Method of monitoring electrochemical cells

• US 4,727,006 A
• Filed: 02/12/1986
• Issued: 02/23/1988
• Est. Priority Date: 02/12/1986
• Status: Expired due to Fees

• Current Assignee: United States Of America As Represented By The Secretary Of The Army (Government of the United States of America)
• Original Assignee: The United States Of America As Represented By The Secretary Of The Army
• Inventors: Chaskin, Deborah M., Malinowski, Gregory J.
• Primary Examiner(s): Hearn, Brian E.
• Assistant Examiner(s): KALAFUT, STEPHEN J
• Application Number:
  US06/831,027
• Time in Patent Office: 741 Days
• Field of Search: 429/50, 429/61, 429/62, 429/90, 320/35, 320/36, 436/147, 73/52
• US Class Current: 429/50
• CPC Class Codes: H01M 10/48 Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569
• CPC Class Codes: H01M 2200/00 Safety devices for primary or secondary batteries
• CPC Class Codes: H01M 2200/10 Temperature sensitive devices
• CPC Class Codes: H01M 2200/20 Pressure-sensitive devices
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y10S 320/13 Fault detection

Abstract

The physical and electrical condition of electrochemical cells of a batterys monitored on a continuous basis so that corrective action can be taken before explosion and/or venting occurs by a method including the steps of:

(A) coating the electrically conductive shell of each cell of the battery with a thin non electrically conductive layer,

(B) applying a sensor stripe over the non electrically conductive layer so that the sensor stripe does not make electrical contact to the shell of the cell,

(C) connecting leads to the sensor and then coating the sensor with a protective layer, and

(D) connecting the sensor leads of individual cells of the battery into an electrical series circuit, the remaining leads of the series sensor circuit being connected to an alarm/control network that monitors the conductivity of the series electrical path.

Claims

1. Method of monitoring on a continuous basis the physical and electrical condition of electrochemical cells of a battery so that corrective action can be taken before explosion and/or venting occurs, and wherein each of the electrochemical cells has an electrically conductive shell, said method including the steps of:

(A) coating the electrically conductive shell of each cell of the battery with a thin non electrically conductive layer,

(B) applying a sensor stripe over the non electrically conductive layer so that the sensor does not make electrical contact to the shell of the cell, wherein the sensor stripe is comprised of multiple sensor elements including a conductive thermally sensitive material and a conductive stress/strain material, and wherein said materials are connected together to form a continuous series electrical path using bonding pads of a metallic material to interface the junctions of the conductive thermally sensitive material and the sensor leads.

(C) connectng leads to the sensor and then coating the sensor with a protective layer, and

(D) connecting the sensor leads of individual cells of the battery into an electrical series circuit, the remaining leads of the series sensor circuit being connected to an alarm/control network that monitors the conductivity of the series electrical path.

2. Method according to claim 1 wherein the thin non-electrically conductive layer is a good thermal conductor and has a low elasticity coefficient.

3. Method according to claim 2 wherein the thin non-electrically conductive layer is selected from the group consisting of a thin layer of epoxy and an anodized surface.

4. Method according to claim 3 wherein the thin non-electrically conductive layer is a thin layer of epoxy.

5. Method according to claim 3 wherein the thin non-electrically conductive layer is an anodized surface.

6. Method according to claim 1 wherein the sensor stripe is comprised of an electrically conductive material having a low elasticity coefficient, that is not very malleable, and that has a melting point equal to that temperature at which the cell being monitored becomes critical.

7. Method according to claim 6 wherein the sensor stripe is comprised of an alloy of 121/2 percent by weight of tin, 25 percent by weight of lead, 50 percent by weight of bismuth, and 121/2 percent by weight of cadmium and having a melting point of 75°

C.

8. Method according to claim 6 wherein the sensor stripe is composed of an alloy of 63 percent by weight of tin and 37 percent by weight of lead and having a melting point of 183°

C.

9. Method according to claim 1 wherein the non-electrically conductive layer and the sensor stripe cover the venting device of the cell.

10. Method according to claim 1 wherein the non-electrically conductive layer and the sensor stripe do not cover the venting device of the cell.

11. Method according to claim 1 wherein the protective layer is comprised of thermally shrunk polymer tubing.