite reverse osmosis membranes, asymmetric reverse osmosis membranes, dialysis membranes and gas separation membranes, said membranes being made of silicone rubbers, natural rubbers, synthetic rubbers, nylons, organopolysiloxanepolycarbonate block copolymers, cellulose, ethyl cellulose, hydroxypropyl cellulose, cellulose esters, sulfonated polyphenylene oxides, polyvinylalcohols, polyvinylidene fluoride, polyethyleneimines, polystyrene sulfonates, polyvinyl butyral, polyvinyl acetate, polyacrylonitrile, polymethacrylates, polyacrylics, polybutadiene, polyesters, polyamides, polyimides, polycarbonates, and polybenzimidazoles.

5. The method of claim 4 wherein said membrane is in the form of a module.

6. The method of claim 5 wherein said membrane comprises one or more spirally-wound asymmetric cellulose acetate membrane modules.

7. The method of claim 5 wherein said membrane comprises cuprammonium cellulose hollow fine fibers.

8. The method of claim 1 including the additional step of charcoal filtration of said substantially pure water.

9. The method of claim 1 wherein the pressure on the contact side of said membrane is substantially atmospheric and the pressure on the permeate side of said membrane is lower than the partial pressure of said water vapor in said exhaust stream.

10. The method of claim 1 wherein said cooling of said exhaust stream is accomplished by means selected from convection, radiation and heat exchange.

11. The method of claim 2 wherein said condensation of said water vapor in said separated water vapor permeate is by means of a condenser and said compression of said noncondensable gases in said separated water vapor permeate is by means of a vacuum pump.

12. The method of claim 3 wherein said compression of said separated water vapor permeate is by means of a vacuum pump and said condensation of said water vapor is by means of a condenser.

13. The method of claim 1 wherein said internal combustion engine is a hydrocarbon fuel-burning engine

14. The method of claim 13 wherein said hydrocarbon fuel is diesel.

15. The method of claim 13 wherein said hydrocarbon fuel is gasoline.

16. The method of claim 13 wherein said hydrocarbon fuel is methane.