High magnetic permeability composites containing fibers with ferrite fill

• US 4,725,490 A
• Filed: 05/05/1986
• Issued: 02/16/1988
• Est. Priority Date: 05/05/1986
• Status: Expired due to Fees

• Current Assignee: Hoechst Celanese Corporation (Sanofi )
• Original Assignee: Hoechst Celanese Corporation (Sanofi )
• Inventors: Goldberg, Harris A.
• Primary Examiner(s): Cannon, James C.
• Application Number:
  US06/859,292
• Time in Patent Office: 652 Days
• Field of Search: 342/1, 342/2, 342/3, 342/5, 342/6, 343/756, 343/897, 343/909, 428/292, 428/293, 428/294, 428/302, 428/329, 428/697, 428/701
• US Class Current: 442/202
• CPC Class Codes: H01Q 15/02 Refracting or diffracting devices, e.g. lens, prism
• CPC Class Codes: H01Q 17/005 using woven or wound filaments; impregnated nets or clothes
• CPC Class Codes: Y10T 442/3171 Strand material is a blend of polymeric material and a filler material
• CPC Class Codes: Y10T 442/642 Strand or fiber material is a blend of polymeric material and a filler material

Abstract

High magnetic permeability composites are obtained by incorporating ferrite fibers in the composites. The ferrite fibers consist of a polymer and particulate ferrite fill at a concentration above the percolation threshold for the ferrite fill in the polymer (typically greater than 30 volume percent). The aspect ratio and ferrite concentration of the fibers are selected to minimize demagnetization fields in the fibers. The fibers can be dispersed in low concentration in an unoriented fashion in the composites to impart high magnetic permeability to the composite. In other embodiments, the fibers are oriented in the composites to impart high magnetic permeability to the composite for incident radiation of a particular linear polarization.

Claims

1. A composite material having enhanced magnetic permeability comprising a non-magnetic matrix material and nonconducting fibers dispersed in said matrix material at a volume concentration less than 30% with respect to the matrix material, said fibers having an average aspect ratio of at least 20, said fibers having ferrite particulates therein at a concentration above the percolation threshold of said ferrite material in said fiber, and said fibers having longitudinal axes oriented randomly with respect to one another, so that the magnetic permeability of the composite is approximately proportional to the product of the magnetic permeability of the ferrite and the volume percent of ferrite material in the composite.

2. The composite of claim 1 wherein the volume percent and permeability of the ferrite are selected to minimize the reflectivity of the composite to incident electromagnetic radiation.

3. The composite of claim 2 wherein the magnetic permeability of the ferrite is between 10 and 100 in the frequency range of 100 MHz to 1000 MHz, and wherein the aspect ratio of the fibers is at least 50.

4. The composite of claim 1 wherein said fibers are sintered ferrite rods.

5. The composite of claim 1 wherein said fibers are less than 70 volume percent polymer and greater than 30 volume percent ferrite.

6. The composite of claim 5 wherein the polymer is selected from the group consisting of polyvinyl alcohol, polybenzimidazole and polyacrylonitrile.

7. The composite of claim 1 further comprising nonmagnetic, dielectric fibers dispersed in said matrix.

8. A composite material having enhanced magnetic permeability comprising:

a non-magnetic matrix material; and

non-conducting fibers dispersed in said matrix material at a volume concentration below a percolation threshold for said fibers in said matrix, said fibers having an aspect ratio of at least 50 and comprising;

a polymer material and a particulate ferrite, wherein the volume percent of the particulate ferrite in said fiber is above a percolation threshold for said ferrite in said polymer.

9. A composite material having reduced reflectivity to electromagnetic radiation comprising:

a low density, low dielectric constant matrix;

chopped, ferrite filled fiber dispersed in said matrix, said fiber having a magnetic permeability greater than its dielectric constant; and

chopped, non-magnetic, dielectric filled fiber dispersed in said matrix.

10. The composite material of claim 9 wherein the fibers are selected so that the dielectric constant of the composite is approximately equal to the magnetic permeability of the composite at a predetermined frequency of interest.

11. The composite material of claim 9 wherein said dielectric filled fibers comprise a polymer and lead-zirconium titanate (PZT), PbZrTiO₄.

12. The composite material of claim 9 wherein said ferrite filled fibers comprise a polymer and spinel particulates.

13. An absorber for polarized electromagnetic energy in a frequency range from about 10 megahertz to about 10 GHz, said energy being incident on the absorber from free air, said absorber comprising fibers at least a portion of which includes a ferrite, longitudinal axes of said fibers being generally parallel to one another, and wherein said fibers are generally aligned with the magnetic field of said polarized electromagnetic energy and wherein said fibers comprise a polymer and from 20 to 80 volume percent particulate ferrite fill.

14. The absorber of claim 13 wherein the fibers have an average aspect ratio of at least 50.

15. The absorber of claim 13 wherein the magnetic permeability of the fibers is greater than 4.

16. The absorber of claim 13 further comprising nonmagnetic dielectric fibers having longitudinal axes aligned generally parallel to one another, and wherein said dielectric fibers are generally aligned with the electric field of said polarized electromagnetic energy.

17. The absorber of claim 16 wherein said dielectric fibers comprise a polymer and a particulate, high dielectric constant fill.

18. The absorber of claim 16 wherein the dielectric constant of the non-magnetic dielectric fiber is greater than 4.

19. The absorber of claim 13 wherein the effective dielectric constant of the absorber is approximately equal to the effective magnetic permeability of the absorber, for said polarized electromagnetic radiation.

20. An electromagnetic energy absorbing sheet material in which the dielectric constant presented to incident electromagnetic radiation is approximately equal to the magnetic permeability, comprising non-conducting fibers containing ferrite, said ferrite-containing fibers being oriented approximately parallel to one another, and non-conducting fibers containing a dielectric material, said dielectric material containing fibers oriented approximately parallel to one another.

21. The material of claim 20 wherein the ferrite fibers are oriented approximately perpendicular to the dielectric fibers.

22. The material of claim 20 wherein the ferrite fibers and dielectric fibers are composited with a polymer binder.

23. The material of claim 22 wherein the ferrite of said ferrite fibers is a spinel corresponding to the formula

24. The material of claim 22 wherein the dielectric fibers comprise a polymer and a particulate dielectric fill comprising from 20 to 70 percent by volume of the fiber.

25. The material of claim 24 wherein the dielectric fill is a ferroelectric material such as lead-zirconium titanate (PZT), PbZrTiO₄.